David Mitzi | Scholars@Duke

David Mitzi
Simon Family Distinguished Professor

David Mitzi received his B.S. in Electrical Engineering and Engineering Physics from Princeton University in 1985 and his Ph.D. in Applied Physics from Stanford University in 1990. Prior to joining the faculty at Duke in 2014, Dr. Mitzi spent 23 years at IBM’s T.J. Watson Research Center, where his focus was on the search for and application of new electronic materials, including organic-inorganic perovskites and inorganic materials for photovoltaic, LED, transistor and memory applications. For his final five years at IBM, he served as manager for the Photovoltaic Science and Technology Department, where he initiated and managed a multi-company program to develop a low-cost, high-throughput approach to deposit thin-film chalcogenide-based absorber layers for high-efficiency solar cells. Dr. Mitzi’s current research interests involve making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market. He holds a number of patents, and has authored or coauthored more than 200 papers and book chapters.

Current Research Interests

Making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market.

Current Appointments & Affiliations

Simon Family Distinguished Professor, Thomas Lord Department of Mechanical Engineering and Materials Science, Pratt School of Engineering 2016
Professor in the Department of Mechanical Engineering and Materials Science, Thomas Lord Department of Mechanical Engineering and Materials Science, Pratt School of Engineering 2014
Professor of Chemistry, Chemistry, Trinity College of Arts & Sciences 2015
Faculty Network Member of The Energy Initiative, Duke University Energy Initiative, Initiatives 2012

Contact Information

363 Gross Hall, Box 90300, Durham, NC 27708
Box 90300 Hudson Hall, Durham, NC 27708-0300
david.mitzi@duke.edu (919) 660-5356
Google Scholar - David B. Mitzi
Mitzi group website

Background
Education, Training, & Certifications
- Ph.D., Stanford University 1990
- B.S., Princeton University 1985
Duke Appointment History
- Visiting Professor in the Department of Mechanical Engineering and Materials Science, Thomas Lord Department of Mechanical Engineering and Materials Science, Pratt School of Engineering 2014
Recognition
In the News
- OCT 13, 2020 Pratt School of Engineering
  
  Chiral Ingredients Split Electron Spins in Hybrid Semiconductors
- NOV 20, 2019 Pratt School of Engineering
  
  Six Duke Engineers Among Global Highly Cited
- NOV 19, 2019
  
  Global List of Highly Cited Puts Duke in Top Ten
- AUG 27, 2019
  
  Professors, Alumna Honored by American Chemical Society
- NOV 27, 2018
  
  Duke Faculty Plentiful On ‘Highly Cited’ List
- OCT 8, 2018 Pratt School of Engineering
  
  Supercomputer Predicts Optical and Thermal Properties of Complex Hybrid Materials
- AUG 23, 2018 Pratt School of Engineering
  
  Pratt Researchers Join National Effort to Unlock New Energy Technologies
- AUG 21, 2018
  
  Duke Engineers Join National Center on Emerging Energy Materials
- FEB 10, 2018 Pratt School of Engineering
  
  Mitzi Elected to Materials Research Society Fellows
- JAN 3, 2018 Pratt School of Engineering
  
  Laser Evaporation Technology to Create New Solar Materials
- APR 28, 2017
  
  Energy Initiative Awards Seven New Seed Grants
- MAY 5, 2016
  
  Duke Awards Distinguished Professorships, Inducts New Bass Society Members
- MAY 7, 2015 Duke Research Blog
  
  Duke Initiative Brings a Lot of Energy to Research
- OCT 23, 2014 Pratt School of Engineering
  
  Mitzi Awarded SunShot Initiative Funding to Improve Thin-Film Solar Cell Materials
- AUG 18, 2014 Pratt School of Engineering
  
