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Metal-based NO sensing by selective ligand dissociation

Publication ,  Journal Article
Franz, KJ; Singh, N; Lippard, SJ
Published in: Angewandte Chemie - International Edition
2000

Nitric oxide reacts selectively with the O2 stable, weakly fluorescent complex [Co(DATI-4)] in dichloromethane solution to dissociate a fluorophore- substituted arm of the aminotroponiminate ligand DATI-4. The resulting cobalt-dinitrosyl adduct (see picture) effects a positive fluorescence response. The detection limit of 2 is 50-100 μm for NO.

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Published In

Angewandte Chemie - International Edition

DOI

Publication Date

2000

Volume

39

Issue

12

Start / End Page

2120 / 2122

Related Subject Headings

  • Organic Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

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Franz, K. J., Singh, N., & Lippard, S. J. (2000). Metal-based NO sensing by selective ligand dissociation. Angewandte Chemie - International Edition, 39(12), 2120–2122. https://doi.org/10.1002/1521-3773(20000616)39:12<2120::AID-ANIE2120>3.0.CO;2-M
Franz, K. J., N. Singh, and S. J. Lippard. “Metal-based NO sensing by selective ligand dissociation.” Angewandte Chemie - International Edition 39, no. 12 (2000): 2120–22. https://doi.org/10.1002/1521-3773(20000616)39:12<2120::AID-ANIE2120>3.0.CO;2-M.
Franz KJ, Singh N, Lippard SJ. Metal-based NO sensing by selective ligand dissociation. Angewandte Chemie - International Edition. 2000;39(12):2120–2.
Franz, K. J., et al. “Metal-based NO sensing by selective ligand dissociation.” Angewandte Chemie - International Edition, vol. 39, no. 12, 2000, pp. 2120–22. Scival, doi:10.1002/1521-3773(20000616)39:12<2120::AID-ANIE2120>3.0.CO;2-M.
Franz KJ, Singh N, Lippard SJ. Metal-based NO sensing by selective ligand dissociation. Angewandte Chemie - International Edition. 2000;39(12):2120–2122.

Published In

Angewandte Chemie - International Edition

DOI

Publication Date

2000

Volume

39

Issue

12

Start / End Page

2120 / 2122

Related Subject Headings

  • Organic Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences