David Mitzi
Simon Family Professor
David Mitzi received his B.S. in Electrical Engineering and Engineering Physics from Princeton University in 1985 and his Ph.D. in Applied Physics from Stanford University in 1990. Prior to joining the faculty at Duke in 2014, Dr. Mitzi spent 23 years at IBM’s T.J. Watson Research Center, where his focus was on the search for and application of new electronic materials, including organic-inorganic hybrids and inorganic materials for photovoltaic, LED, transistor and memory applications. For his final five years at IBM, he served as manager for the Photovoltaic Science and Technology Department, where he initiated and managed a multi-company program to develop a low-cost, high-throughput approach to deposit thin-film chalcogenide-based absorber layers for high-efficiency solar cells. Dr. Mitzi’s current research interests involve making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market. He holds a number of patents, and has authored or coauthored more than 200 papers and book chapters.
Current Research Interests
Making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market.
Current Appointments & Affiliations
- Simon Family Professor, Mechanical Engineering and Materials Science, Pratt School of Engineering 2016
- Professor in the Department of Mechanical Engineering and Materials Science, Mechanical Engineering and Materials Science, Pratt School of Engineering 2014
- Professor of Chemistry, Chemistry, Trinity College of Arts & Sciences 2015
- Faculty Network Member of The Energy Initiative, Duke University Energy Initiative, Initiatives 2012
Contact Information
- 363 Gross Hall, Box 90300, Durham, NC 27708
- 363 Gross Hall, Box 90300, Durham, NC 27708
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david.mitzi@duke.edu
(919) 660-5356
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Google Scholar - David B. Mitzi
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Mitzi group website
- Background
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Education, Training, & Certifications
- Ph.D., Stanford University 1990
- B.S., Princeton University 1985
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Duke Appointment History
- Visiting Professor in the Department of Mechanical Engineering and Materials Science, Mechanical Engineering and Materials Science, Pratt School of Engineering 2014
- Recognition
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In the News
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NOV 27, 2018 -
OCT 8, 2018 Pratt School of Engineering -
AUG 23, 2018 Pratt School of Engineering -
AUG 21, 2018 -
FEB 10, 2018 Pratt School of Engineering -
JAN 3, 2018 Pratt School of Engineering -
APR 28, 2017 -
MAY 5, 2016 -
MAY 7, 2015 Duke Research Blog -
OCT 23, 2014 -
AUG 18, 2014
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Awards & Honors
- Expertise
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Subject Headings
- Research
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Selected Grants
- Center for Hybrid Organic-Inorganic Semiconductors for Energy (CHOISE) 2019 - 2023
- MRI: Acquisition of a Cryogen-Free Physical Properties Measurement System (PPMS DynaCool) awarded by National Science Foundation 2018 - 2021
- DMREF: Collaborative Research: HybriD3: Discovery, Design, Dissemination of Organic-Inorganic Hybrid Semiconductor Materials for Optoelectronic Applications awarded by National Science Foundation 2017 - 2021
- GOALI: Doping Control and Processes in Metal Halide Perovskites awarded by National Science Foundation 2017 - 2020
- Melt Processing of Operationally-Stable Perovskite Photovoltaic Films and Devices awarded by Office of Naval Research 2017 - 2020
- High-Performance Perovskite-Based Solar Cells awarded by Department of Energy 2014 - 2019
- GAANN - Department of Chemistry awarded by Department of Education 2015 - 2019
- Defect Engineering in Zinc-Blende-Type Absorbers awarded by National Science Foundation 2015 - 2019
- Publications & Artistic Works
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Selected Publications
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Academic Articles
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Li, T., Zeidell, A. M., Findik, G., Dunlap-Shohl, W. A., Euvrard, J., Gundogdu, K., … Mitzi, D. B. (2019). Phase-Pure Hybrid Layered Lead Iodide Perovskite Films Based on a Two-Step Melt-Processing Approach. Chemistry of Materials, 31(11), 4267–4274. https://doi.org/10.1021/acs.chemmater.9b01265Full Text
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Sun, J. P., Márquez, J. A., Stange, H., Mainz, R., & Mitzi, D. B. (2019). Phase and film formation pathway for vacuum-deposited C u2BaSn(S,Se)4 absorber layers. Physical Review Materials, 3(5). https://doi.org/10.1103/PhysRevMaterials.3.055402Full Text
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Jana, M. K., Janke, S. M., Dirkes, D. J., Dovletgeldi, S., Liu, C., Qin, X., … Mitzi, D. B. (2019). Direct-Bandgap 2D Silver-Bismuth Iodide Double Perovskite: The Structure-Directing Influence of an Oligothiophene Spacer Cation.. Journal of the American Chemical Society, 141(19), 7955–7964. https://doi.org/10.1021/jacs.9b02909Full Text
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Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P., & Mitzi, D. B. (2019). Synthetic Approaches for Halide Perovskite Thin Films.. Chemical Reviews, 119(5), 3193–3295. https://doi.org/10.1021/acs.chemrev.8b00318Full Text
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Mitzi, D. B. (2019). Introduction: Perovskites.. Chemical Reviews, 119(5), 3033–3035. https://doi.org/10.1021/acs.chemrev.8b00800Full Text
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Ding, J., Han, Q., Ge, Q. Q., Xue, D. J., Ma, J. Y., Zhao, B. Y., … Hu, J. S. (2019). Fully Air-Bladed High-Efficiency Perovskite Photovoltaics. Joule, 3(2), 402–416. https://doi.org/10.1016/j.joule.2018.10.025Full Text
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Zhu, L. L., Huang, Y. E., Lin, Y. P., Huang, X. Y., Liu, H. Q., Mitzi, D. B., & Du, K. Z. (2019). Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron, 445–448. https://doi.org/10.1016/j.poly.2018.11.026Full Text
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Khazaee, M., Sardashti, K., Chung, C. C., Sun, J. P., Zhou, H., Bergmann, E., … Mitzi, D. B. (2019). Dual-source evaporation of silver bismuth iodide films for planar junction solar cells. Journal of Materials Chemistry A, 7(5), 2095–2105. https://doi.org/10.1039/c8ta08679fFull Text
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Li, T., Dunlap-Shohl, W. A., Reinheimer, E. W., Le Magueres, P., & Mitzi, D. B. (2019). Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching.. Chemical Science, 10(4), 1168–1175. https://doi.org/10.1039/c8sc03863eFull Text
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Dunlap-Shohl, W. A., Hill, I. G., Yan, Y., & Mitzi, D. B. (2018). Photovoltaic Effect in Indium(I) Iodide Thin Films. Chemistry of Materials, 30(22), 8226–8232. https://doi.org/10.1021/acs.chemmater.8b03593Full Text
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Ghadiri, E., Shin, D., Shafiee, A., Warren, W. S., & Mitzi, D. B. (2018). Grain-Resolved Ultrafast Photophysics in Cu2BaSnS4- xSe x Semiconductors Using Pump-Probe Diffuse Reflectance Spectroscopy and Microscopy.. Acs Applied Materials & Interfaces, 10(46), 39615–39623. https://doi.org/10.1021/acsami.8b12307Full Text
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Han, Q., Ding, J., Bai, Y., Li, T., Ma, J. Y., Chen, Y. X., … Hu, J. S. (2018). Carrier Dynamics Engineering for High-Performance Electron-Transport-Layer-free Perovskite Photovoltaics. Chem, 4(10), 2405–2417. https://doi.org/10.1016/j.chempr.2018.08.004Full Text Open Access Copy
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Liu, C., Huhn, W., Du, K.-Z., Vazquez-Mayagoitia, A., Dirkes, D., You, W., … Blum, V. (2018). Tunable Semiconductors: Control over Carrier States and Excitations in Layered Hybrid Organic-Inorganic Perovskites.. Physical Review Letters, 121(14). https://doi.org/10.1103/physrevlett.121.146401Full Text
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Wessler, G. C., Zhu, T., Sun, J. P., Harrell, A., Huhn, W. P., Blum, V., & Mitzi, D. B. (2018). Band Gap Tailoring and Structure-Composition Relationship within the Alloyed Semiconductor Cu 2 BaGe 1- x Sn x Se 4. Chemistry of Materials, 30(18), 6566–6574. https://doi.org/10.1021/acs.chemmater.8b03380Full Text
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Teymur, B., Zhou, Y., Ngaboyamahina, E., Glass, J. T., & Mitzi, D. B. (2018). Solution-Processed Earth-Abundant Cu2BaSn(S,Se)4 Solar Absorber Using a Low-Toxicity Solvent. Chemistry of Materials, 30(17), 6116–6123. https://doi.org/10.1021/acs.chemmater.8b02556Full Text
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Li, T., Wang, X., Yan, Y., & Mitzi, D. B. (2018). Phase Stability and Electronic Structure of Prospective Sb-Based Mixed Sulfide and Iodide 3D Perovskite (CH3NH3)SbSI2.. The Journal of Physical Chemistry Letters, 9(14), 3829–3833. https://doi.org/10.1021/acs.jpclett.8b01641Full Text
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Khazaee, M., Sardashti, K., Sun, J. P., Zhou, H., Clegg, C., Hill, I. G., … Mitzi, D. B. (2018). A Versatile Thin-Film Deposition Method for Multidimensional Semiconducting Bismuth Halides. Chemistry of Materials, 30(10), 3538–3544. https://doi.org/10.1021/acs.chemmater.8b01341Full Text
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Dunlap-Shohl, W. A., Barraza, E. T., Barrette, A., Gundogdu, K., Stiff-Roberts, A. D., & Mitzi, D. B. (2018). MAPbI3 Solar Cells with Absorber Deposited by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. Acs Energy Letters, 3(2), 270–275. https://doi.org/10.1021/acsenergylett.7b01144Full Text
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Barraza, E. T., Dunlap-Shohl, W. A., Mitzi, D. B., & Stiff-Roberts, A. D. (2018). Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. Journal of Electronic Materials, 47(2), 917–926. https://doi.org/10.1007/s11664-017-5814-0Full Text
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Zhou, Y., Shin, D., Ngaboyamahina, E., Han, Q., Parker, C. B., Mitzi, D. B., & Glass, J. T. (2018). Efficient and Stable Pt/TiO2/CdS/Cu2BaSn(S,Se)4 Photocathode for Water Electrolysis Applications. Acs Energy Letters, 3(1), 177–183. https://doi.org/10.1021/acsenergylett.7b01062Full Text
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Dunlap-Shohl, W. A., Daunis, T. B., Wang, X., Wang, J., Zhang, B., Barrera, D., … Mitzi, D. B. (2018). Room-temperature fabrication of a delafossite CuCrO2 hole transport layer for perovskite solar cells. Journal of Materials Chemistry A, 6(2), 469–477. https://doi.org/10.1039/c7ta09494aFull Text
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Liu, J., Han, Q., Bai, Y., Du, K. Z., Li, T., Ji, D., … Mitzi, D. B. (2017). Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes. Energy and Environmental Science, 10(11), 2365–2371. https://doi.org/10.1039/c7ee02272gFull Text
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Du, K. Z., Wang, X., Han, Q., Yan, Y., & Mitzi, D. B. (2017). Heterovalent B-Site Co-Alloying Approach for Halide Perovskite Bandgap Engineering. Acs Energy Letters, 2(10), 2486–2490. https://doi.org/10.1021/acsenergylett.7b00824Full Text
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Zhu, T., Huhn, W. P., Wessler, G. C., Shin, D., Saparov, B., Mitzi, D. B., & Blum, V. (2017). I2-II-IV-VI4 (I = Cu, Ag; II = Sr, Ba; IV = Ge, Sn; VI = S, Se): Chalcogenides for Thin-Film Photovoltaics. Chemistry of Materials, 29(18), 7868–7879. https://doi.org/10.1021/acs.chemmater.7b02638Full Text
