Skip to main content
Journal cover image

Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns

Publication ,  Journal Article
Loehlin, JH; Franz, KJ; Gist, L; Moore, RH
Published in: Acta Crystallographica Section B: Structural Science
October 1, 1998

An analysis of the structures of five new cocrystals with saturated hydrogen bonding between amines and alcohols is presented. These five are all cocrystals with p-phenylenediamine (PDA) and a mono- or diol. The cocrystals are p-phenylenediamine-phenol (1/2) [PDA·2 phenol, (I)], p-phenylenediamine-p-phenylphenol (1/2) [PDA·2 p-phenylphenol (II)], p-phenylenediamine-2,6-dihydroxynaphthalene (1/1) [PDA·2,6-dihydroxynaphthalene (III)], p-phenylenediamine-1,6-hexanediol (1/1) [PDA-1,6-hexanediol (IV)] and p-phenylenediamine-p-chlorophenol (1/2) [PDA·2 p-chlorophenol (V)]. These crystals have two distinctly different supramolecular hydrogen-bond patterns, when considering only the hydroxyl and amine groups. There are, in addition, variations in the ways covalently bonded crosslinks connect these hydrogen-bond networks. The graph sets of the hydrogen-bond networks of these and other published saturated amine-alcohol crystals are compared and suggestions made on how to present the graph-set descriptions, especially those involving infinite two- and three-dimensional networks of intersecting chains which are characteristic of most of these materials.

Duke Scholars

Published In

Acta Crystallographica Section B: Structural Science

DOI

ISSN

0108-7681

Publication Date

October 1, 1998

Volume

54

Issue

5

Start / End Page

695 / 704

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0912 Materials Engineering
  • 0306 Physical Chemistry (incl. Structural)
  • 0301 Analytical Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Loehlin, J. H., Franz, K. J., Gist, L., & Moore, R. H. (1998). Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns. Acta Crystallographica Section B: Structural Science, 54(5), 695–704. https://doi.org/10.1107/S0108768198003231
Loehlin, J. H., K. J. Franz, L. Gist, and R. H. Moore. “Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns.” Acta Crystallographica Section B: Structural Science 54, no. 5 (October 1, 1998): 695–704. https://doi.org/10.1107/S0108768198003231.
Loehlin JH, Franz KJ, Gist L, Moore RH. Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns. Acta Crystallographica Section B: Structural Science. 1998 Oct 1;54(5):695–704.
Loehlin, J. H., et al. “Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns.” Acta Crystallographica Section B: Structural Science, vol. 54, no. 5, Oct. 1998, pp. 695–704. Scopus, doi:10.1107/S0108768198003231.
Loehlin JH, Franz KJ, Gist L, Moore RH. Supramolecular Alcohol-Amine Crystals and Their Hydrogen-Bond Patterns. Acta Crystallographica Section B: Structural Science. 1998 Oct 1;54(5):695–704.
Journal cover image

Published In

Acta Crystallographica Section B: Structural Science

DOI

ISSN

0108-7681

Publication Date

October 1, 1998

Volume

54

Issue

5

Start / End Page

695 / 704

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0912 Materials Engineering
  • 0306 Physical Chemistry (incl. Structural)
  • 0301 Analytical Chemistry