  David Mitzi: Harvesting More of the Sun’s Shine
Awards & Honors
Expertise
Subject Headings
Research
Selected Grants
- REU SITE: Collaborative Research: Nanoscale Detectives -- Elucidating the Structure and Dynamics of Hybrid Perovskite Systems awarded by National Science Foundation 2021 - 2024
- GOALI: Additive and Stoichiometry Engineering in Perovskites: Building Deeper Understanding of the Impact on Optoelectronic Properties for Energy Applications awarded by National Science Foundation 2020 - 2023
- Design and Validation of Defect-Resistant Multinary Chalcogenide Semiconductors for Energy Conversion awarded by Department of Energy 2019 - 2022
- MRI: Acquisition of a Cryogen-Free Physical Properties Measurement System (PPMS DynaCool) awarded by National Science Foundation 2018 - 2021
- DMREF: Collaborative Research: HybriD3: Discovery, Design, Dissemination of Organic-Inorganic Hybrid Semiconductor Materials for Optoelectronic Applications awarded by National Science Foundation 2017 - 2021
- Melt Processing of Operationally-Stable Perovskite Photovoltaic Films and Devices awarded by Office of Naval Research 2017 - 2020
- GOALI: Doping Control and Processes in Metal Halide Perovskites awarded by National Science Foundation 2017 - 2020
- High-Performance Perovskite-Based Solar Cells awarded by Department of Energy 2014 - 2019
- GAANN - Department of Chemistry awarded by Department of Education 2015 - 2019
- Defect Engineering in Zinc-Blende-Type Absorbers awarded by National Science Foundation 2015 - 2019
External Relationships
- International Business Machines Corp.
- Moscow Autumn Perovskite Photovoltaics International Conference
- Next Generation Solar Energy Conference
- Perovskite Evaporation Conference
- UK EPSRC Centre for Doctoral Training in New and Sustainable Photovoltaics (involves Universities of Liverpool, Bath, Cambridge, Loughborough, Oxford, Sheffield and Southampton)
- Wiley Publishing, Inc.
Publications & Artistic Works
Selected Publications
- Academic Articles
  - Euvrard, J., Gunawan, O., Zhong, X., Harvey, S. P., Kahn, A., & Mitzi, D. B. (2021). P-Type molecular doping by charge transfer in halide perovskite. Materials Advances, 2(9), 2956–2965. https://doi.org/10.1039/d1ma00160d
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  - Li, C., Ma, H., Li, T., Dai, J., Rasel, M. A. J., Mattoni, A., … Tian, Z. (2021). Remarkably Weak Anisotropy in Thermal Conductivity of Two-Dimensional Hybrid Perovskite Butylammonium Lead Iodide Crystals. Nano Letters, 21(9), 3708–3714. https://doi.org/10.1021/acs.nanolett.0c04550
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  - Abdelsamie, M., Li, T., Babbe, F., Xu, J., Han, Q., Blum, V., … Toney, M. F. (2021). Mechanism of Additive-Assisted Room-Temperature Processing of Metal Halide Perovskite Thin Films. Acs Applied Materials & Interfaces, 13(11), 13212–13225. https://doi.org/10.1021/acsami.0c22630
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  - Almora, O., Baran, D., Bazan, G. C., Berger, C., Cabrera, C. I., Catchpole, K. R., … Brabec, C. J. (2021). Device Performance of Emerging Photovoltaic Materials (Version 1). Advanced Energy Materials, 11(11). https://doi.org/10.1002/aenm.202002774
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  - Teymur, B., Levcenco, S., Hempel, H., Bergmann, E., Márquez, J. A., Choubrac, L., … Mitzi, D. B. (2021). Optoelectronic and material properties of solution-processed Earth-abundant Cu2BaSn(S, Se)4 films for solar cell applications. Nano Energy, 80. https://doi.org/10.1016/j.nanoen.2020.105556
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  - Song, J., Teymur, B., Zhou, Y., Ngaboyamahina, E., & Mitzi, D. B. (2021). Porous Cu2BaSn(S,Se)4Film as a Photocathode Using Non-Toxic Solvent and a Ball-Milling Approach. Acs Applied Energy Materials, 4(1), 81–87. https://doi.org/10.1021/acsaem.0c01892
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  - Euvrard, J., Yan, Y., & Mitzi, D. B. (2021). Electrical doping in halide perovskites. Nature Reviews Materials. https://doi.org/10.1038/s41578-021-00286-z
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  - Singh, A., Jana, M. K., & Mitzi, D. B. (2021). Reversible Crystal-Glass Transition in a Metal Halide Perovskite. Advanced Materials (Deerfield Beach, Fla.), 33(3), e2005868. https://doi.org/10.1002/adma.202005868
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  - Li, T., Dunlap-Shohl, W. A., & Mitzi, D. B. (2020). Bifacial perovskite solar cells via a rapid lamination process. Acs Applied Energy Materials, 3(10), 9493–9497. https://doi.org/10.1021/acsaem.0c00756
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  - Jana, M. K., Song, R., Liu, H., Khanal, D. R., Janke, S. M., Zhao, R., … Mitzi, D. B. (2020). Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling. Nature Communications, 11(1), 4699. https://doi.org/10.1038/s41467-020-18485-7
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  - Jiang, T., Bai, Y., Zhang, P., Han, Q., Mitzi, D. B., & Therien, M. J. (2020). Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption. Proceedings of the National Academy of Sciences of the United States of America, 117(34), 20430–20437. https://doi.org/10.1073/pnas.2009996117
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  - Sun, J. P., McKeown Wessler, G. C., Wang, T., Zhu, T., Blum, V., & Mitzi, D. B. (2020). Erratum: Structural tolerance factor approach to defect-resistant I2‑II-IV‑X4 semiconductor design (Chemistry of Materials (2020) 32:4 (1636-1649) DOI: 10.1021/acs.chemmater.9b05107). Chemistry of Materials, 32(13), 5925–5926. https://doi.org/10.1021/acs.chemmater.0c02346
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  - Lu, H., Xiao, C., Song, R., Li, T., Maughan, A. E., Levin, A., … Beard, M. C. (2020). Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c03899
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  - Márquez, J. A., Sun, J. P., Stange, H., Ali, H., Choubrac, L., Schäfer, S., … Mainz, R. (2020). High-temperature decomposition of Cu2BaSnS4with Sn loss reveals newly identified compound Cu2Ba3Sn2S8. Journal of Materials Chemistry A, 8(22), 11346–11353. https://doi.org/10.1039/d0ta02348e
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  - Ye, F., Wu, H., Qin, M., Yang, S., Niu, G., Lu, X., … Choy, W. C. H. (2020). High-Quality MAPbBr3 Cuboid Film with Promising Optoelectronic Properties Prepared by a Hot Methylamine Precursor Approach. Acs Applied Materials & Interfaces, 12(21), 24498–24504. https://doi.org/10.1021/acsami.0c04516