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Xiao, Z., Du, K.-Z., Meng, W., Mitzi, D. B., & Yan, Y. (2017). Chemical Origin of the Stability Difference between Copper(I)- and Silver(I)-Based Halide Double Perovskites.. Angewandte Chemie (International Ed. in English), 56(40), 12107–12111. https://doi.org/10.1002/anie.201705113Full Text
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Li, T., Dunlap-Shohl, W. A., Han, Q., & Mitzi, D. B. (2017). Melt Processing of Hybrid Organic-Inorganic Lead Iodide Layered Perovskites. Chemistry of Materials, 29(15), 6200–6204. https://doi.org/10.1021/acs.chemmater.7b02363Full Text
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Du, K.-Z., Tu, Q., Zhang, X., Han, Q., Liu, J., Zauscher, S., & Mitzi, D. B. (2017). Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity.. Inorganic Chemistry, 56(15), 9291–9302. https://doi.org/10.1021/acs.inorgchem.7b01094Full Text
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Du, K.-Z., Meng, W., Wang, X., Yan, Y., & Mitzi, D. B. (2017). Bandgap Engineering of Lead-Free Double Perovskite Cs2 AgBiBr6 through Trivalent Metal Alloying.. Angewandte Chemie (International Ed. in English), 56(28), 8158–8162. https://doi.org/10.1002/anie.201703970Full Text
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Meng, W., Wang, X., Xiao, Z., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Parity-Forbidden Transitions and Their Impact on the Optical Absorption Properties of Lead-Free Metal Halide Perovskites and Double Perovskites.. The Journal of Physical Chemistry Letters, 8(13), 2999–3007. https://doi.org/10.1021/acs.jpclett.7b01042Full Text
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Xiao, Z., Du, K.-Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Correction to "Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study".. Journal of the American Chemical Society, 139(27). https://doi.org/10.1021/jacs.7b06199Full Text
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Shin, D., Saparov, B., & Mitzi, D. B. (2017). Defect Engineering in Multinary Earth-Abundant Chalcogenide Photovoltaic Materials. Advanced Energy Materials, 7(11). https://doi.org/10.1002/aenm.201602366Full Text
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Shin, D., Zhu, T., Huang, X., Gunawan, O., Blum, V., & Mitzi, D. B. (2017). Earth-Abundant Chalcogenide Photovoltaic Devices with over 5% Efficiency Based on a Cu2 BaSn(S,Se)4 Absorber.. Advanced Materials (Deerfield Beach, Fla.), 29(24). https://doi.org/10.1002/adma.201606945Full Text
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Xiao, Z., Du, K.-Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study.. Journal of the American Chemical Society, 139(17), 6054–6057. https://doi.org/10.1021/jacs.7b02227Full Text
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Wallace, S. K., Mitzi, D. B., & Walsh, A. (2017). The steady rise of kesterite solar cells. Acs Energy Letters, 2(4), 776–779. https://doi.org/10.1021/acsenergylett.7b00131Full Text
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Xiao, Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Searching for promising new perovskite-based photovoltaic absorbers: The importance of electronic dimensionality. Materials Horizons, 4(2), 206–216. https://doi.org/10.1039/c6mh00519eFull Text
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Younts, R., Duan, H.-S., Gautam, B., Saparov, B., Liu, J., Mongin, C., … Gundogdu, K. (2017). Efficient Generation of Long-Lived Triplet Excitons in 2D Hybrid Perovskite.. Advanced Materials (Deerfield Beach, Fla.), 29(9). https://doi.org/10.1002/adma.201604278Full Text
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Shin, D., Ngaboyamahina, E., Zhou, Y., Glass, J. T., & Mitzi, D. B. (2016). Synthesis and Characterization of an Earth-Abundant Cu2BaSn(S,Se)4 Chalcogenide for Photoelectrochemical Cell Application.. The Journal of Physical Chemistry Letters, 7(22), 4554–4561. https://doi.org/10.1021/acs.jpclett.6b02010Full Text
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Xiao, Z., Meng, W., Mitzi, D. B., & Yan, Y. (2016). Crystal Structure of AgBi2I7 Thin Films.. The Journal of Physical Chemistry Letters, 7(19), 3903–3907. https://doi.org/10.1021/acs.jpclett.6b01834Full Text
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Chagarov, E., Sardashti, K., Haight, R., Mitzi, D. B., & Kummel, A. C. (2016). Density-functional theory computer simulations of CZTS0.25Se0.75 alloy phase diagrams. Journal of Chemical Physics, 145(6). https://doi.org/10.1063/1.4959591Full Text
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Dunlap-Shohl, W. A., Younts, R., Gautam, B., Gundogdu, K., & Mitzi, D. B. (2016). Effects of cd diffusion and doping in high-performance perovskite solar cells using CdS as electron transport layer. Journal of Physical Chemistry C, 120(30), 16437–16445. https://doi.org/10.1021/acs.jpcc.6b05406Full Text
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Shin, D., Saparov, B., Zhu, T., Huhn, W. P., Blum, V., & Mitzi, D. B. (2016). BaCu 2 Sn(S,Se) 4 : Earth-abundant chalcogenides for thin-film photovoltaics. Chemistry of Materials, 28(13), 4771–4780. https://doi.org/10.1021/acs.chemmater.6b01832Full Text
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Ke, W., Xiao, C., Wang, C., Saparov, B., Duan, H.-S., Zhao, D., … Yan, Y. (2016). Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells.. Advanced Materials (Deerfield Beach, Fla.), 28(26), 5214–5221. https://doi.org/10.1002/adma.201600594Full Text
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Liu, X., Feng, Y., Cui, H., Liu, F., Hao, X., Conibeer, G., … Green, M. (2016). The current status and future prospects of kesterite solar cells: A brief review. Progress in Photovoltaics: Research and Applications, 24(6), 879–898. https://doi.org/10.1002/pip.2741Full Text
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Saparov, B., Sun, J. P., Meng, W., Xiao, Z., Duan, H. S., Gunawan, O., … Mitzi, D. B. (2016). Thin-Film Deposition and Characterization of a Sn-Deficient Perovskite Derivative Cs2SnI6. Chemistry of Materials, 28(7), 2315–2322. https://doi.org/10.1021/acs.chemmater.6b00433Full Text
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Saparov, B., & Mitzi, D. B. (2016). Organic-Inorganic Perovskites: Structural Versatility for Functional Materials Design.. Chemical Reviews, 116(7), 4558–4596. https://doi.org/10.1021/acs.chemrev.5b00715Full Text
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Xiao, Z., Meng, W., Saparov, B., Duan, H.-S., Wang, C., Feng, C., … Yan, Y. (2016). Photovoltaic Properties of Two-Dimensional (CH3NH3)2Pb(SCN)2I2 Perovskite: A Combined Experimental and Density Functional Theory Study.. The Journal of Physical Chemistry Letters, 7(7), 1213–1218. https://doi.org/10.1021/acs.jpclett.6b00248Full Text
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Hong, F., Saparov, B., Meng, W., Xiao, Z., Mitzi, D. B., & Yan, Y. (2016). Viability of Lead-Free Perovskites with Mixed Chalcogen and Halogen Anions for Photovoltaic Applications. Journal of Physical Chemistry C, 120(12), 6435–6441. https://doi.org/10.1021/acs.jpcc.6b00920Full Text
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Meng, W., Saparov, B., Hong, F., Wang, J., Mitzi, D. B., & Yan, Y. (2016). Alloying and Defect Control within Chalcogenide Perovskites for Optimized Photovoltaic Application. Chemistry of Materials, 28(3), 821–829. https://doi.org/10.1021/acs.chemmater.5b04213Full Text
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Tai, K. F., Gunawan, O., Kuwahara, M., Chen, S., Mhaisalkar, S. G., Huan, C. H. A., & Mitzi, D. B. (2016). Fill Factor Losses in Cu2ZnSn(SxSe1-x)4 Solar Cells: Insights from Physical and Electrical Characterization of Devices and Exfoliated Films. Advanced Energy Materials, 6(3). https://doi.org/10.1002/aenm.201501609Full Text
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Berry, J., Buonassisi, T., Egger, D. A., Hodes, G., Kronik, L., Loo, Y.-L., … Cahen, D. (2015). Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges.. Advanced Materials (Deerfield Beach, Fla.), 27(35), 5102–5112. https://doi.org/10.1002/adma.201502294Full Text
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Saparov, B., Hong, F., Sun, J. P., Duan, H. S., Meng, W., Cameron, S., … Mitzi, D. B. (2015). Thin-Film Preparation and Characterization of Cs3Sb2I9: A Lead-Free Layered Perovskite Semiconductor. Chemistry of Materials, 27(16), 5622–5632. https://doi.org/10.1021/acs.chemmater.5b01989Full Text
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Loo, L., & Patel, P. (2015). Perovskite photovoltaics: David Mitzi addresses the promises and challenges. Mrs Bulletin, 40(8), 636–637. https://doi.org/10.1557/mrs.2015.176Full Text
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Abou-Ras, D., Edoff, M., Minemoto, T., Mitzi, D., & Romeo, A. (2015). Preface. Thin Solid Films, 582. https://doi.org/10.1016/j.tsf.2015.01.001Full Text
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Bishop, D. M., McCandless, B. E., Haight, R., Mitzi, D. B., & Birkmire, R. W. (2015). Fabrication and electronic properties of CZTSe single crystals. Ieee Journal of Photovoltaics, 5(1), 390–394. https://doi.org/10.1109/JPHOTOV.2014.2363552Full Text
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Gershon, T., Shin, B., Bojarczuk, N., Hopstaken, M., Mitzi, D. B., & Guha, S. (2015). The role of sodium as a surfactant and suppressor of non-radiative recombination at internal surfaces in Cu2ZnSnS4. Advanced Energy Materials, 5(2). https://doi.org/10.1002/aenm.201400849Full Text
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Sardashti, K., Haight, R., Gokmen, T., Wang, W., Chang, L. Y., Mitzi, D. B., & Kummel, A. C. (2015). Impact of nanoscale elemental distribution in high-performance kesterite solar cells. Advanced Energy Materials, 5(10). https://doi.org/10.1002/aenm.201402180Full Text
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Park, H. H., Jayaraman, A., Heasley, R., Yang, C., Hartle, L., Mankad, R., … Gordon, R. G. (2014). Atomic layer deposition of Al-incorporated Zn(O,S) thin films with tunable electrical properties. Applied Physics Letters, 105(20). https://doi.org/10.1063/1.4901899Full Text
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Kim, J., Hiroi, H., Todorov, T. K., Gunawan, O., Kuwahara, M., Gokmen, T., … Mitzi, D. B. (2014). High efficiency Cu2ZnSn(S,Se)4 solar cells by applying a double In2S3/CdS emitter.. Advanced Materials (Deerfield Beach, Fla.), 26(44), 7427–7431. https://doi.org/10.1002/adma.201402373Full Text
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Kim, J., Hiroi, H., Todorov, T. K., Gunawan, O., Kuwahara, M., Gokmen, T., … Mitzi, D. B. (2014). Solar Cells: High Efficiency Cu2 ZnSn(S,Se)4 Solar Cells by Applying a Double In2 S3 /CdS Emitter (Adv. Mater. 44/2014).. Advanced Materials (Deerfield Beach, Fla.), 26(44). https://doi.org/10.1002/adma.201470303Full Text
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Gokmen, T., Gunawan, O., & Mitzi, D. B. (2014). Semi-empirical device model for Cu2ZnSn(S,Se)4 solar cells. Applied Physics Letters, 105(3). https://doi.org/10.1063/1.4890844Full Text
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Wang, W., Winkler, M. T., Gunawan, O., Gokmen, T., Todorov, T. K., Zhu, Y., & Mitzi, D. B. (2014). Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency. Advanced Energy Materials, 4(7). https://doi.org/10.1002/aenm.201301465Full Text
