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Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.

Publication ,  Journal Article
Mukherjee, P; Widenhoefer, RA
Published in: Organic letters
March 2010

A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF(6) catalyzes the intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regioselectivity and syn-stereoselectivity.

Duke Scholars

Published In

Organic letters

DOI

EISSN

1523-7052

ISSN

1523-7060

Publication Date

March 2010

Volume

12

Issue

6

Start / End Page

1184 / 1187

Related Subject Headings

  • Urea
  • Stereoisomerism
  • Silver
  • Propanols
  • Organogold Compounds
  • Organic Chemistry
  • Molecular Structure
  • Gold
  • Catalysis
  • Amination
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Mukherjee, P., & Widenhoefer, R. A. (2010). Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles. Organic Letters, 12(6), 1184–1187. https://doi.org/10.1021/ol902923e
Mukherjee, Paramita, and Ross A. Widenhoefer. “Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.Organic Letters 12, no. 6 (March 2010): 1184–87. https://doi.org/10.1021/ol902923e.
Mukherjee P, Widenhoefer RA. Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles. Organic letters. 2010 Mar;12(6):1184–7.
Mukherjee, Paramita, and Ross A. Widenhoefer. “Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.Organic Letters, vol. 12, no. 6, Mar. 2010, pp. 1184–87. Epmc, doi:10.1021/ol902923e.
Mukherjee P, Widenhoefer RA. Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles. Organic letters. 2010 Mar;12(6):1184–1187.
Journal cover image

Published In

Organic letters

DOI

EISSN

1523-7052

ISSN

1523-7060

Publication Date

March 2010

Volume

12

Issue

6

Start / End Page

1184 / 1187

Related Subject Headings

  • Urea
  • Stereoisomerism
  • Silver
  • Propanols
  • Organogold Compounds
  • Organic Chemistry
  • Molecular Structure
  • Gold
  • Catalysis
  • Amination