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  - Sun, J. P., McKeown Wessler, G. C., Wang, T., Zhu, T., Blum, V., & Mitzi, D. B. (2020). Structural Tolerance Factor Approach to Defect-Resistant I2-II-IV-X4 Semiconductor Design. Chemistry of Materials, 32(4), 1636–1649. https://doi.org/10.1021/acs.chemmater.9b05107
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  - Todorov, T., Hillhouse, H. W., Aazou, S., Sekkat, Z., Vigil-Galán, O., Deshmukh, S. D., … Dale, P. J. (2020). Solution-based synthesis of kesterite thin film semiconductors. Jphys Energy, 2(1). https://doi.org/10.1088/2515-7655/ab3a81
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  - Euvrard, J., Gunawan, O., & Mitzi, D. B. (2019). Impact of PbI2 Passivation and Grain Size Engineering in CH3NH3PbI3 Solar Absorbers as Revealed by Carrier-Resolved Photo-Hall Technique. Advanced Energy Materials, 9(47). https://doi.org/10.1002/aenm.201902706
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  - Gunawan, O., Pae, S. R., Bishop, D. M., Virgus, Y., Noh, J. H., Jeon, N. J., … Shin, B. (2019). Carrier-resolved photo-Hall effect. Nature, 575(7781), 151–155. https://doi.org/10.1038/s41586-019-1632-2
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  - Jana, M. K., Liu, C., Lidin, S., Dirkes, D. J., You, W., Blum, V., & Mitzi, D. B. (2019). Resolving rotational stacking disorder and electronic level alignment in a 2d oligothiophene-based lead iodide perovskite. Chemistry of Materials, 31(20), 8523–8532. https://doi.org/10.1021/acs.chemmater.9b03208
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  - Dunlap-Shohl, W. A., Barraza, E. T., Barrette, A., Dovletgeldi, S., Findik, G., Dirkes, D. J., … Mitzi, D. B. (2019). Tunable internal quantum well alignment in rationally designed oligomer-based perovskite films deposited by resonant infrared matrix-assisted pulsed laser evaporation. Materials Horizons, 6(8), 1707–1716. https://doi.org/10.1039/c9mh00366e
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  - Zhang, B., Thampy, S., Dunlap-Shohl, W. A., Xu, W., Zheng, Y., Cao, F.-Y., … Hsu, J. W. P. (2019). Mg Doped CuCrO₂ as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells. Nanomaterials (Basel, Switzerland), 9(9). https://doi.org/10.3390/nano9091311
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  - Dunlap-Shohl, W. A., Li, T., & Mitzi, D. B. (2019). Interfacial Effects during Rapid Lamination within MAPbI3 Thin Films and Solar Cells. Acs Applied Energy Materials, 2(7), 5083–5093. https://doi.org/10.1021/acsaem.9b00747
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  - Li, T., Zeidell, A. M., Findik, G., Dunlap-Shohl, W. A., Euvrard, J., Gundogdu, K., … Mitzi, D. B. (2019). Phase-Pure Hybrid Layered Lead Iodide Perovskite Films Based on a Two-Step Melt-Processing Approach. Chemistry of Materials, 31(11), 4267–4274. https://doi.org/10.1021/acs.chemmater.9b01265
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  - Sun, J. P., Márquez, J. A., Stange, H., Mainz, R., & Mitzi, D. B. (2019). Phase and film formation pathway for vacuum-deposited C u2BaSn(S,Se)4 absorber layers. Physical Review Materials, 3(5). https://doi.org/10.1103/PhysRevMaterials.3.055402
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  - Jana, M. K., Janke, S. M., Dirkes, D. J., Dovletgeldi, S., Liu, C., Qin, X., … Mitzi, D. B. (2019). Direct-Bandgap 2D Silver-Bismuth Iodide Double Perovskite: The Structure-Directing Influence of an Oligothiophene Spacer Cation. Journal of the American Chemical Society, 141(19), 7955–7964. https://doi.org/10.1021/jacs.9b02909
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  - Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P., & Mitzi, D. B. (2019). Synthetic Approaches for Halide Perovskite Thin Films. Chemical Reviews, 119(5), 3193–3295. https://doi.org/10.1021/acs.chemrev.8b00318
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  - Mitzi, D. B. (2019). Introduction: Perovskites. Chemical Reviews, 119(5), 3033–3035. https://doi.org/10.1021/acs.chemrev.8b00800
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  - Ding, J., Han, Q., Ge, Q. Q., Xue, D. J., Ma, J. Y., Zhao, B. Y., … Hu, J. S. (2019). Fully Air-Bladed High-Efficiency Perovskite Photovoltaics. Joule, 3(2), 402–416. https://doi.org/10.1016/j.joule.2018.10.025
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  - Zhu, L. L., Huang, Y. E., Lin, Y. P., Huang, X. Y., Liu, H. Q., Mitzi, D. B., & Du, K. Z. (2019). Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron, 158, 445–448. https://doi.org/10.1016/j.poly.2018.11.026
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  - Khazaee, M., Sardashti, K., Chung, C. C., Sun, J. P., Zhou, H., Bergmann, E., … Mitzi, D. B. (2019). Dual-source evaporation of silver bismuth iodide films for planar junction solar cells. Journal of Materials Chemistry A, 7(5), 2095–2105. https://doi.org/10.1039/c8ta08679f
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  - Li, T., Dunlap-Shohl, W. A., Reinheimer, E. W., Le Magueres, P., & Mitzi, D. B. (2019). Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching. Chemical Science, 10(4), 1168–1175. https://doi.org/10.1039/c8sc03863e
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  - Dunlap-Shohl, W. A., Hill, I. G., Yan, Y., & Mitzi, D. B. (2018). Photovoltaic Effect in Indium(I) Iodide Thin Films. Chemistry of Materials, 30(22), 8226–8232. https://doi.org/10.1021/acs.chemmater.8b03593
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  - Ghadiri, E., Shin, D., Shafiee, A., Warren, W. S., & Mitzi, D. B. (2018). Grain-Resolved Ultrafast Photophysics in Cu₂BaSnS_{4- x}Se _x Semiconductors Using Pump-Probe Diffuse Reflectance Spectroscopy and Microscopy. Acs Applied Materials & Interfaces, 10(46), 39615–39623. https://doi.org/10.1021/acsami.8b12307
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  - Han, Q., Ding, J., Bai, Y., Li, T., Ma, J. Y., Chen, Y. X., … Hu, J. S. (2018). Carrier Dynamics Engineering for High-Performance Electron-Transport-Layer-free Perovskite Photovoltaics. Chem, 4(10), 2405–2417. https://doi.org/10.1016/j.chempr.2018.08.004
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  - Liu, C., Huhn, W., Du, K.-Z., Vazquez-Mayagoitia, A., Dirkes, D., You, W., … Blum, V. (2018). Tunable Semiconductors: Control over Carrier States and Excitations in Layered Hybrid Organic-Inorganic Perovskites. Physical Review Letters, 121(14), 146401. https://doi.org/10.1103/physrevlett.121.146401