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Winkler, M. T., Wang, W., Gunawan, O., Hovel, H. J., Todorov, T. K., & Mitzi, D. B. (2014). Optical designs that improve the efficiency of Cu2ZnSn(S,Se) 4 solar cells. Energy and Environmental Science, 7(3), 1029–1036. https://doi.org/10.1039/c3ee42541jFull Text
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Haight, R., Shao, X., Wang, W., & Mitzi, D. B. (2014). Electronic and elemental properties of the Cu2ZnSn(S,Se)4surface and grain boundaries. Applied Physics Letters, 104(3). https://doi.org/10.1063/1.4862791Full Text
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Gunawan, O., Gokmen, T., & Mitzi, D. B. (2014). Suns- VOC characteristics of high performance kesterite solar cells. Journal of Applied Physics, 116(8). https://doi.org/10.1063/1.4893315Full Text Open Access Copy
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Haight, R., Barkhouse, A., Wang, W., Luo, Y., Shao, X., Mitzi, D. B., … Sugimoto, H. (2014). CdS and Cd-free buffer layers on solution phase grown Cu 2ZnSn(SxSe1- x)4 :Band alignments and electronic structure determined with femtosecond ultraviolet photoelectron spectroscopy. Materials Research Society Symposium Proceedings, 1638. https://doi.org/10.1557/opl.2014.196Full Text
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Hiroi, H., Kim, J., Kuwahara, M., Todorov, T. K., Nair, D., Hopstaken, M., … Sugimoto, H. (2014). Over 12% efficiency Cu 2 ZnSn(SeS) 4 solar cell via hybrid buffer layer. 2014 Ieee 40th Photovoltaic Specialist Conference, Pvsc 2014, 30–32. https://doi.org/10.1109/PVSC.2014.6925044Full Text
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Patel, P., & Mitzi, D. (2014). Perovskites in the spotlight. Mrs Bulletin, 39(9), 768–769. https://doi.org/10.1557/mrs.2014.200Full Text
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Todorov, T., Sugimoto, H., Gunawan, O., Gokmen, T., & Mitzi, D. B. (2014). High-efficiency devices with pure solution-processed Cu2 ZnSn(S,Se)4 Absorbers. Ieee Journal of Photovoltaics, 4(1), 483–485. https://doi.org/10.1109/JPHOTOV.2013.2287754Full Text
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Polizzotti, A., Repins, I. L., Noufi, R., Wei, S. H., & Mitzi, D. B. (2013). The state and future prospects of kesterite photovoltaics. Energy and Environmental Science, 6(11), 3171–3182. https://doi.org/10.1039/c3ee41781fFull Text
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Gokmen, T., Gunawan, O., & Mitzi, D. B. (2013). Minority carrier diffusion length extraction in Cu2ZnSn(Se,S) 4 solar cells. Journal of Applied Physics, 114(11). https://doi.org/10.1063/1.4821841Full Text
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Gokmen, T., Gunawan, O., Todorov, T. K., & Mitzi, D. B. (2013). Band tailing and efficiency limitation in kesterite solar cells. Applied Physics Letters, 103(10). https://doi.org/10.1063/1.4820250Full Text
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Mitzi, D. B., Gunawan, O., Todorov, T. K., & Barkhouse, D. A. R. (2013). Prospects and performance limitations for Cu-Zn-Sn-S-Se photovoltaic technology.. Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences, 371(1996). https://doi.org/10.1098/rsta.2011.0432Full Text
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Todorov, T. K., Gunawan, O., Gokmen, T., & Mitzi, D. B. (2013). Solution-processed Cu(In,Ga)(S,Se)2 absorber yielding a 15.2% efficient solar cell. Progress in Photovoltaics: Research and Applications, 21(1), 82–87. https://doi.org/10.1002/pip.1253Full Text
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Todorov, T. K., Tang, J., Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., & Mitzi, D. B. (2013). Beyond 11% effi ciency: Characteristics of state-of-the-art Cu 2ZnSn(S,Se)4Solar Cells. Advanced Energy Materials, 3(1), 34–38. https://doi.org/10.1002/aenm.201200348Full Text
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Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., & Mitzi, D. B. (2012). Hydrazine-processed Ge-substituted CZTSe solar cells. Chemistry of Materials, 24(23), 4588–4593. https://doi.org/10.1021/cm302881gFull Text
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Miller, D. W., Warren, C. W., Gunawan, O., Gokmen, T., Mitzi, D. B., & Cohen, J. D. (2012). Electronically active defects in the Cu 2ZnSn(Se,S) 4 alloys as revealed by transient photocapacitance spectroscopy. Applied Physics Letters, 101(14). https://doi.org/10.1063/1.4754834Full Text
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Graetzel, M., Janssen, R. A. J., Mitzi, D. B., & Sargent, E. H. (2012). Materials interface engineering for solution-processed photovoltaics.. Nature, 488(7411), 304–312. https://doi.org/10.1038/nature11476Full Text
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Gunawan, O., Gokmen, T., Warren, C. W., Cohen, J. D., Todorov, T. K., Barkhouse, D. A. R., … Mitzi, D. B. (2012). Electronic properties of the Cu 2ZnSn(Se,S) 4 absorber layer in solar cells as revealed by admittance spectroscopy and related methods. Applied Physics Letters, 100(25). https://doi.org/10.1063/1.4729751Full Text
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Barkhouse, D. A. R., Haight, R., Sakai, N., Hiroi, H., Sugimoto, H., & Mitzi, D. B. (2012). Cd-free buffer layer materials on Cu 2ZnSn(S xSe 1-x) 4: Band alignments with ZnO, ZnS, and In 2S 3. Applied Physics Letters, 100(19). https://doi.org/10.1063/1.4714737Full Text
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Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., Todorov, T. K., & Mitzi, D. B. (2012). Low band gap liquid-processed CZTSe solar cell with 10.1% efficiency. Energy and Environmental Science, 5(5), 7060–7065. https://doi.org/10.1039/c2ee00056cFull Text
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Barkhouse, D. A. R., Gunawan, O., Gokmen, T., Todorov, T. K., & Mitzi, D. B. (2012). Device characteristics of a 10.1% hydrazine-processed Cu 2ZnSn(Se,S) 4 solar cell. Progress in Photovoltaics: Research and Applications, 20(1), 6–11. https://doi.org/10.1002/pip.1160Full Text
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Shin, B., Wang, K., Gunawan, O., Reuter, K. B., Chey, S. J., Bojarczuk, N. A., … Guha, S. (2011). High efficiency Cu 2ZnSn(S xSe 1-x) 4 thin film solar cells by thermal co-evaporation. Conference Record of the Ieee Photovoltaic Specialists Conference, 002510–002514. https://doi.org/10.1109/PVSC.2011.6186456Full Text
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Li, J., Mitzi, D. B., & Shenoy, V. B. (2011). Structure and electronic properties of grain boundaries in earth-abundant photovoltaic absorber Cu2ZnSnSe4.. Acs Nano, 5(11), 8613–8619. https://doi.org/10.1021/nn203230gFull Text
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Cao, Q., Gunawan, O., Copel, M., Reuter, K. B., Chey, S. J., Deline, V. R., & Mitzi, D. B. (2011). Defects in Cu(In,Ga)Se 2 chalcopyrite semiconductors: A comparative study of material properties, defect states, and photovoltaic performance. Advanced Energy Materials, 1(5), 845–853. https://doi.org/10.1002/aenm.201100344Full Text
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Todorov, T., Gunawan, O., Chey, S. J., De Monsabert, T. G., Prabhakar, A., & Mitzi, D. B. (2011). Progress towards marketable earth-abundant chalcogenide solar cells. Thin Solid Films, 519(21), 7378–7381. https://doi.org/10.1016/j.tsf.2010.12.225Full Text
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Haight, R., Barkhouse, A., Gunawan, O., Shin, B., Copel, M., Hopstaken, M., & Mitzi, D. B. (2011). Band alignment at the Cu2 ZnSn (SxSe1-x) 4 /CdS interface. Applied Physics Letters, 98(25). https://doi.org/10.1063/1.3600776Full Text
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Mitzi, D. B., Gunawan, O., Todorov, T. K., Wang, K., & Guha, S. (2011). The path towards a high-performance solution-processed kesterite solar cell. Solar Energy Materials and Solar Cells, 95(6), 1421–1436. https://doi.org/10.1016/j.solmat.2010.11.028Full Text
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Wang, K., Shin, B., Reuter, K. B., Todorov, T., Mitzi, D. B., & Guha, S. (2011). Structural and elemental characterization of high efficiency Cu2ZnSnS4solar cells. Applied Physics Letters, 98(5). https://doi.org/10.1063/1.3543621Full Text
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Gunawan, O., Todorov, T. K., & Mitzi, D. B. (2010). Loss mechanisms in hydrazine-processed Cu2 ZnSn (Se,S) 4 solar cells. Applied Physics Letters, 97(23). https://doi.org/10.1063/1.3522884Full Text
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Yuan, M., Mitzi, D. B., Gunawan, O., Kellock, A. J., Chey, S. J., & Deline, V. R. (2010). Antimony assisted low-temperature processing of CuIn1 - XGa xSe2 - ySy solar cells. Thin Solid Films, 519(2), 852–856. https://doi.org/10.1016/j.tsf.2010.08.135Full Text
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Wang, K., Gunawan, O., Todorov, T., Shin, B., Chey, S. J., Bojarczuk, N. A., … Guha, S. (2010). Thermally evaporated Cu2ZnSnS4solar cells. Applied Physics Letters, 97(14). https://doi.org/10.1063/1.3499284Full Text
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Hibberd, C. J., Chassaing, E., Liu, W., Mitzi, D. B., Lincot, D., & Tiwari, A. N. (2010). Non-vacuum methods for formation of Cu(In, Ga)(Se, S) 2 thin film photovoltaic absorbers. Progress in Photovoltaics: Research and Applications, 18(6), 434–452. https://doi.org/10.1002/pip.914Full Text
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Mitzi, D. (2010). Plain-as-dirt solar cell may lower material costs. Laser Focus World, 46(5), 9–9.Link to Item
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Todorov, T. K., Reuter, K. B., & Mitzi, D. B. (2010). High-efficiency solar cell with Earth-abundant liquid-processed absorber.. Advanced Materials (Deerfield Beach, Fla.), 22(20), E156–E159. https://doi.org/10.1002/adma.200904155Full Text
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Liu, W., Mitzi, D. B., Yuan, M., Kellock, A. J., Jay Chey, S., & Gunawan, O. (2010). 12% Efficiency CuIn(Se,S)2 photovoltaic device prepared using a hydrazine solution process. Chemistry of Materials, 22(3), 1010–1014. https://doi.org/10.1021/cm901950qFull Text
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Yuan, M., Mitzi, D. B., Liu, W., Kellock, A. J., Jay Chey, S., & Deline, V. R. (2010). Optimization of CIGS-based PV device through antimony doping. Chemistry of Materials, 22(2), 285–287. https://doi.org/10.1021/cm903428fFull Text
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Todorov, T., & Mitzi, D. B. (2010). Direct liquid coating of chalcopyrite light-absorbing layers for photovoltaic devices. European Journal of Inorganic Chemistry, (1), 17–28. https://doi.org/10.1002/ejic.200900837Full Text
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Jay Chey, S., Liu, W., Yuan, M., & Mitzi, D. B. (2009). Characterization of indium tin oxide and al-doped zinc oxide thin films deposited by confocal RF magnetron sputter deposition. Conference Record of the Ieee Photovoltaic Specialists Conference, 001149–001153. https://doi.org/10.1109/PVSC.2009.5411222Full Text
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Mitzi, D. B. (2009). Solution processing of chalcogenide semiconductors via dimensional reduction. Advanced Materials, 21(31), 3141–3158. https://doi.org/10.1002/adma.200802027Full Text
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Yuan, M., & Mitzi, D. B. (2009). Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films.. Dalton Transactions (Cambridge, England : 2003), (31), 6078–6088. https://doi.org/10.1039/b900617fFull Text
