Overview
Research interests in Prof. Craig's group bridge physical organic and materials chemistry. Many of these interests are guided by the vision that important challenges in materials science might be better tackled not from the traditional perspective of an engineer, but rather from the molecular perspective of an organic chemist. Current interests include the design and synthesis of self-healing polymers and the use of modern mechanochemistry in new stress-responsive polymers, catalysis, and the study of transition states and reactive intermediates. These areas require an interdisciplinary and nontraditional mix of synthetic organic and polymer chemistry, single-molecule spectroscopy, supramolecular chemistry, and materials characterization.
Research interests are complemented by numerous teaching and outreach activities, including: (1) hosting intensive undergraduate and high school research experiences for a diverse group of both Duke and non-Duke students; (2) exploiting effective, scalable, and low-cost mechanisms for content dissemination; (3) team-based and active learning content in the undergraduate and graduate classroom.
Current Appointments & Affiliations
William T. Miller Distinguished Professor of Chemistry
·
2013 - Present
Chemistry,
Trinity College of Arts & Sciences
Professor in the Department of Chemistry
·
2012 - Present
Chemistry,
Trinity College of Arts & Sciences
Bass Fellow
·
2012 - Present
Chemistry,
Trinity College of Arts & Sciences
In the News
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Recent Publications
Fracture of polymer-like networks with hybrid bond strengths
Journal Article Journal of the Mechanics and Physics of Solids · February 1, 2025 The design and functionality of polymeric materials hinge on failure resistance. While molecular-level details drive crack evolution in polymer networks, the connection between individual chain scission and bulk failure remains unclear and difficult to pro ... Full text CiteEnabling Selective Mechanochemical Scission of Network Crosslinks by Exchanging Single Carbon Atoms for Silicon.
Journal Article Journal of the American Chemical Society · February 2025 The tearing of a polymer network arises from mechanochemically coupled bond-breaking events in the backbone of a polymer chain. An emerging research area is the identification of molecular strategies for network toughening, such as the strategic placement ... Full text CiteStructure-property relationships for the force-triggered disrotatory ring-opening of cyclobutene.
Journal Article Chemical science · February 2025 Symmetry forbidden reactions are notoriously difficult to study experimentally, for the simple reason that their competing symmetry allowed pathways typically dominate. Covalent polymer mechanochemistry offers an opportunity to broaden access to symmetry f ... Full text CiteRecent Grants
NSF-BSF: Emergent Rheology of Blends Containing Supramolecular Polymers
ResearchPrincipal Investigator · Awarded by National Science Foundation · 2024 - 2027Covalent Polymer Mechanochemistry
ResearchPrincipal Investigator · Awarded by National Science Foundation · 2023 - 2027Multi-State Catalysts Modulated by Mechanical Force
ResearchCo Investigator · Awarded by Department of Energy · 2017 - 2027View All Grants
Education, Training & Certifications
Stanford University ·
1997
Ph.D.
University of Cambridge (United Kingdom) ·
1992
M.Phil.
Duke University ·
1991
B.S.