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  - Wessler, G. C., Zhu, T., Sun, J. P., Harrell, A., Huhn, W. P., Blum, V., & Mitzi, D. B. (2018). Band Gap Tailoring and Structure-Composition Relationship within the Alloyed Semiconductor Cu2BaGe1- xSnxSe4. Chemistry of Materials, 30(18), 6566–6574. https://doi.org/10.1021/acs.chemmater.8b03380
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  - Teymur, B., Zhou, Y., Ngaboyamahina, E., Glass, J. T., & Mitzi, D. B. (2018). Solution-Processed Earth-Abundant Cu2BaSn(S,Se)4 Solar Absorber Using a Low-Toxicity Solvent. Chemistry of Materials, 30(17), 6116–6123. https://doi.org/10.1021/acs.chemmater.8b02556
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  - Li, T., Wang, X., Yan, Y., & Mitzi, D. B. (2018). Phase Stability and Electronic Structure of Prospective Sb-Based Mixed Sulfide and Iodide 3D Perovskite (CH3NH3)SbSI2. The Journal of Physical Chemistry Letters, 9(14), 3829–3833. https://doi.org/10.1021/acs.jpclett.8b01641
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  - Khazaee, M., Sardashti, K., Sun, J. P., Zhou, H., Clegg, C., Hill, I. G., … Mitzi, D. B. (2018). A Versatile Thin-Film Deposition Method for Multidimensional Semiconducting Bismuth Halides. Chemistry of Materials, 30(10), 3538–3544. https://doi.org/10.1021/acs.chemmater.8b01341
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  - Dunlap-Shohl, W. A., Barraza, E. T., Barrette, A., Gundogdu, K., Stiff-Roberts, A. D., & Mitzi, D. B. (2018). MAPbI3 Solar Cells with Absorber Deposited by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. Acs Energy Letters, 3(2), 270–275. https://doi.org/10.1021/acsenergylett.7b01144
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  - Barraza, E. T., Dunlap-Shohl, W. A., Mitzi, D. B., & Stiff-Roberts, A. D. (2018). Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. Journal of Electronic Materials, 47(2), 917–926. https://doi.org/10.1007/s11664-017-5814-0
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  - Zhou, Y., Shin, D., Ngaboyamahina, E., Han, Q., Parker, C. B., Mitzi, D. B., & Glass, J. T. (2018). Efficient and Stable Pt/TiO2/CdS/Cu2BaSn(S,Se)4 Photocathode for Water Electrolysis Applications. Acs Energy Letters, 3(1), 177–183. https://doi.org/10.1021/acsenergylett.7b01062
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  - Dunlap-Shohl, W. A., Daunis, T. B., Wang, X., Wang, J., Zhang, B., Barrera, D., … Mitzi, D. B. (2018). Room-temperature fabrication of a delafossite CuCrO2 hole transport layer for perovskite solar cells. Journal of Materials Chemistry A, 6(2), 469–477. https://doi.org/10.1039/c7ta09494a
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  - Liu, J., Han, Q., Bai, Y., Du, K. Z., Li, T., Ji, D., … Mitzi, D. B. (2017). Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes. Energy and Environmental Science, 10(11), 2365–2371. https://doi.org/10.1039/c7ee02272g
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  - Du, K. Z., Wang, X., Han, Q., Yan, Y., & Mitzi, D. B. (2017). Heterovalent B-Site Co-Alloying Approach for Halide Perovskite Bandgap Engineering. Acs Energy Letters, 2(10), 2486–2490. https://doi.org/10.1021/acsenergylett.7b00824
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  - Zhu, T., Huhn, W. P., Wessler, G. C., Shin, D., Saparov, B., Mitzi, D. B., & Blum, V. (2017). I2-II-IV-VI4 (I = Cu, Ag; II = Sr, Ba; IV = Ge, Sn; VI = S, Se): Chalcogenides for Thin-Film Photovoltaics. Chemistry of Materials, 29(18), 7868–7879. https://doi.org/10.1021/acs.chemmater.7b02638
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  - Xiao, Z., Du, K.-Z., Meng, W., Mitzi, D. B., & Yan, Y. (2017). Chemical Origin of the Stability Difference between Copper(I)- and Silver(I)-Based Halide Double Perovskites. Angewandte Chemie (International Ed. in English), 56(40), 12107–12111. https://doi.org/10.1002/anie.201705113
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  - Li, T., Dunlap-Shohl, W. A., Han, Q., & Mitzi, D. B. (2017). Melt Processing of Hybrid Organic-Inorganic Lead Iodide Layered Perovskites. Chemistry of Materials, 29(15), 6200–6204. https://doi.org/10.1021/acs.chemmater.7b02363
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  - Du, K.-Z., Tu, Q., Zhang, X., Han, Q., Liu, J., Zauscher, S., & Mitzi, D. B. (2017). Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity. Inorganic Chemistry, 56(15), 9291–9302. https://doi.org/10.1021/acs.inorgchem.7b01094
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  - Du, K.-Z., Meng, W., Wang, X., Yan, Y., & Mitzi, D. B. (2017). Bandgap Engineering of Lead-Free Double Perovskite Cs2 AgBiBr6 through Trivalent Metal Alloying. Angewandte Chemie (International Ed. in English), 56(28), 8158–8162. https://doi.org/10.1002/anie.201703970
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  - Meng, W., Wang, X., Xiao, Z., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Parity-Forbidden Transitions and Their Impact on the Optical Absorption Properties of Lead-Free Metal Halide Perovskites and Double Perovskites. The Journal of Physical Chemistry Letters, 8(13), 2999–3007. https://doi.org/10.1021/acs.jpclett.7b01042
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  - Xiao, Z., Du, K.-Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Correction to "Intrinsic Instability of Cs₂In(I)M(III)X₆ (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study". Journal of the American Chemical Society, 139(27), 9409. https://doi.org/10.1021/jacs.7b06199
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  - Shin, D., Saparov, B., & Mitzi, D. B. (2017). Defect Engineering in Multinary Earth-Abundant Chalcogenide Photovoltaic Materials. Advanced Energy Materials, 7(11). https://doi.org/10.1002/aenm.201602366
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  - Shin, D., Zhu, T., Huang, X., Gunawan, O., Blum, V., & Mitzi, D. B. (2017). Earth-Abundant Chalcogenide Photovoltaic Devices with over 5% Efficiency Based on a Cu₂ BaSn(S,Se)₄ Absorber. Advanced Materials (Deerfield Beach, Fla.), 29(24). https://doi.org/10.1002/adma.201606945
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  - Xiao, Z., Du, K.-Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Intrinsic Instability of Cs₂In(I)M(III)X₆ (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study. Journal of the American Chemical Society, 139(17), 6054–6057. https://doi.org/10.1021/jacs.7b02227