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Mitzi, D. B. (2009). PHYS 485-Solution processing of CIGS absorber layers using a hydrazine-based approach. Abstracts of Papers of the American Chemical Society, 237.Link to Item
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Mitzi, D. B., Yuan, M., Liu, W., Kellock, A. J., Jay Chey, S., Deline, V., & Schrott, A. G. (2008). A high-efficiency solution-deposited thin-film photovoltaic device. Advanced Materials, 20(19), 3657–3662. https://doi.org/10.1002/adma.200800555Full Text
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Mitzi, D. B. (2008). Solution Processing of Inorganic Materials. Solution Processing of Inorganic Materials, 1–497. https://doi.org/10.1002/9780470407790Full Text
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Mitzi, D. B. (2008). Solution Processing of Chalcogenide Semiconductors via Dimensional Reduction, 77–108. https://doi.org/10.1002/9780470407790.ch3Full Text
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Tromp, R. M., Afzali, A., Freitag, M., Mitzi, D. B., & Chen, Z. (2008). Novel strategy for diameter-selective separation and functionalization of single-wall carbon nanotubes.. Nano Letters, 8(2), 469–472. https://doi.org/10.1021/nl072437bFull Text
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Kanatzidis, M. G., Poeppelmeier, K. R., Bobev, S., Guloy, A. M., Hwu, S. J., Lachgar, A., … Seshadri, R. (2008). Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences. Progress in Solid State Chemistry, 36(1–2), 1–133. https://doi.org/10.1016/j.progsolidstchem.2007.02.002Full Text
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Mitzi, D. B., & Afzali, A. (2007). Diels-alder adduct of pentacene and maleimide: Crystal growth and the influence of solvent molecules on structure and hydrogen bonding. Crystal Growth and Design, 7(4), 691–697. https://doi.org/10.1021/cg060559wFull Text
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Mitzi, D. B. (2007). N4H9Cu7S4: a hydrazinium-based salt with a layered Cu7S4- framework.. Inorganic Chemistry, 46(3), 926–931. https://doi.org/10.1021/ic0621291Full Text
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Mitzi, D. B. (2007). Synthesis, structure, and properties of organic-inorganic perovskites and related materials, 48, 1–121. https://doi.org/10.1002/9780470166499.ch1Full Text
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Mitzi, D. B., Raoux, S., Schrott, A. G., Copel, M., Kellock, A., & Jordan-Sweet, J. (2006). Solution-based processing of the phase-change material KSb 5S8. Chemistry of Materials, 18(26), 6278–6282. https://doi.org/10.1021/cm0619510Full Text
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Mitzi, D. B., Copel, M., & Murray, C. E. (2006). High-mobility p-type transistor based on a spin-coated metal telluride semiconductor. Advanced Materials, 18(18), 2448–2452. https://doi.org/10.1002/adma.200600157Full Text
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Milliron, D. J., Mitzi, D. B., Copel, M., & Murray, C. E. (2006). Solution-processed metal chalcogenide films for p-type transistors. Chemistry of Materials, 18(3), 581–590. https://doi.org/10.1021/cm052300rFull Text
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Mitzi, D. B., Copel, M., Murray, C. E., Kosbar, L. L., & Afzali, A. (2005). Thin-film transistors based on spin-coated chalcogenide semiconductor channels. Proceedings Electrochemical Society, PV 2004-15, 189–199.
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Mitzi, D. B. (2005). Polymorphic one-dimensional (N2H4)2ZnTe: soluble precursors for the formation of hexagonal or cubic zinc telluride.. Inorganic Chemistry, 44(20), 7078–7086. https://doi.org/10.1021/ic050833wFull Text
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Knutson, J. L., Martin, J. D., & Mitzi, D. B. (2005). Tuning the band gap in hybrid tin iodide perovskite semiconductors using structural templating.. Inorganic Chemistry, 44(13), 4699–4705. https://doi.org/10.1021/ic050244qFull Text
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Mitzi, D. B. (2005). Synthesis, structure, and thermal properties of soluble hydrazinium germanium(IV) and tin(IV) selenide salts. Inorganic Chemistry, 44(10), 3755–3761. https://doi.org/10.1021/ic0482761Full Text Link to Item
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Mitzi, D. B., Copel, M., & Chey, S. J. (2005). Low-voltage transistor employing a high-mobility spin-coated chalcogenide semiconductor. Advanced Materials, 17(10), 1285–1289. https://doi.org/10.1002/adma.200401443Full Text
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Mitzi, D. B. (2005). Synthesis, structure, and thermal properties of soluble hydrazinium germanium(IV) and tin(IV) selenide salts.. Inorganic Chemistry, 44(10), 3755–3761. https://doi.org/10.1021/ic048276lFull Text
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Mitzi, D., Copel, M., & Chey, S. J. (2005). Standing up to be counted. Iii Vs Review, 18(6), 38–39. https://doi.org/10.1016/S0961-1290(05)71232-1Full Text
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Mitzi, D. B. (2004). Solution-processed inorganic semiconductors. Journal of Materials Chemistry, 14(15), 2355–2365. https://doi.org/10.1039/b403482aFull Text
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Mitzi, D. B., Kosbar, L. L., Murray, C. E., Copel, M., & Afzali, A. (2004). High-mobility ultrathin semiconducting films prepared by spin coating.. Nature, 428(6980), 299–303. https://doi.org/10.1038/nature02389Full Text
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Xu, Z., & Mitzi, D. B. (2003). [CH(3)(CH(2))(11)NH(3)]SnI(3): a hybrid semiconductor with MoO(3)-type tin(II) iodide layers.. Inorganic Chemistry, 42(21), 6589–6591. https://doi.org/10.1021/ic0347081Full Text
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Xu, Z. T., & Mitzi, D. B. (2003). SnI42--based hybrid perovskites templated by multiple organic cations: Combining organic functionalities through noncovalent interactions. Chemistry of Materials, 15(19), 3632–3637. https://doi.org/10.1021/cm034267jFull Text Link to Item
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Maxcy, K. R., Willett, R. D., Mitzi, D. B., & Afzali, A. (2003). Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online, 59(6). https://doi.org/10.1107/S1600536803007414Full Text
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Xu, Z., Mitzi, D. B., & Medeiros, D. R. (2003). [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.. Inorganic Chemistry, 42(5), 1400–1402. https://doi.org/10.1021/ic0261981Full Text
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Xu, Z., Mitzi, D. B., Dimitrakopoulos, C. D., & Maxcy, K. R. (2003). Semiconducting perovskites (2-XC6H4C2H4NH3)2SnI4 (X = F, Cl, Br): steric interaction between the organic and inorganic layers.. Inorganic Chemistry, 42(6), 2031–2039. https://doi.org/10.1021/ic0261474Full Text
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Lee, Y., Mitzi, D. B., Barnes, P. W., & Vogt, T. (2003). Pressure-induced phase transitions and templating effect in three-dimensional organic-inorganic hybrid perovskites. Physical Review B Condensed Matter and Materials Physics, 68(2). https://doi.org/10.1103/PhysRevB.68.020103Full Text
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Mitzi, D. B., Dimitrakopoulos, C. D., Rosner, J., Medeiros, D. R., Xu, Z., & Noyan, C. (2002). Hybrid field-effect transistor based on a low-temperature melt-processed channel layer. Advanced Materials, 14(23), 1772–1776. https://doi.org/10.1002/1521-4095(20021203)14:23<1772::AID-ADMA1772>3.0.CO;2-YFull Text
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Mitzi, D. B., Medeiros, D. R., & DeHaven, P. W. (2002). Low-temperature melt processing of organic-inorganic hybrid films. Chemistry of Materials, 14(7), 2839–2841. https://doi.org/10.1021/cm020264fFull Text
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Kagan, C. R., Afzali, A., Breen, T. L., Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2002). Solution deposition and patterning of organic and organic-inorganic thin film transistors.. Abstracts of Papers of the American Chemical Society, 223, D73–D73.Link to Item
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Maxcy, K. R., Mitzi, D. B., Afzali, A., & Willett, R. D. (2002). Benzylammonium tin(II) iodide based perovskites.. Abstracts of Papers of the American Chemical Society, 223, A13–A13.Link to Item
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Maxey, K. R., Mitzi, D. B., Afzali, A., & Willett, R. (2002). Benzylammonium TiN(II) iodide based perovskites.. Abstracts of Papers of the American Chemical Society, 223, U656–U656.Link to Item
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Mitzi, D. B., Medeiros, D. R., Dimitrakopoulos, C. D., Malenfant, P. R. L., Kosbar, L. L., Xu, Z. T., & DeHaven, P. W. (2002). Organic-inorganic perovskite semiconductors: Chemistry, properties, and device applications.. Abstracts of Papers of the American Chemical Society, 223, C23–C23.Link to Item
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Mitzi, D. B., Medeiros, D. R., & Malenfant, P. R. L. (2002). Intercalated organic-inorganic perovskites stabilized by fluoroaryl-aryl interactions.. Inorganic Chemistry, 41(8), 2134–2145. https://doi.org/10.1021/ic011190xFull Text
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Mitzi, D. B. (2001). Templating and structural engineering in organic-inorganic perovskites. Journal of the Chemical Society, Dalton Transactions, (1), 1–12. https://doi.org/10.1039/b007070jFull Text
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Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2001). Structurally tailored organic-inorganic perovskites: Optical properties and solution-processed channel materials for thin-film transistors. Chemistry of Materials, 13(10), 3728–3740. https://doi.org/10.1021/cm010105gFull Text
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Mitzi, D. B. (2001). Thin-film deposition of organic-inorganic hybrid materials. Chemistry of Materials, 13(10), 3283–3298. https://doi.org/10.1021/cm0101677Full Text
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Kagan, C. R., Mitzi, D. B., Dimitrakopoulos, C. D., Breen, T. L., Afzali, A., & Kosbar, L. L. (2001). Organic-inorganic thin-film field effect transistors.. Abstracts of Papers of the American Chemical Society, 221, U632–U632.Link to Item
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Kagan, C. R., Mitzi, D. B., Dimitrakopoulos, C. D., Breen, T. L., Afzali, A., & Kosbar, L. L. (2001). Organic-inorganic perovskites as semiconducting channels in thin film transistors.. Abstracts of Papers of the American Chemical Society, 221, U735–U735.Link to Item
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Maxcy, K. R., Willett, R., Afzali, A., & Mitzi, D. B. (2001). Thioxanthene lead perovskite structure and optical properties.. Abstracts of Papers of the American Chemical Society, 221, U657–U657.Link to Item
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Mitzi, D. B., & Brock, P. (2001). Structure and optical properties of several organic-inorganic hybrids containing corner-sharing chains of bismuth iodide octahedra.. Inorganic Chemistry, 40(9), 2096–2104. https://doi.org/10.1021/ic000622lFull Text
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Mitzi, D. B., Chondroudis, K., & Kagan, C. R. (2001). Organic-inorganic electronics.. Ibm Journal of Research and Development, 45, 29–46.
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Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2001). Organic-inorganic electronic devices based on hybrid perovskites. Annual Device Research Conference Digest, 185–186.
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Mitzi, D. B. (2000). Organic-inorganic perovskites containing trivalent metal halide layers: the templating influence of the organic cation layer.. Inorganic Chemistry, 39(26), 6107–6113. https://doi.org/10.1021/ic000794iFull Text
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Maxcy, K. R., Afzali, A., & Mitzi, D. B. (2000). Crystal growth of perovskites and chain compounds with complex organic cations.. Abstracts of Papers of the American Chemical Society, 219, U861–U861.Link to Item
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Chondroudis, K., & Mitzi, D. B. (2000). The use of ionic salt dyes as amorphous, thermally stable emitting layers in organic light-emitting diodes. Applied Physics Letters, 76(1), 58–60. https://doi.org/10.1063/1.125655Full Text
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Chondroudis, K., Mitzi, D. B., & Brock, P. (2000). Effect of thermal annealing on the optical and morphological properties of (AETH)PbX 4 (X = Br, I) perovskite films prepared using single source thermal ablation. Chemistry of Materials, 12(1), 169–175. https://doi.org/10.1021/cm990516lFull Text
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Mitzi, D. B., Chondroudis, K., & Kagan, C. R. (1999). Design, Structure, and Optical Properties of Organic-Inorganic Perovskites Containing an Oligothiophene Chromophore.. Inorganic Chemistry, 38(26), 6246–6256. https://doi.org/10.1021/ic991048kFull Text
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Kagan, C. R., Mitzi, D. B., & Dimitrakopoulos, C. D. (1999). Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science (New York, N.Y.), 286(5441), 945–947. https://doi.org/10.1126/science.286.5441.945Full Text
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Chondroudis, K., & Mitzi, D. B. (1999). Electroluminescence from an organic-inorganic perovskite incorporating a quaterthiophene dye within lead halide perovskite layers. Chemistry of Materials, 11(11), 3028–3030. https://doi.org/10.1021/cm990561tFull Text
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Mitzi, D. B. (1999). A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3) 2PbCl4. Journal of Solid State Chemistry, 145(2), 694–704.
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Mitzi, D. B. (1999). A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3) 2PbCl4. Journal of Solid State Chemistry, 145(2), 694–704. https://doi.org/10.1006/jssc.1999.8281Full Text
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Mitzi, D. B., Prikas, M. T., & Chondroudis, K. (1999). Thin film deposition of organic-inorganic hybrid materials using a single source thermal ablation technique. Chemistry of Materials, 11(3), 542–544. https://doi.org/10.1021/cm9811139Full Text
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Mitzi, D. B., Liang, K. N., & Wang, S. M. (1998). Synthesis and characterization of [NH2C(I)=NH2](2)ASnI(5) with A = iodoformamidinium or formamidinium: The chemistry of cyanamide and tin(II) iodide in concentrated aqueous hydriodic acid solutions. Inorganic Chemistry, 37(2), 321–327. https://doi.org/10.1021/ic971332gFull Text Link to Item
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Kossler, W. J., Dai, Y., Petzinger, K. G., Greer, A. J., Williams, D. L., Koster, E., … Mitzi, D. B. (1998). Transparency of the ab planes of Bi2Sr2CaCu2O8+δ to magnetic fields. Physical Review Letters, 80(3), 592–595.
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Kossler, W. J., Dai, Y., Petzinger, K. G., Greer, A. J., Williams, D. L., Koster, E., … Mitzi, D. B. (1998). Transparency of the ab Planes of Bi 2 Sr 2 CaCu 2 O 8+δ to magnetic fields. Physical Review Letters, 80(3), 592–595. https://doi.org/10.1103/PhysRevLett.80.592Full Text
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Liang, K., Mitzi, D. B., & Prikas, M. T. (1998). Synthesis and Characterization of Organic-Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique. Chemistry of Materials, 10(1), 403–411. https://doi.org/10.1021/cm970568fFull Text
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Mitzi, D. B., & Liang, K. (1997). Synthesis, Resistivity, and Thermal Properties of the Cubic Perovskite NH2CH=NH2SnI3and Related Systems. Journal of Solid State Chemistry, 134(2), 376–381. https://doi.org/10.1006/jssc.1997.7593Full Text
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Mitzi, D. B., & Liang, K. (1997). Preparation and Properties of (C4H9NH3)2EuI4: A Luminescent Organic-Inorganic Perovskite with a Divalent Rare-Earth Metal Halide Framework. Chemistry of Materials, 9(12), 2990–2995.
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Mitzi, D. B., & Liang, K. N. (1997). Preparation and properties of(C4H9NH3)(2)EUI4: A luminescent organic-inorganic perovskite with a divalent rare-earth metal halide framework. Chemistry of Materials, 9(12), 2990–2995. https://doi.org/10.1021/cm970352dFull Text Link to Item
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Koutselas, I. B., Mitzi, D. B., Papavassiliou, G. C., Papaioannou, G. J., & Krautscheid, H. (1997). Optical and related properties of natural one-dimensional semiconductors based on PbI and SnI units. Synthetic Metals, 86(1–3), 2171–2172.
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Wang, S. M., Mitzi, D. B., Landrum, G. A., Genin, H., & Hoffmann, R. (1997). Synthesis and solid state chemistry of CH3BiI2: A structure with an extended one-dimensional organometallic framework. Journal of the American Chemical Society, 119(4), 724–732. https://doi.org/10.1021/ja961753hFull Text Link to Item
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Mitzi, D. B., & Liang, K. (1997). Preparation and Properties of (C4H9NH3)2EuI4: A Luminescent Organic-Inorganic Perovskite with a Divalent Rare-Earth Metal Halide Framework. Chemistry of Materials, 9(12), 2990–2995.
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Mitzi, D. B. (1996). Synthesis and Crystal Structure of the Alkylbismuth Diiodides: A Family of Extended One-Dimensional Organometallic Compounds. Inorganic Chemistry, 35(26), 7614–7619.
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Mitzi, D. B., & Wang, S. M. (1996). Layered group IVB metal halide organic-inorganic perovskites. Abstracts of Papers of the American Chemical Society, 211, 86-INOR.Link to Item
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Mitzi, D. B. (1996). Synthesis, crystal structure, and optical and thermal properties of (C4H9NH3)(2)MI(4) (M=Ge, Sn, Pb). Chemistry of Materials, 8(3), 791–800. https://doi.org/10.1021/cm9505097Full Text Link to Item
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Chen, B. H., Walker, D., Scott, B. A., & Mitzi, D. B. (1996). Synthesis and structure of a new perovskite, SrCuO 2.5. Journal of Solid State Chemistry, 121(2), 498–501. https://doi.org/10.1006/jssc.1996.0070Full Text
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Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., & Guloy, A. M. (1995). Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets.. Science (New York, N.Y.), 267(5203), 1473–1476. https://doi.org/10.1126/science.267.5203.1473Full Text
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Mitzi, D. B., Feild, C. A., Schlesinger, Z., & Laibowitz, R. B. (1995). Transport, optical, and magnetic properties of the conducting halide perovskite ch3nh3sni3. Journal of Solid State Chemistry, 114(1), 159–163. https://doi.org/10.1006/jssc.1995.1023Full Text
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Wang, S., Guloy, A., Mitzi, D. B., & Feild, C. A. (1995). Synthesis and Characterization of [NH2C(I)=NH2]3MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single (110) Perovskite Sheets. Journal of the American Chemical Society, 117(19), 5297–5302. https://doi.org/10.1021/ja00124a012Full Text
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Scott, B. A., Suard, E. Y., Tsuei, C. C., Mitzi, D. B., McGuire, T. R., Chen, B. H., & Walker, D. (1994). Layer dependence of the superconducting transition temperature of HgBa2Can-1CunO2n+2+δ. Physica C: Superconductivity and Its Applications, 230(3–4), 239–245. https://doi.org/10.1016/0921-4534(94)90835-4Full Text
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Takigawa, M., & Mitzi, D. B. (1994). NMR studies of spin excitations in superconducting Bi2Sr2CaCu2O8+ delta single crystals.. Physical Review Letters, 73(9), 1287–1290. https://doi.org/10.1103/physrevlett.73.1287Full Text
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Tsuei, C. C., Gupta, A., Trafas, G., & Mitzi, D. (1994). Superconducting mercury-based cuprate films with a zero-resistance transition temperature of 124 Kelvin.. Science (New York, N.Y.), 263(5151), 1259–1261. https://doi.org/10.1126/science.263.5151.1259Full Text
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Mitzi, D. B., Feild, C. A., Harrison, W. T. A., & Guloy, A. M. (1994). Conducting tin halides with a layered organic-based perovskite structure. Nature, 369(6480), 467–469. https://doi.org/10.1038/369467a0Full Text
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Wu, X. D., Fanton, J. G., Kino, G. S., Ryu, S., Mitzi, D. B., & Kapitulnik, A. (1993). Thermal diffusivity of Bi2Sr2CaCu2O8 single crystals. Physica C: Superconductivity and Its Applications, 218(3–4), 417–423. https://doi.org/10.1016/0921-4534(93)90044-QFull Text
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Phelps, R. B., Akavoor, P., Kesmodel, L. L., Demuth, J. E., & Mitzi, D. B. (1993). Surface phonons on Bi2Sr2CaCu2O8+ delta.. Physical Review. B, Condensed Matter, 48(17), 12936–12940. https://doi.org/10.1103/physrevb.48.12936Full Text
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Arribére, A., Pastoriza, H., Goffman, M. F., de la Cruz F, Mitzi, D. B., & Kapitulnik, A. (1993). Loss of interplane correlation in Bi2Sr2CaCu2O8 single crystals.. Physical Review. B, Condensed Matter, 48(10), 7486–7491. https://doi.org/10.1103/physrevb.48.7486Full Text
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Harshman, D. R., Brandt, E. H., Fiory, A. T., Inui, M., Mitzi, D. B., Schneemeyer, L. F., & Waszczak, J. V. (1993). Longitudinal disordering of vortex lattices in anisotropic superconductors.. Physical Review. B, Condensed Matter, 47(5), 2905–2908. https://doi.org/10.1103/physrevb.47.2905Full Text
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Wells, B. O., Shen, Z. X., Dessau, D. S., Spicer, W. E., Mitzi, D. B., Lombardo, L., … Arko, A. J. (1992). Evidence for k-dependent, in-plane anisotropy of the superconducting gap in Bi2Sr2CaCu2O8+ delta.. Physical Review. B, Condensed Matter, 46(18), 11830–11834. https://doi.org/10.1103/physrevb.46.11830Full Text
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Borg, A., King, P. L., Pianetta, P., Lindau, I., Mitzi, D. B., Kapitulnik, A., … Bianconi, A. (1992). Ca 3d unoccupied states in Bi2Sr2CaCu2O8 investigated by Ca L2,3 x-ray-absorption near-edge structure.. Physical Review. B, Condensed Matter, 46(13), 8487–8495. https://doi.org/10.1103/physrevb.46.8487Full Text
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Pastoriza, H., de la Cruz F, Mitzi, D. B., & Kapitulnik, A. (1992). Two-step transition towards the reversibility region in Bi2Sr2CaCu2O8- delta single crystals.. Physical Review. B, Condensed Matter, 46(14), 9278–9281. https://doi.org/10.1103/physrevb.46.9278Full Text
