Electrochemical charge storage properties of vertically aligned carbon nanotube films: Effects of thermal oxidation

Vertically aligned carbon nanotube (VACNT) films were synthesized and investigated in vitro for their potential use as a neural stimulation electrode. Materials and electrochemical (EC) characterization (cyclic voltammetry, electrochemical impedance spectroscopy, and high-rate potential transient measurements) were performed before and after flash oxidation in O 2 at various temperatures and over a wide frequency range. The results showed distinct EC behavior within three ranges of treatment temperature. Oxidative thermal treatments that did not visibly etch the VACNT film caused a significant improvement in electrode performance compared to the as-deposited electrode. Surprisingly, flash oxidation within a narrow temperature range (400 < T ≥ 450 °C) selectively increased capacitance/charge injection at high frequencies (10 2-10 4 Hz). A phenomenological model is proposed to explain the temperature-dependent behavior and indicates the importance of modifying a porous coating to increase the charging rate rather than maximizing the total charge accumulated at long times for high-rate charge storage applications. © 2012 American Chemical Society.

Duke Scholars

Author Charles Parker  

Author Brian R. Stoner Electrical and Computer Engineering

Author Warren M. Grill Biomedical Engineering

Author Jeffrey Glass Electrical and Computer Engineering