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  - Wallace, S. K., Mitzi, D. B., & Walsh, A. (2017). The steady rise of kesterite solar cells. Acs Energy Letters, 2(4), 776–779. https://doi.org/10.1021/acsenergylett.7b00131
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  - Xiao, Z., Meng, W., Wang, J., Mitzi, D. B., & Yan, Y. (2017). Searching for promising new perovskite-based photovoltaic absorbers: The importance of electronic dimensionality. Materials Horizons, 4(2), 206–216. https://doi.org/10.1039/c6mh00519e
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  - Younts, R., Duan, H.-S., Gautam, B., Saparov, B., Liu, J., Mongin, C., … Gundogdu, K. (2017). Efficient Generation of Long-Lived Triplet Excitons in 2D Hybrid Perovskite. Advanced Materials (Deerfield Beach, Fla.), 29(9). https://doi.org/10.1002/adma.201604278
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  - Shin, D., Ngaboyamahina, E., Zhou, Y., Glass, J. T., & Mitzi, D. B. (2016). Synthesis and Characterization of an Earth-Abundant Cu₂BaSn(S,Se)₄ Chalcogenide for Photoelectrochemical Cell Application. The Journal of Physical Chemistry Letters, 7(22), 4554–4561. https://doi.org/10.1021/acs.jpclett.6b02010
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  - Xiao, Z., Meng, W., Mitzi, D. B., & Yan, Y. (2016). Crystal Structure of AgBi₂I₇ Thin Films. The Journal of Physical Chemistry Letters, 7(19), 3903–3907. https://doi.org/10.1021/acs.jpclett.6b01834
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  - Chagarov, E., Sardashti, K., Haight, R., Mitzi, D. B., & Kummel, A. C. (2016). Density-functional theory computer simulations of CZTS0.25Se0.75 alloy phase diagrams. Journal of Chemical Physics, 145(6). https://doi.org/10.1063/1.4959591
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  - Dunlap-Shohl, W. A., Younts, R., Gautam, B., Gundogdu, K., & Mitzi, D. B. (2016). Effects of cd diffusion and doping in high-performance perovskite solar cells using CdS as electron transport layer. Journal of Physical Chemistry C, 120(30), 16437–16445. https://doi.org/10.1021/acs.jpcc.6b05406
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  - Shin, D., Saparov, B., Zhu, T., Huhn, W. P., Blum, V., & Mitzi, D. B. (2016). BaCu2Sn(S,Se)4: Earth-abundant chalcogenides for thin-film photovoltaics. Chemistry of Materials, 28(13), 4771–4780. https://doi.org/10.1021/acs.chemmater.6b01832
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  - Ke, W., Xiao, C., Wang, C., Saparov, B., Duan, H.-S., Zhao, D., … Yan, Y. (2016). Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells. Advanced Materials (Deerfield Beach, Fla.), 28(26), 5214–5221. https://doi.org/10.1002/adma.201600594
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  - Liu, X., Feng, Y., Cui, H., Liu, F., Hao, X., Conibeer, G., … Green, M. (2016). The current status and future prospects of kesterite solar cells: A brief review. Progress in Photovoltaics: Research and Applications, 24(6), 879–898. https://doi.org/10.1002/pip.2741
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  - Saparov, B., Sun, J. P., Meng, W., Xiao, Z., Duan, H. S., Gunawan, O., … Mitzi, D. B. (2016). Thin-Film Deposition and Characterization of a Sn-Deficient Perovskite Derivative Cs2SnI6. Chemistry of Materials, 28(7), 2315–2322. https://doi.org/10.1021/acs.chemmater.6b00433
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  - Saparov, B., & Mitzi, D. B. (2016). Organic-Inorganic Perovskites: Structural Versatility for Functional Materials Design. Chemical Reviews, 116(7), 4558–4596. https://doi.org/10.1021/acs.chemrev.5b00715
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  - Xiao, Z., Meng, W., Saparov, B., Duan, H.-S., Wang, C., Feng, C., … Yan, Y. (2016). Photovoltaic Properties of Two-Dimensional (CH3NH3)2Pb(SCN)2I2 Perovskite: A Combined Experimental and Density Functional Theory Study. The Journal of Physical Chemistry Letters, 7(7), 1213–1218. https://doi.org/10.1021/acs.jpclett.6b00248
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  - Hong, F., Saparov, B., Meng, W., Xiao, Z., Mitzi, D. B., & Yan, Y. (2016). Viability of Lead-Free Perovskites with Mixed Chalcogen and Halogen Anions for Photovoltaic Applications. Journal of Physical Chemistry C, 120(12), 6435–6441. https://doi.org/10.1021/acs.jpcc.6b00920
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  - Meng, W., Saparov, B., Hong, F., Wang, J., Mitzi, D. B., & Yan, Y. (2016). Alloying and Defect Control within Chalcogenide Perovskites for Optimized Photovoltaic Application. Chemistry of Materials, 28(3), 821–829. https://doi.org/10.1021/acs.chemmater.5b04213
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  - Tai, K. F., Gunawan, O., Kuwahara, M., Chen, S., Mhaisalkar, S. G., Huan, C. H. A., & Mitzi, D. B. (2016). Fill Factor Losses in Cu2ZnSn(SxSe1-x)4 Solar Cells: Insights from Physical and Electrical Characterization of Devices and Exfoliated Films. Advanced Energy Materials, 6(3). https://doi.org/10.1002/aenm.201501609
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  - Berry, J., Buonassisi, T., Egger, D. A., Hodes, G., Kronik, L., Loo, Y.-L., … Cahen, D. (2015). Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges. Advanced Materials (Deerfield Beach, Fla.), 27(35), 5102–5112. https://doi.org/10.1002/adma.201502294
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  - Saparov, B., Hong, F., Sun, J. P., Duan, H. S., Meng, W., Cameron, S., … Mitzi, D. B. (2015). Thin-Film Preparation and Characterization of Cs3Sb2I9: A Lead-Free Layered Perovskite Semiconductor. Chemistry of Materials, 27(16), 5622–5632. https://doi.org/10.1021/acs.chemmater.5b01989
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  - Loo, L., & Patel, P. (2015). Perovskite photovoltaics: David Mitzi addresses the promises and challenges. Mrs Bulletin, 40(8), 636–637. https://doi.org/10.1557/mrs.2015.176
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  - Abou-Ras, D., Edoff, M., Minemoto, T., Mitzi, D., & Romeo, A. (2015). Preface. Thin Solid Films, 582, 1. https://doi.org/10.1016/j.tsf.2015.01.001
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  - Bishop, D. M., McCandless, B. E., Haight, R., Mitzi, D. B., & Birkmire, R. W. (2015). Fabrication and electronic properties of CZTSe single crystals. Ieee Journal of Photovoltaics, 5(1), 390–394. https://doi.org/10.1109/JPHOTOV.2014.2363552