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Lombardo, L. W., Mitzi, D. B., Kapitulnik, A., & Leone, A. (1992). Defect dependence of the irreversibility line in Bi2Sr2CaCu2O8 single crystals.. Physical Review. B, Condensed Matter, 46(9), 5615–5620. https://doi.org/10.1103/physrevb.46.5615Full Text
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Safar, H., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1992). SQUID picovoltometry of single crystal Bi2Sr2CaCu2O8+ delta : Observation of the crossover from high-temperature Arrhenius to low-temperature vortex-glass behavior.. Physical Review Letters, 68(17), 2672–2675. https://doi.org/10.1103/physrevlett.68.2672Full Text
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Dessau, D. S., Shen, Z., Wells, B. O., King, D. M., Spicer, W. E., Arko, A. J., … Kapitulnik, A. (1992). Nature of the high-binding-energy dip in the low-temperature photoemission spectra of Bi2Sr2CaCu2O8+ delta.. Physical Review. B, Condensed Matter, 45(9), 5095–5098. https://doi.org/10.1103/physrevb.45.5095Full Text
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Tsuei, C. C., Chi, C. C., Frey, T., Mitzi, D. B., Kazyaka, T., Haugan, T., … Wu, M. K. (1992). A jelly-roll process for high temperature superconducting tapes and wires. Materials Chemistry and Physics, 32(1), 95–98. https://doi.org/10.1016/0254-0584(92)90253-5Full Text
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Yazyi, J., Arribére, A., Durán, C., de la Cruz, F., Mitzi, D. B., & Kapitulnik, A. (1991). Inter- and intraplane softening of the vortex structure in Bi2.1Sr1.9Ca0.9Cu2O8+δ: a two-step transition. Physica C: Superconductivity and Its Applications, 184(4–6), 254–258. https://doi.org/10.1016/0921-4534(91)90390-KFull Text
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Dessau, D. S., Wells, B. O., Shen, Z. X., Spicer, W. E., Arko, A. J., List, R. S., … Geballe, T. H. (1991). Search for a proximity effect induced gap in gold/high Tc junctions. Applied Physics Letters, 58(12), 1332–1334. https://doi.org/10.1063/1.104301Full Text
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Shen, Z., Dessau, D. S., Wells, B. O., Olson, C. G., Mitzi, D. B., Lombado, L., … Arko, A. J. (1991). Evidence of chemical-potential shift with hole doping in Bi2Sr2CaCu2O8+ delta.. Physical Review. B, Condensed Matter, 44(21), 12098–12101. https://doi.org/10.1103/physrevb.44.12098Full Text
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Harshman, D. R., Kleiman, R. N., Inui, M., Espinosa, G. P., Mitzi, D. B., Kapitulnik, A., … Williams, D. L. (1991). Magnetic penetration depth and flux dynamics in single-crystal Bi2Sr2CaCu2O8+ delta.. Physical Review Letters, 67(22), 3152–3155. https://doi.org/10.1103/physrevlett.67.3152Full Text
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Duran, C., Yazyi, J., de la Cruz F, Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Flux-lattice melting, anisotropy, and the role of interlayer coupling in Bi-Sr-Ca-Cu-O single crystals.. Physical Review. B, Condensed Matter, 44(14), 7737–7740. https://doi.org/10.1103/physrevb.44.7737Full Text
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Hsu, J. W., Mitzi, D. B., Kapitulnik, A., & Lee, M. (1991). In-plane dissipation maxima and vortex-line distortions in the resistive transitions of oxygen-doped Bi2Sr2CaCu2O8+ delta single crystals.. Physical Review Letters, 67(15), 2095–2098. https://doi.org/10.1103/physrevlett.67.2095Full Text
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Walstedt, R. E., Bell, R. F., & Mitzi, D. B. (1991). Nuclear relaxation behavior of the superconducting cuprates: Bi2Sr2CaCu2O8.. Physical Review. B, Condensed Matter, 44(14), 7760–7763. https://doi.org/10.1103/physrevb.44.7760Full Text
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Chan, L. P., Harshman, D. R., Lynn, K. G., Massidda, S., & Mitzi, D. B. (1991). Pair momentum distribution in Bi2Sr2CaCu2O8+ delta measured by positron annihilation: Existence and nature of the Fermi surface.. Physical Review Letters, 67(10), 1350–1353. https://doi.org/10.1103/physrevlett.67.1350Full Text
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Dessau, D. S., Wells, B. O., Shen, Z., Spicer, W. E., Arko, A. J., List, R. S., … Kapitulnik, A. (1991). Anomalous spectral weight transfer at the superconducting transition of Bi2Sr2CaCu2O8+ delta.. Physical Review Letters, 66(16), 2160–2163. https://doi.org/10.1103/physrevlett.66.2160Full Text
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Grier, D. G., Murray, C. A., Bolle, C. A., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Translational and bond-orientational order in the vortex lattice of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+ delta.. Physical Review Letters, 66(17), 2270–2273. https://doi.org/10.1103/physrevlett.66.2270Full Text
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Parmigiani, F., Shen, Z. X., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1991). O 1s core levels in Bi2Sr2CaCu2O8+ delta single crystals.. Physical Review. B, Condensed Matter, 43(4), 3085–3090. https://doi.org/10.1103/physrevb.43.3085Full Text
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Bolle, C. A., Gammel, P. L., Grier, D. G., Murray, C. A., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Observation of a commensurate array of flux chains in tilted flux lattices in Bi-Sr-Ca-Cu-O single crystals.. Physical Review Letters, 66(1), 112–115. https://doi.org/10.1103/physrevlett.66.112Full Text
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Dessau, D. S., Shen, Z. X., Wells, B. O., Spicer, W. E., List, R. S., Arko, A. J., … Schirber, J. E. (1990). Electronic structure of the gold/Bi2Sr2CaCu2O8and gold/EuBa2Cu3O7-δinterfaces as studied by photoemission spectroscopy. Applied Physics Letters, 57(3), 307–309. https://doi.org/10.1063/1.104219Full Text
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Lindberg, P. A. P., Wells, B. O., Shen, Z. X., Dessau, D. S., Lindau, I., Spicer, W. E., … Kapitulnik, A. (1990). Interaction of overlayers of Al and Rb with single-crystalline surfaces of Bi2Sr2CaCu2O8. Journal of Applied Physics, 67(5), 2667–2670. https://doi.org/10.1063/1.345480Full Text
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Wells, B. O., Shen, Z., Dessau, D. S., Spicer, W. E., Olson, C. G., Mitzi, D. B., … Arko, A. (1990). Angle-resolved-photoemission study of Bi2Sr2CaCu2O8+ delta : Metallicity of the Bi-O plane.. Physical Review Letters, 65(24), 3056–3059. https://doi.org/10.1103/physrevlett.65.3056Full Text
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BISHOP, D. J., GAMMEL, P. L., MURRAY, C. A., MITZI, D. B., & KAPITULNIK, A. (1990). OBSERVATION OF AN HEXATIC VORTEX GLASS IN FLUX LATTICES OF THE HIGH-TC SUPERCONDUCTOR BI2.1SR1.9CA0.9CU2O8+DELTA. Annals of the New York Academy of Sciences, 581, 77–87.Link to Item
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Ferrari, M. J., Johnson, M., Wellstood, F. C., Clarke, J., Mitzi, D., Rosenthal, P. A., … Beasley, M. R. (1990). Ferrari et al. reply.. Physical Review Letters, 65(2). https://doi.org/10.1103/physrevlett.65.279Full Text
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Murray, C. A., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1990). Observation of a hexatic vortex glass in flux lattices of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+ delta.. Physical Review Letters, 64(19), 2312–2315. https://doi.org/10.1103/physrevlett.64.2312Full Text
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Kim, J. H., Bozovic, I., Mitzi, D. B., Kapitulnik, A., & Harris, J. S. (1990). Optical anisotropy of Bi2Sr2CaCu2O8.. Physical Review. B, Condensed Matter, 41(10), 7251–7253. https://doi.org/10.1103/physrevb.41.7251Full Text
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Mitzi, D. B., Lombardo, L. W., Kapitulnik, A., Laderman, S. S., & Jacowitz, R. D. (1990). Growth and properties of oxygen- and ion-doped Bi2Sr2CaCu2O8+ delta single crystals.. Physical Review. B, Condensed Matter, 41(10), 6564–6574. https://doi.org/10.1103/physrevb.41.6564Full Text
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Harshman, D. R., Kleiman, R. N., Haddon, R. C., Chichester-Hicks, S. V., Kaplan, M. L., Rupp, L. W., … Mitzi, D. B. (1990). Magnetic penetration depth in the organic superconductor kappa -. Physical Review Letters, 64(11), 1293–1296. https://doi.org/10.1103/physrevlett.64.1293Full Text
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Ferrari, M. J., Johnson, M., Wellstood, F. C., Clarke, J., Mitzi, D., Rosenthal, P. A., … Beasley, M. R. (1990). Distribution of flux-pinning energies in YBa2Cu3O7- delta and Bi2Sr2CaCu2O8+ delta from flux noise.. Physical Review Letters, 64(1), 72–75. https://doi.org/10.1103/physrevlett.64.72Full Text
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Fanton, J. T., Mitzi, D. B., Kapitulnik, A., Khuri-Yakub, B. T., Kino, G. S., Gazit, D., & Feigelson, R. S. (1989). Photothermal measurements of high Tcsuperconductors. Applied Physics Letters, 55(6), 598–599. https://doi.org/10.1063/1.101843Full Text
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Lindberg, P. A. P., Shen, Z. X., Wells, B. O., Dessau, D. S., Borg, A., Lindau, I., … Kapitulnik, A. (1989). Spectroscopic evidence of two-dimensional character of the 90 K Bi 2(Sr,La,Ca)3Cu2O8 superconductors. Applied Physics Letters, 55(11), 1141–1143. https://doi.org/10.1063/1.101889Full Text
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Lindberg, P. A., Shen, Z., Wells, B. O., Dessau, D. S., Ellis, W. P., Borg, A., … Kapitulnik, A. (1989). Photoemission study of absorption mechanisms in Bi2.0Sr1.8Ca0.8La0.3Cu2.1O8+ delta, BaBiO3, and Nd1.85Ce0.15CuO4.. Physical Review. B, Condensed Matter, 40(13), 8840–8843. https://doi.org/10.1103/physrevb.40.8840Full Text
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Lindberg, P. A., Shen, Z., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1989). Electronic structure of clean and Ag-covered single-crystalline Bi2Sr2CuO6.. Physical Review. B, Condensed Matter, 40(13), 8769–8773. https://doi.org/10.1103/physrevb.40.8769Full Text
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Lindberg, P. A., Shen, Z., Dessau, D. S., Wells, B. O., Mitzi, D. B., Lindau, I., … Kapitulnik, A. (1989). Energy dispersions of single-crystalline Bi2.0Sr1.8Ca0.8La0.3Cu2.1O8+ delta superconductors determined using angle-resolved photoelectron spectroscopy.. Physical Review. B, Condensed Matter, 40(7), 5169–5171. https://doi.org/10.1103/physrevb.40.5169Full Text
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Wells, B. O., Lindberg, P. A., Shen, Z., Dessau, D. S., Spicer, W. E., Lindau, I., … Kapitulnik, A. (1989). Valence-band states in Bi2(Ca,Sr,La)3Cu2O8.. Physical Review. B, Condensed Matter, 40(7), 5259–5262. https://doi.org/10.1103/physrevb.40.5259Full Text
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Lindberg, P. A. P., Shen, Z. X., Dessau, D. S., Wells, B. O., Borg, A., Ellis, W., … Kapitulnik, A. (1989). The electronic structure of Bi 2.0 Sr 1.8 La 0.3 Ca 0.8 Cu 2.1 O 8+δ superconductors studied using ultraviolet and X-ray photoelectron spectroscopy. Physica C: Superconductivity and Its Applications, 159(5), 649–653. https://doi.org/10.1016/0921-4534(89)91299-9Full Text
