An unusual dienone-phenol rearrangement product formed during the synthesis of mometasone furoate (Sch 32088).

Journal Article (Journal Article)

The structure of an unusual dienone-phenol rearrangement product 4 obtained during the synthesis of mometasone furoate (Sch 32088) was assigned on the basis of NMR and x-ray crystallographic data. The mechanism of formation is discussed.

Full Text

Duke Authors

Cited Authors

  • Draper, RW; Puar, MS; Vater, EJ; McPhail, AT

Published Date

  • March 1, 1998

Published In

Volume / Issue

  • 63 / 3

Start / End Page

  • 135 - 140

PubMed ID

  • 9558713

Electronic International Standard Serial Number (EISSN)

  • 1878-5867

International Standard Serial Number (ISSN)

  • 0039-128X

Digital Object Identifier (DOI)

  • 10.1016/s0039-128x(97)00155-4

Language

  • eng