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  - Sardashti, K., Haight, R., Gokmen, T., Wang, W., Chang, L. Y., Mitzi, D. B., & Kummel, A. C. (2015). Impact of nanoscale elemental distribution in high-performance kesterite solar cells. Advanced Energy Materials, 5(10). https://doi.org/10.1002/aenm.201402180
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  - Park, H. H., Jayaraman, A., Heasley, R., Yang, C., Hartle, L., Mankad, R., … Gordon, R. G. (2014). Atomic layer deposition of Al-incorporated Zn(O,S) thin films with tunable electrical properties. Applied Physics Letters, 105(20). https://doi.org/10.1063/1.4901899
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  - Kim, J., Hiroi, H., Todorov, T. K., Gunawan, O., Kuwahara, M., Gokmen, T., … Mitzi, D. B. (2014). High efficiency Cu2ZnSn(S,Se)4 solar cells by applying a double In2S3/CdS emitter. Advanced Materials (Deerfield Beach, Fla.), 26(44), 7427–7431. https://doi.org/10.1002/adma.201402373
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  - Kim, J., Hiroi, H., Todorov, T. K., Gunawan, O., Kuwahara, M., Gokmen, T., … Mitzi, D. B. (2014). Solar Cells: High Efficiency Cu2 ZnSn(S,Se)4 Solar Cells by Applying a Double In2 S3 /CdS Emitter (Adv. Mater. 44/2014). Advanced Materials (Deerfield Beach, Fla.), 26(44), 7426. https://doi.org/10.1002/adma.201470303
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  - Gokmen, T., Gunawan, O., & Mitzi, D. B. (2014). Semi-empirical device model for Cu2ZnSn(S,Se)4 solar cells. Applied Physics Letters, 105(3). https://doi.org/10.1063/1.4890844
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  - Wang, W., Winkler, M. T., Gunawan, O., Gokmen, T., Todorov, T. K., Zhu, Y., & Mitzi, D. B. (2014). Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency. Advanced Energy Materials, 4(7). https://doi.org/10.1002/aenm.201301465
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  - Winkler, M. T., Wang, W., Gunawan, O., Hovel, H. J., Todorov, T. K., & Mitzi, D. B. (2014). Optical designs that improve the efficiency of Cu2ZnSn(S,Se) 4 solar cells. Energy and Environmental Science, 7(3), 1029–1036. https://doi.org/10.1039/c3ee42541j
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  - Haight, R., Shao, X., Wang, W., & Mitzi, D. B. (2014). Electronic and elemental properties of the Cu2ZnSn(S,Se) 4 surface and grain boundaries. Applied Physics Letters, 104(3). https://doi.org/10.1063/1.4862791
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  - Gunawan, O., Gokmen, T., & Mitzi, D. B. (2014). Suns- VOC characteristics of high performance kesterite solar cells. Journal of Applied Physics, 116(8). https://doi.org/10.1063/1.4893315
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  - Haight, R., Barkhouse, A., Wang, W., Luo, Y., Shao, X., Mitzi, D. B., … Sugimoto, H. (2014). CdS and Cd-free buffer layers on solution phase grown Cu 2ZnSn(SxSe1- x)4 :Band alignments and electronic structure determined with femtosecond ultraviolet photoelectron spectroscopy. Materials Research Society Symposium Proceedings, 1638. https://doi.org/10.1557/opl.2014.196
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  - Hiroi, H., Kim, J., Kuwahara, M., Todorov, T. K., Nair, D., Hopstaken, M., … Sugimoto, H. (2014). Over 12% efficiency Cu2ZnSn(SeS)4 solar cell via hybrid buffer layer. 2014 Ieee 40th Photovoltaic Specialist Conference, Pvsc 2014, 30–32. https://doi.org/10.1109/PVSC.2014.6925044
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  - Patel, P., & Mitzi, D. (2014). Perovskites in the spotlight. Mrs Bulletin, 39(9), 768–769. https://doi.org/10.1557/mrs.2014.200
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  - Todorov, T., Sugimoto, H., Gunawan, O., Gokmen, T., & Mitzi, D. B. (2014). High-efficiency devices with pure solution-processed Cu2 ZnSn(S,Se)4 Absorbers. Ieee Journal of Photovoltaics, 4(1), 483–485. https://doi.org/10.1109/JPHOTOV.2013.2287754
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  - Polizzotti, A., Repins, I. L., Noufi, R., Wei, S. H., & Mitzi, D. B. (2013). The state and future prospects of kesterite photovoltaics. Energy and Environmental Science, 6(11), 3171–3182. https://doi.org/10.1039/c3ee41781f
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  - Gokmen, T., Gunawan, O., & Mitzi, D. B. (2013). Minority carrier diffusion length extraction in Cu2ZnSn(Se,S) 4 solar cells. Journal of Applied Physics, 114(11). https://doi.org/10.1063/1.4821841
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  - Gokmen, T., Gunawan, O., Todorov, T. K., & Mitzi, D. B. (2013). Band tailing and efficiency limitation in kesterite solar cells. Applied Physics Letters, 103(10). https://doi.org/10.1063/1.4820250
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  - Mitzi, D. B., Gunawan, O., Todorov, T. K., & Barkhouse, D. A. R. (2013). Prospects and performance limitations for Cu-Zn-Sn-S-Se photovoltaic technology. Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences, 371(1996), 20110432. https://doi.org/10.1098/rsta.2011.0432
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  - Todorov, T. K., Gunawan, O., Gokmen, T., & Mitzi, D. B. (2013). Solution-processed Cu(In,Ga)(S,Se)2 absorber yielding a 15.2% efficient solar cell. Progress in Photovoltaics: Research and Applications, 21(1), 82–87. https://doi.org/10.1002/pip.1253
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  - Todorov, T. K., Tang, J., Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., & Mitzi, D. B. (2013). Beyond 11% effi ciency: Characteristics of state-of-the-art Cu 2ZnSn(S,Se)4Solar Cells. Advanced Energy Materials, 3(1), 34–38. https://doi.org/10.1002/aenm.201200348
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  - Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., & Mitzi, D. B. (2012). Hydrazine-processed Ge-substituted CZTSe solar cells. Chemistry of Materials, 24(23), 4588–4593. https://doi.org/10.1021/cm302881g
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  - Miller, D. W., Warren, C. W., Gunawan, O., Gokmen, T., Mitzi, D. B., & Cohen, J. D. (2012). Electronically active defects in the Cu 2ZnSn(Se,S) 4 alloys as revealed by transient photocapacitance spectroscopy. Applied Physics Letters, 101(14). https://doi.org/10.1063/1.4754834
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  - Graetzel, M., Janssen, R. A. J., Mitzi, D. B., & Sargent, E. H. (2012). Materials interface engineering for solution-processed photovoltaics. Nature, 488(7411), 304–312. https://doi.org/10.1038/nature11476