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Urbach, J. S., Mitzi, D. B., Kapitulnik, A., Wei, J. Y., & Morris, D. E. (1989). Low-temperature specific heat of single-crystal Bi2CaSr2Cu2O8 and Tl2Ca2Ba2Cu3O10.. Physical Review. B, Condensed Matter, 39(16), 12391–12394. https://doi.org/10.1103/physrevb.39.12391Full Text
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Shen, Z., Lindberg, P. A., Dessau, D. S., Lindau, I., Spicer, W. E., Mitzi, D. B., … Kapitulnik, A. (1989). Photoelectron energy-loss study of the Bi2CaSr2Cu2O8 superconductor.. Physical Review. B, Condensed Matter, 39(7), 4295–4298. https://doi.org/10.1103/physrevb.39.4295Full Text
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Kuiper, P., Grioni, M., Sawatzky, G. A., Mitzi, D. B., Kapitulnik, A., Santaniello, A., … Thiry, P. (1989). Symmetry of the oxygen hole states in Bi2Sr2CaCu2O8 investigated by XAS. Physica C: Superconductivity and Its Applications, 157(2), 260–262. https://doi.org/10.1016/0921-4534(89)90012-9Full Text
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Lindberg, P. A., Shen, Z., Wells, B. O., Dessau, D. S., Mitzi, D. B., Lindau, I., … Kapitulnik, A. (1989). Reaction of Rb and oxygen overlayers with single-crystalline Bi2Sr2CaCu2O8+ delta superconductors.. Physical Review. B, Condensed Matter, 39(4), 2890–2893. https://doi.org/10.1103/physrevb.39.2890Full Text
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Lee, M., Mitzi, D. B., Kapitulnik, A., & Beasley, M. R. (1989). Electron tunneling and the energy gap in Bi2Sr2CaCu2Ox.. Physical Review. B, Condensed Matter, 39(1), 801–803. https://doi.org/10.1103/physrevb.39.801Full Text
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Lindberg, P. A. P., Shen, Z. X., Hwang, J., Shih, C. K., Lindau, I., Spicer, W. E., … Kapitulnik, A. (1989). Electronic structure of the La1 + xBa2 - xCu3O7 + δ system studied by photoelectron spectroscopy. Solid State Communications, 69(1), 27–31. https://doi.org/10.1016/0038-1098(89)90020-3Full Text
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Lindberg, P. A. P., Shen, Z. X., Lindau, I., Spicer, W. E., Mitzi, D. B., & Kapitulnik, A. (1989). Photoemission study of the electronic structure (Pr0.2La0.8)(Ba1.875La0.125)Cu3O7-gd. Solid State Communications, 72(6), 575–578. https://doi.org/10.1016/0038-1098(89)91036-3Full Text
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Newsam, J. M., Jacobson, A. J., Goshorn, D. P., Lewandowski, J. T., Mitzi, D. B., Kapitulnik, A., … Yelon, W. B. (1989). Orthorhombic and tetragonal structures in the La(Ba2-yLay)Cu3O7-x system. Solid State Ionics, 32–33(PART 2), 1064–1079. https://doi.org/10.1016/0167-2738(89)90399-8Full Text
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Kirillov, D., Bozovic, I., Geballe, T. H., Kapitulnik, A., & Mitzi, D. B. (1988). Raman scattering spectra of superconducting Bi2Sr2CaCu2O8 single crystals.. Physical Review. B, Condensed Matter, 38(16), 11955–11957. https://doi.org/10.1103/physrevb.38.11955Full Text
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Kirk, M. D., Nogami, J., Baski, A. A., Mitzi, D. B., Kapitulnik, A., Geballe, T. H., & Quate, C. F. (1988). The Origin of the Superstructure in Bi2Sr2CaCu2O8+dgr as Revealed by Scanning Tunneling Microscopy.. Science (New York, N.Y.), 242(4886), 1673–1675. https://doi.org/10.1126/science.242.4886.1673Full Text
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Lindberg, P. A. P., Shen, Z. X., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1988). Surface structure of Bi2Sr2CaCu2O8+δhigh-temperature superconductors studied using low-energy electron diffraction. Applied Physics Letters, 53(25), 2563–2565. https://doi.org/10.1063/1.100532Full Text
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Shen, Z., Lindberg, P. A., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1988). Valence-band and core-level photoemission study of single-crystal Bi2CaSr2Cu2O8 superconductors.. Physical Review. B, Condensed Matter, 38(16), 11820–11823. https://doi.org/10.1103/physrevb.38.11820Full Text
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Mitzi, D. B., Feffer, P. T., Newsam, J. M., Webb, D. J., Klavins, P., Jacobson, A. J., & Kapitulnik, A. (1988). Site-selective doping and superconductivity in (La1-yPry)(Ba2-xLax)Cu3O7+ delta.. Physical Review. B, Condensed Matter, 38(10), 6667–6676. https://doi.org/10.1103/physrevb.38.6667Full Text
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Newsam, J. (1988). Orthorhombic and tetragonal structures in the La(La/Ba)2Cu3O9−δ system. Solid State Ionics, 26(2), 168–168. https://doi.org/10.1016/0167-2738(88)90150-6Full Text
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Kirk, M. D., Nogami, J., Baski, A. A., Mitzi, D. B., Kapitulnik, A., Geballe, T. H., & Quate, C. F. (1988). The origin of the superstructure in Bi2Sr2CaCu 2O8+δ as revealed by scanning tunneling microscopy. Science, 242(4886), 1673–1675.
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Bozovic, I., Mitzi, D., Beasley, M., Kapitulnik, A., Geballe, T., Perkowitz, S., … Yom, S. S. (1987). Vibrational spectra and lattice instabilities in the high-Tc superconductors YBa2Cu3O7 and GdBa2Cu3O7.. Physical Review. B, Condensed Matter, 36(7), 4000–4002. https://doi.org/10.1103/physrevb.36.4000Full Text
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Kirk, M. D., Smith, D. P., Mitzi, D. B., Sun, J. Z., Webb, D. J., Char, K., … Quate, C. F. (1987). Point-contact electron tunneling into the high-Tc superconductor Y-Ba-Cu-O.. Physical Review. B, Condensed Matter, 35(16), 8850–8852. https://doi.org/10.1103/physrevb.35.8850Full Text
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Naito, M., Smith, D. P., Kirk, M. D., Oh, B., Hahn, M. R., Char, K., … Quate, C. F. (1987). Electron-tunneling studies of thin films of high-Tc superconducting La-Sr-Cu-O.. Physical Review. B, Condensed Matter, 35(13), 7228–7231. https://doi.org/10.1103/physrevb.35.7228Full Text
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Sun, J. Z., Webb, D. J., Naito, M., Char, K., Hahn, M. R., Hsu, J. W., … Kapitulnik, A. (1987). Superconductivity and magnetism in the high-Tc superconductor YBaCuO.. Physical Review Letters, 58(15), 1574–1576. https://doi.org/10.1103/physrevlett.58.1574Full Text
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Laibowitz, R. B., & Mitzi, D. B. (1984). CHANNEL SQUID.. Ibm Technical Disclosure Bulletin, 26(11), 5775–5776.
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Wallace, S. K., Svane, K. L., Huhn, W. P., Zhu, T., Mitzi, D. B., Blum, V., & Walsh, A. (n.d.). Candidate photoferroic absorber materials for thin-film solar cells from naturally occurring minerals: enargite, stephanite, and bournonite. Sustainable Energy & Fuels, 1(6), 1339–1350. https://doi.org/10.1039/c7se00277gFull Text
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Zeldov, E., & Amer, N. M. (n.d.). Flux-pinning energies in high-Tcsuperconductors. Physical Review Letters, 65(2), 278–278. https://doi.org/10.1103/physrevlett.65.278Full Text
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Book Sections
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Gunawan, O., Gokmen, T., & Mitzi, D. B. (2015). Device Characteristics of Hydrazine-Processed CZTSSe. In Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells (pp. 387–411). https://doi.org/10.1002/9781118437865.ch17Full Text
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Mitzi, D. B. (2008). Preface. https://doi.org/10.1002/9780470407790Full Text
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Conference Papers
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Jiang, T., Bai, Y., Han, Q., Mitzi, D., & Therien, M. (2018). How to turn iron into ruthenium. In Abstracts of Papers of the American Chemical Society (Vol. 256). Boston, MA: AMER CHEMICAL SOC.Link to Item
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Mitzi, D. (2018). Halide perovskites beyond CH3NH3PbI3: Structural diversity and opportunities for semiconductor design. In Abstracts of Papers of the American Chemical Society (Vol. 255). New Orleans, LA: AMER CHEMICAL SOC.Link to Item
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Stiff-Roberts, A. D., Mitzi, D. B., Barraza, E. T., & Dunlap-Shohl, W. A. (2018). Resonant infrared matrix-assisted pulsed laser evaporation of hybrid perovskites. In Optics Infobase Conference Papers (Vol. Part F107-NOMA 2018). https://doi.org/10.1364/NOMA.2018.NoM4D.2Full Text
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Keenan, E., Hu, J., Zhi, J., Mitzi, D., & You, W. (2017). Diffusion of cations in 2D/3D perovskite films made by melt infiltration. In Abstracts of Papers of the American Chemical Society (Vol. 253). San Francisco, CA: AMER CHEMICAL SOC.Link to Item
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Gunawan, O., Gokmen, T., & Mitzi, D. B. (2015). High intensity and integrated Suns-Voc characterization of high performance kesterite solar cells. In 2015 Ieee 42nd Photovoltaic Specialist Conference, Pvsc 2015. https://doi.org/10.1109/PVSC.2015.7355690Full Text
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Mitzi, D. (2013). Solution-processing of high-performance CZTS devices for photovoltaic application. In Abstracts of Papers of the American Chemical Society (Vol. 245). New Orleans, LA: AMER CHEMICAL SOC.Link to Item
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Mitzi, D. B., Todorov, T. K., Gunawan, O., Barkhouse, A. R., Bag, S., Qiu, X., … Miyamoto, H. (2011). Slurry-based processing of high-performance CZTSSe photovoltaic absorber layers. In Acs National Meeting Book of Abstracts.
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Mitzi, D. B., Todorov, T. K., Gunawan, O., Yuan, M., Cao, Q., Liu, W., … Fogel, K. E. (2010). Torwards marketable efficiency solution-processed kesterite and chalcopyrite photovoltaic devices. In Conference Record of the Ieee Photovoltaic Specialists Conference (pp. 640–645). https://doi.org/10.1109/PVSC.2010.5616865Full Text
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Liu, W., Mitzi, D. B., Chey, S. J., & Kellock, A. (2009). CuIn(Se,S)2 absorbers processed using a hydrazine-based solution approach. In Materials Research Society Symposium Proceedings (Vol. 1123, pp. 117–122).
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Mitzi, D. B., Yuan, M., Liu, W., Kellock, A. J., Chey, S. J., Gignac, L., & Schrott, A. G. (2009). Hydrazine-based deposition route for device-quality CIGS films. In Thin Solid Films (Vol. 517, pp. 2158–2162). https://doi.org/10.1016/j.tsf.2008.10.079Full Text
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Chey, S. J., Wei, L., Min, Y., & Mitzi, D. B. (2009). CHARACTERIZATION OF INDIUM TIN OXIDE AND AL-DOPED ZINC OXIDE THIN FILMS DEPOSITED BY CONFOCAL RF MAGNETRON SPUTTER DEPOSITION. In 2009 34th Ieee Photovoltaic Specialists Conference, Vols 1 3 (pp. 29–33). Philadelphia, PA: IEEE.Link to Item
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Mitzi, D. B., Min Yuan, Wei Liu, Kellock, A., Chey, S. J., Schrott, A., & Deline, V. (2008). Solution processing of CIGS absorber layers using a hydrazine-based approach. In Conference Record of the Ieee Photovoltaic Specialists Conference. https://doi.org/10.1109/PVSC.2008.4922730Full Text
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Milliron, D. J., & Mitzi, D. B. (2006). Solution processed metal chalcogenide thin films for flexible and large scale electronics. In Acs National Meeting Book of Abstracts (Vol. 231).
