Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.

Journal Article (Journal Article)

A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF(6) catalyzes the intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regioselectivity and syn-stereoselectivity.

Full Text

Duke Authors

Cited Authors

  • Mukherjee, P; Widenhoefer, RA

Published Date

  • March 2010

Published In

Volume / Issue

  • 12 / 6

Start / End Page

  • 1184 - 1187

PubMed ID

  • 20180519

Pubmed Central ID

  • PMC2929168

Electronic International Standard Serial Number (EISSN)

  • 1523-7052

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol902923e


  • eng