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  - Gunawan, O., Gokmen, T., Warren, C. W., Cohen, J. D., Todorov, T. K., Barkhouse, D. A. R., … Mitzi, D. B. (2012). Electronic properties of the Cu 2ZnSn(Se,S) 4 absorber layer in solar cells as revealed by admittance spectroscopy and related methods. Applied Physics Letters, 100(25). https://doi.org/10.1063/1.4729751
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  - Barkhouse, D. A. R., Haight, R., Sakai, N., Hiroi, H., Sugimoto, H., & Mitzi, D. B. (2012). Cd-free buffer layer materials on Cu 2ZnSn(S xSe 1-x) 4: Band alignments with ZnO, ZnS, and In 2S 3. Applied Physics Letters, 100(19). https://doi.org/10.1063/1.4714737
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  - Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., Todorov, T. K., & Mitzi, D. B. (2012). Low band gap liquid-processed CZTSe solar cell with 10.1% efficiency. Energy and Environmental Science, 5(5), 7060–7065. https://doi.org/10.1039/c2ee00056c
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  - Barkhouse, D. A. R., Gunawan, O., Gokmen, T., Todorov, T. K., & Mitzi, D. B. (2012). Device characteristics of a 10.1% hydrazine-processed Cu 2ZnSn(Se,S) 4 solar cell. Progress in Photovoltaics: Research and Applications, 20(1), 6–11. https://doi.org/10.1002/pip.1160
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  - Shin, B., Wang, K., Gunawan, O., Reuter, K. B., Chey, S. J., Bojarczuk, N. A., … Guha, S. (2011). High efficiency Cu 2ZnSn(S xSe 1-x) 4 thin film solar cells by thermal co-evaporation. Conference Record of the Ieee Photovoltaic Specialists Conference, 002510–002514. https://doi.org/10.1109/PVSC.2011.6186456
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  - Li, J., Mitzi, D. B., & Shenoy, V. B. (2011). Structure and electronic properties of grain boundaries in earth-abundant photovoltaic absorber Cu2ZnSnSe4. Acs Nano, 5(11), 8613–8619. https://doi.org/10.1021/nn203230g
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  - Cao, Q., Gunawan, O., Copel, M., Reuter, K. B., Chey, S. J., Deline, V. R., & Mitzi, D. B. (2011). Defects in Cu(In,Ga)Se 2 chalcopyrite semiconductors: A comparative study of material properties, defect states, and photovoltaic performance. Advanced Energy Materials, 1(5), 845–853. https://doi.org/10.1002/aenm.201100344
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  - Todorov, T., Gunawan, O., Chey, S. J., De Monsabert, T. G., Prabhakar, A., & Mitzi, D. B. (2011). Progress towards marketable earth-abundant chalcogenide solar cells. Thin Solid Films, 519(21), 7378–7381. https://doi.org/10.1016/j.tsf.2010.12.225
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  - Haight, R., Barkhouse, A., Gunawan, O., Shin, B., Copel, M., Hopstaken, M., & Mitzi, D. B. (2011). Band alignment at the Cu2 ZnSn (SxSe1-x) 4 /CdS interface. Applied Physics Letters, 98(25). https://doi.org/10.1063/1.3600776
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  - Mitzi, D. B., Gunawan, O., Todorov, T. K., Wang, K., & Guha, S. (2011). The path towards a high-performance solution-processed kesterite solar cell. Solar Energy Materials and Solar Cells, 95(6), 1421–1436. https://doi.org/10.1016/j.solmat.2010.11.028
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  - Wang, K., Shin, B., Reuter, K. B., Todorov, T., Mitzi, D. B., & Guha, S. (2011). Structural and elemental characterization of high efficiency Cu2 ZnSnS4 solar cells. Applied Physics Letters, 98(5). https://doi.org/10.1063/1.3543621
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  - Gunawan, O., Todorov, T. K., & Mitzi, D. B. (2010). Loss mechanisms in hydrazine-processed Cu2 ZnSn (Se,S) 4 solar cells. Applied Physics Letters, 97(23). https://doi.org/10.1063/1.3522884
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  - Yuan, M., Mitzi, D. B., Gunawan, O., Kellock, A. J., Chey, S. J., & Deline, V. R. (2010). Antimony assisted low-temperature processing of CuIn1 - XGa xSe2 - ySy solar cells. Thin Solid Films, 519(2), 852–856. https://doi.org/10.1016/j.tsf.2010.08.135
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  - Wang, K., Gunawan, O., Todorov, T., Shin, B., Chey, S. J., Bojarczuk, N. A., … Guha, S. (2010). Thermally evaporated Cu2 ZnSnS4 solar cells. Applied Physics Letters, 97(14). https://doi.org/10.1063/1.3499284
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  - Hibberd, C. J., Chassaing, E., Liu, W., Mitzi, D. B., Lincot, D., & Tiwari, A. N. (2010). Non-vacuum methods for formation of Cu(In, Ga)(Se, S)2 thin film photovoltaic absorbers. Progress in Photovoltaics: Research and Applications, 18(6), 434–452. https://doi.org/10.1002/pip.914
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  - Mitzi, D. (2010). Plain-as-dirt solar cell may lower material costs. Laser Focus World, 46(5), 9–9.
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  - Todorov, T. K., Reuter, K. B., & Mitzi, D. B. (2010). High-efficiency solar cell with Earth-abundant liquid-processed absorber. Advanced Materials (Deerfield Beach, Fla.), 22(20), E156–E159. https://doi.org/10.1002/adma.200904155
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  - Liu, W., Mitzi, D. B., Yuan, M., Kellock, A. J., Jay Chey, S., & Gunawan, O. (2010). 12% Efficiency CuIn(Se,S)2 photovoltaic device prepared using a hydrazine solution process. Chemistry of Materials, 22(3), 1010–1014. https://doi.org/10.1021/cm901950q
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  - Yuan, M., Mitzi, D. B., Liu, W., Kellock, A. J., Jay Chey, S., & Deline, V. R. (2010). Optimization of CIGS-based PV device through antimony doping. Chemistry of Materials, 22(2), 285–287. https://doi.org/10.1021/cm903428f
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  - Todorov, T., & Mitzi, D. B. (2010). Direct liquid coating of chalcopyrite light-absorbing layers for photovoltaic devices. European Journal of Inorganic Chemistry, (1), 17–28. https://doi.org/10.1002/ejic.200900837
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  - Jay Chey, S., Liu, W., Yuan, M., & Mitzi, D. B. (2009). Characterization of indium tin oxide and al-doped zinc oxide thin films deposited by confocal RF magnetron sputter deposition. Conference Record of the Ieee Photovoltaic Specialists Conference, 001149–001153. https://doi.org/10.1109/PVSC.2009.5411222
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  - Mitzi, D. B. (2009). Solution processing of chalcogenide semiconductors via dimensional reduction. Advanced Materials, 21(31), 3141–3158. https://doi.org/10.1002/adma.200802027