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Mitzi, D. B., Milliron, D. J., Copel, M., Murray, C., & Kosbar, L. (2005). High mobility solution-deposited chalcogenide films for flexible applications. In 2005 Ieee Vlsi Tsa International Symposium on Vlsi Technology Vlsi Tsa Tech, Proceedings of Technical Papers (pp. 41–44). https://doi.org/10.1109/VTSA.2005.1497075Full Text
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Mitzi, D. B., Xu, Z. T., Dimitrakopoulos, C. D., & Medeiros, D. R. (2003). Structures, properties and devices based on hybrid perovskites and related materials.. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U85–U85). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.Link to Item
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Xu, Z. T., & Mitzi, D. (2003). New structural motifs in semiconducting organic-inorganic perovskites.. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U94–U94). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.Link to Item
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Xu, Z. T., Mitzi, D., & Dimitrakopoulos, C. D. (2003). Crystal and electronic structure correlation in organic-inorganic perovskites.. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U87–U87). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.Link to Item
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Mitzi, D. B., & Chondroudis, K. (2001). Crystal structure and properties of dye-containing organic- inorganic perovskites. In Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals (Vol. 356, pp. 549–558). https://doi.org/10.1080/10587250108023733Full Text
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Koutselas, I. B., Mitzi, D. B., Papavassiliou, G. C., Papaioannou, G. J., & Krautscheid, H. (1997). Optical and related properties and natural one-dimensional semiconductors based on PbI and SnI units. In Synthetic Metals (Vol. 86, pp. 2171–2172). https://doi.org/10.1016/S0379-6779(97)81081-8Full Text
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Takigawa, M., & Mitzi, D. B. (1994). NMR studies of spin dynamics in cuprates. In Journal of Low Temperature Physics (Vol. 95, pp. 89–93). https://doi.org/10.1007/BF00754926Full Text
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Pastoriza, H., Arribere, A., Goffman, M. F., de la Cruz, F., Mitzi, D. B., & Kapitulnik, A. (1994). Evidence for the quasi-two dimensional behavior of the vortex structure in Bi2Sr2CaCu2O8 single crystals. In Physica B: Physics of Condensed Matter (Vol. 194–196, pp. 2227–2228). https://doi.org/10.1016/0921-4526(94)91613-6Full Text
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Renner, C., Fischer, Kent, A. D., Mitzi, D. B., & Kapitulnik, A. (1994). Spatially resolved vacuum tunneling spectroscopy on Bi2Sr2CaCu2O8 by STM at 4.8K. In Physica B: Physics of Condensed Matter (Vol. 194–196, pp. 1689–1690). https://doi.org/10.1016/0921-4526(94)91344-7Full Text
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Hallen, H. D., Hess, H. F., Chang, A. M., Pfeiffer, L. N., West, K. W., & Mitzi, D. B. (1993). High-resolution scanning Hall probe microscopy. In Scanning Probe Microscopies Ii. SPIE. https://doi.org/10.1117/12.146371Full Text
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Duran, C., Yazyi, J., Arribere, A., De La Cruz, F., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1992). Superconducting interlayer decoupling and softening of the flux line structure in BSCCO single crystals. In Superconductor Science and Technology (Vol. 5). https://doi.org/10.1088/0953-2048/5/1S/060Full Text
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Bishop, D. J., Gammel, P. L., Murray, C. A., Mitzi, D. B., & Kapitulnik, A. (1991). Observation of an hexatic vortex glass in flux lattices of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+δ. In Physica B: Physics of Condensed Matter (Vol. 169, pp. 72–79). https://doi.org/10.1016/0921-4526(91)90210-6Full Text
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Chan, L. P., Harshman, D. R., Lynn, K. G., Massidda, S., & Mitzi, D. B. (1991). Evidence for a fermi surface in Bi2Sr2CaCu2O8+δ measured by positron 2D-ACAR. In Journal of Physics and Chemistry of Solids (Vol. 52, pp. 1557–1567). https://doi.org/10.1016/0022-3697(91)90140-UFull Text
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Dessau, D. S., Shen, Z. X., Wells, B. O., Spicer, W. E., List, R. S., Arko, A. J., … Gebaiie, T. H. (1991). The gold/high temperature superconductor interface; metallicity of the near surface region and a search for the proximity effect. In Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films (Vol. 9, pp. 383–389). https://doi.org/10.1116/1.577418Full Text
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Bishop, D. J., Gammel, P. L., Murray, C. A., Mitzi, D. B., & Kapitulnik, A. (1990). Observation of an Hexatic Vortex Glass in Flux Lattices of the High Tc Superconductor Bi2.1Sr1.9Ca0.9Cu2O8+§. In Annals of the New York Academy of Sciences (Vol. 581, pp. 77–87). https://doi.org/10.1111/j.1749-6632.1990.tb22701.xFull Text
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FANTON, J. T., KAPITULNIK, A., MITZI, D. B., KHURIYAKUB, B. T., & KINO, G. S. (1990). PHOTOTHERMAL MEASUREMENTS OF HIGH-TC SUPERCONDUCTORS. In J. C. MURPHY, L. C. AAMODT, J. W. M. SPICER, & B. S. H. ROYCE (Eds.), Photoacoustic and Photothermal Phenomena Ii (Vol. 62, pp. 202–204). BALTIMORE, MD: SPRINGER-VERLAG BERLIN.Link to Item
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KAPITULNIK, A., & MITZI, D. B. (1990). GROWTH AND PROPERTIES OF OXYGEN DOPED BI2SR2CACU2O8+DELTA SINGLE-CRYSTALS. In R. NICOLSKY (Ed.), Proceedings of the Ictps 90 International Conference on Transport Properties of Superconductors (Vol. 25, pp. 491–501). RIO DE JANEIRO, BRAZIL: WORLD SCIENTIFIC PUBL CO PTE LTD.Link to Item
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WELLS, B. O., LINDBERG, P. A. P., SHEN, Z. X., DESSAU, D. S., SPICER, W. E., LINDAU, I., … KAPITULNIK, A. (1990). NATURE OF THE VALENCE BAND STATES IN BI2(CA,SR,LA)3CU2O8. In R. L. STOCKBAUER, S. V. KRISHNASWAMY, & R. L. KURTZ (Eds.), High Tc Superconducting Thin Films : Processing, Characterization, and Applications (Vol. 200, pp. 36–41). BOSTON, MA: AIP PRESS.Link to Item
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Lindberg, P. A. P., Shen, Z. X., Dessau, D. S., Wells, B. O., Borg, A., Mitzi, D. B., … Kapitulnik, A. (1989). Electronic structure of single crystalline Bi2(Sr,Ca,La)3Cu2O8. In Physica C: Superconductivity and Its Applications (Vol. 162–164, pp. 1313–1314). https://doi.org/10.1016/0921-4534(89)90709-0Full Text
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- Teaching & Mentoring
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Recent Courses
- ME 394: Engineering Undergraduate Fellows Projects 2019
- ME 555: Advanced Topics in Mechanical Engineering 2019
- ME 391: Undergraduate Projects in Mechanical Engineering 2018
- ME 592: Research Independent Study in Mechanical Engineering or Material Science 2018
- ENRGYEGR 490: Special Topics in Energy Engineering 2017
- Scholarly, Clinical, & Service Activities
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Presentations & Appearances
- Earth-Abundant Kesterite Solar Cells: Opportunities and Challenges (Keynote Lecture). 3rd International Renewable and Sustainable Energy Conference (IRSEC). Mediterranean Space of Technology and Innovation (MSTI), Moroccan Agency for Solar Energy (MASEN), Deutsche Gesellschaft für Internationale Zusammenarbeit (GIZ), and National Higher School of IT (ENSIAS) of Mohamme V University of Rabat-Morocco. December 11, 2015 2015
- Organic-Inorganic Perovskites: Opportunities and Challenges for Photovoltaic Materials Design. Fall Materials Research Society (MRS) Meeting -- Symposium OO: Nanomaterials-Based Solar Energy Conversion. Materials Research Society. December 2, 2015 2015
- Kesterite Solar Cells: Recent Progress and Open Circuit Voltage Limitation. Fall Materials Research Society (MRS) Meeting -- Symposium NN: Thin-Film and Nanostructure Solar Cell Materials and Devices for Next-Generation Photovoltaics. Materials Research Society. December 1, 2015 2015
- Recent Progress in Kesterite-Based Photovoltaic Technology (Keynote Lecture). Center for Sustainable Materials Chemistry Conference and Annual Meeting. Oregon State University. November 4, 2015 2015
- Recent Progress in Kesterite-Based Photovoltaic Technology. 2015 PV Conference and Exhibition of China. China Photovoltaic Industry Association, jointly with Chinese Renewable Energy Society, China National Renewable Energy Center and Chinese Renewable Energy Industries Association. October 13, 2015 2015
- Recent Progress in Kesterite-Based Photovoltaic Technology. Advances in Photovoltaics. Institute of Physics (IOP). September 29, 2015 2015
- Recent Progress in Kesterite-Based Photovoltaic Technology. Solution Processed Innovative Solar Cells (SPINS15). nanoGe. September 1, 2015 2015
- Organic-Inorganic Perovskites: Historical Perspectives and Future Prospects. National Academies—Condensed Matter and Materials Research Committee Spring Meeting. National Academies. June 15, 2015 2015
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Los Alamos National Laboratories seminar. Los Alamos National Laboratories. June 2, 2015 2015
- Hybrids, Perovskites, New Directions. Organic-electronics Structure and Optical Properties Workshop. North Carolina State University. May 20, 2015 2015
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Next Generation Solar: Photovoltaics Canada. Next Generation Solar and University of Toronto. May 14, 2015 2015
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. MRS / APSc (Applied Sciences) Seminar. University of North Carolina, Chapel Hill. April 30, 2015 2015
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Physics Department Seminar. University of Toledo. April 23, 2015 2015
- Organic-Inorganic Perovskites: An Historical Perspective. 2015 ANSER Solar Energy Symposium. Northwestern University. April 17, 2015 2015
- Current Status and Future Prospects of Earth-Abundant Kesterite Photovoltaics. 150 Year Anniversary BASF Science Symposium. BASF. March 10, 2015 2015
- Background on Hybrid Organic-Inorganic Perovskites and Early Device Work. NSF-BSF Workshop on Hybrid Organic-Inorganic Perovskites (HOIP). Weizmann Institute of Science. February 22, 2015 2015
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Chemistry Department Seminar Series. Duke University . January 27, 2015 2015
- Current Status and Future Prospects of Earth-Abundant Kesterite Photovoltaics. 1st International Symposium on Interactive Materials Science Cadet Program (iSIMSC). Osaka University. November 17, 2014 2014
- Current Status and Future Prospects of Earth-Abundant Kesterite Photovoltaics. KAUST Solar Future Meeting. KAUST. November 9, 2014 2014
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Materials Science and Engineering Colloquium. University of Texas at Dallas. October 24, 2014 2014
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Pratt New Faculty Lecture Series & FIP Photonics and Optics Seminar Series. Duke University. October 22, 2014 2014
- Current Status and Future Prospects of Earth-Abundant Kesterite Photovoltaics. Condensed Matter Physics Seminar. Stanford University. October 16, 2014 2014
- Solution Processing of Thin-Film Solar Cells: Opportunities and Challenges. Andlinger Center’s 2014-2015 Highlight Seminar Series. Princeton University. September 29, 2014 2014
- Development of High-Performance Solution-Processed Chalcopyrite/Kesterite Films for Photovoltaic Application. International Conference on Solution Processed Semiconductor Solar Cells. Oxford University. September 11, 2014 2014
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Service to the Profession
- Symposium Co-Organizer. MRS Fall Meeting -- Symposium W (Perovskite-Based and Related Novel Material Solar Cells) . Materials Research Society (MRS). November 30, 2014 - December 5, 2014 2014
- Science Advisory Board, Center for Sustainable Materials Chemistry, University of Oregon and Oregon State University. 2012 - 2016 2012 - 2016
- Editorial Board for Advanced Energy Materials (Wiley) . March 2011 - 2016 2011 - 2016
Some information on this profile has been compiled automatically from Duke databases and external sources. (Our About page explains how this works.) If you see a problem with the information, please write to Scholars@Duke and let us know. We will reply promptly.
