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Breaking down the supramolecular ensemble: Single-molecule studies of the concentration dependence of main-chain supramolecular polymer molecular weight distributions on surfaces

Publication ,  Journal Article
Serpe, MJ; Whitehead, JR; Craig, SL
Published in: Australian Journal of Chemistry
April 19, 2010

Single molecule atomic force microscopy (AFM) studies of oligonucleotide-based supramolecular polymers on surfaces are used to examine the molecular weight distribution of the polymers formed between a functionalized surface and an AFM tip as a function of monomer concentration. For the concentrations examined here, excellent agreement with a multi-stage open association model of polymerization is obtained, without the need to invoke additional contributions from secondary steric interactions at the surface. © CSIRO 2010.

Duke Scholars

Published In

Australian Journal of Chemistry

DOI

ISSN

0004-9425

Publication Date

April 19, 2010

Volume

63

Issue

4

Start / End Page

624 / 626

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Serpe, M. J., Whitehead, J. R., & Craig, S. L. (2010). Breaking down the supramolecular ensemble: Single-molecule studies of the concentration dependence of main-chain supramolecular polymer molecular weight distributions on surfaces. Australian Journal of Chemistry, 63(4), 624–626. https://doi.org/10.1071/CH09615
Serpe, M. J., J. R. Whitehead, and S. L. Craig. “Breaking down the supramolecular ensemble: Single-molecule studies of the concentration dependence of main-chain supramolecular polymer molecular weight distributions on surfaces.” Australian Journal of Chemistry 63, no. 4 (April 19, 2010): 624–26. https://doi.org/10.1071/CH09615.
Serpe, M. J., et al. “Breaking down the supramolecular ensemble: Single-molecule studies of the concentration dependence of main-chain supramolecular polymer molecular weight distributions on surfaces.” Australian Journal of Chemistry, vol. 63, no. 4, Apr. 2010, pp. 624–26. Scopus, doi:10.1071/CH09615.
Journal cover image

Published In

Australian Journal of Chemistry

DOI

ISSN

0004-9425

Publication Date

April 19, 2010

Volume

63

Issue

4

Start / End Page

624 / 626

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences