Effect of strain in sputtered AlN buffer layers on the growth of GaN by molecular beam epitaxy

The strain dynamic of thin film AlN is investigated before and after the deposition of a GaN epitaxial layer using plasma assisted molecular beam epitaxy. X-ray diffraction ω / 2 θ-scan and asymmetric reciprocal space mapping analysis show that the deposition of GaN alters the strain state of the underlying AlN template. The in-plane lattice constant of the AlN is found to increase upon growth of GaN, giving rise to a more relaxed GaN epitaxial layer. Hence, the subsequent GaN epitaxial thin film possesses better structural quality especially with lower screw dislocation density and flat surface morphology which is evidenced by the X-ray diffraction ω-scan, room temperature photoluminescence, and atomic force microscopy analysis. Such relaxation of AlN upon GaN deposition is only observed for relatively thin AlN templates with thicknesses of 20 nm-30 nm; this effect is negligible for AlN with thickness of 50 nm and above. As the thicker AlN templates already themselves relax before the GaN deposition, the localized strain fields around the misfit dislocations prohibit further change of lattice parameters.

Duke Scholars

Author April S. Brown Electrical and Computer Engineering