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  - Yuan, M., & Mitzi, D. B. (2009). Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films. Dalton Transactions (Cambridge, England : 2003), (31), 6078–6088. https://doi.org/10.1039/b900617f
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  - Mitzi, D. B. (2009). PHYS 485-Solution processing of CIGS absorber layers using a hydrazine-based approach. Abstracts of Papers of the American Chemical Society, 237.
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  - Mitzi, D. B., Yuan, M., Liu, W., Kellock, A. J., Jay Chey, S., Deline, V., & Schrott, A. G. (2008). A high-efficiency solution-deposited thin-film photovoltaic device. Advanced Materials, 20(19), 3657–3662. https://doi.org/10.1002/adma.200800555
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  - Mitzi, D. B. (2008). Solution Processing of Inorganic Materials. Solution Processing of Inorganic Materials, 1–497. https://doi.org/10.1002/9780470407790
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  - Mitzi, D. B. (2008). Solution Processing of Chalcogenide Semiconductors via Dimensional Reduction, 77–108. https://doi.org/10.1002/9780470407790.ch3
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  - Tromp, R. M., Afzali, A., Freitag, M., Mitzi, D. B., & Chen, Z. (2008). Novel strategy for diameter-selective separation and functionalization of single-wall carbon nanotubes. Nano Letters, 8(2), 469–472. https://doi.org/10.1021/nl072437b
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  - Kanatzidis, M. G., Poeppelmeier, K. R., Bobev, S., Guloy, A. M., Hwu, S. J., Lachgar, A., … Seshadri, R. (2008). Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences. Progress in Solid State Chemistry, 36(1–2), 1–133. https://doi.org/10.1016/j.progsolidstchem.2007.02.002
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  - Mitzi, D. B., & Afzali, A. (2007). Diels-alder adduct of pentacene and maleimide: Crystal growth and the influence of solvent molecules on structure and hydrogen bonding. Crystal Growth and Design, 7(4), 691–697. https://doi.org/10.1021/cg060559w
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  - Mitzi, D. B. (2007). N4H9Cu7S4: a hydrazinium-based salt with a layered Cu7S4- framework. Inorganic Chemistry, 46(3), 926–931. https://doi.org/10.1021/ic0621291
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  - Mitzi, D. B. (2007). Synthesis, structure, and properties of organic-inorganic perovskites and related materials, 48, 1–121. https://doi.org/10.1002/9780470166499.ch1
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  - Mitzi, D. B., Raoux, S., Schrott, A. G., Copel, M., Kellock, A., & Jordan-Sweet, J. (2006). Solution-based processing of the phase-change material KSb 5S8. Chemistry of Materials, 18(26), 6278–6282. https://doi.org/10.1021/cm0619510
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  - Mitzi, D. B., Copel, M., & Murray, C. E. (2006). High-mobility p-type transistor based on a spin-coated metal telluride semiconductor. Advanced Materials, 18(18), 2448–2452. https://doi.org/10.1002/adma.200600157
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  - Milliron, D. J., Mitzi, D. B., Copel, M., & Murray, C. E. (2006). Solution-processed metal chalcogenide films for p-type transistors. Chemistry of Materials, 18(3), 581–590. https://doi.org/10.1021/cm052300r
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  - Mitzi, D. B., Copel, M., Murray, C. E., Kosbar, L. L., & Afzali, A. (2005). Thin-film transistors based on spin-coated chalcogenide semiconductor channels. Proceedings Electrochemical Society, PV 2004-15, 189–199.
  - Mitzi, D. B. (2005). Polymorphic one-dimensional (N2H4)2ZnTe: soluble precursors for the formation of hexagonal or cubic zinc telluride. Inorganic Chemistry, 44(20), 7078–7086. https://doi.org/10.1021/ic050833w
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  - Knutson, J. L., Martin, J. D., & Mitzi, D. B. (2005). Tuning the band gap in hybrid tin iodide perovskite semiconductors using structural templating. Inorganic Chemistry, 44(13), 4699–4705. https://doi.org/10.1021/ic050244q
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  - Mitzi, D. B., Kosbar, L. L., Murray, C. E., Copel, M., & Afzali, A. (2004). High-mobility ultrathin semiconducting films prepared by spin coating. Nature, 428(6980), 299–303. https://doi.org/10.1038/nature02389
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  - Xu, Z., & Mitzi, D. B. (2003). [CH(3)(CH(2))(11)NH(3)]SnI(3): a hybrid semiconductor with MoO(3)-type tin(II) iodide layers. Inorganic Chemistry, 42(21), 6589–6591. https://doi.org/10.1021/ic0347081
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  - Xu, Z. T., & Mitzi, D. B. (2003). SnI42--based hybrid perovskites templated by multiple organic cations: Combining organic functionalities through noncovalent interactions. Chemistry of Materials, 15(19), 3632–3637. https://doi.org/10.1021/cm034267j
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  - Maxcy, K. R., Willett, R. D., Mitzi, D. B., & Afzali, A. (2003). Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online, 59(6). https://doi.org/10.1107/S1600536803007414
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  - Xu, Z., Mitzi, D. B., & Medeiros, D. R. (2003). [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic Chemistry, 42(5), 1400–1402. https://doi.org/10.1021/ic0261981
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  - Xu, Z., Mitzi, D. B., Dimitrakopoulos, C. D., & Maxcy, K. R. (2003). Semiconducting perovskites (2-XC6H4C2H4NH3)2SnI4 (X = F, Cl, Br): steric interaction between the organic and inorganic layers. Inorganic Chemistry, 42(6), 2031–2039. https://doi.org/10.1021/ic0261474
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  - Lee, Y., Mitzi, D. B., Barnes, P. W., & Vogt, T. (2003). Pressure-induced phase transitions and templating effect in three-dimensional organic-inorganic hybrid perovskites. Physical Review B Condensed Matter and Materials Physics, 68(2). https://doi.org/10.1103/PhysRevB.68.020103
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  - Mitzi, D. B., Dimitrakopoulos, C. D., Rosner, J., Medeiros, D. R., Xu, Z., & Noyan, C. (2002). Hybrid field-effect transistor based on a low-temperature melt-processed channel layer. Advanced Materials, 14(23), 1772–1776. https://doi.org/10.1002/1521-4095(20021203)14:23<1772::AID-ADMA1772>3.0.CO;2-Y
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  - Mitzi, D. B., Medeiros, D. R., & DeHaven, P. W. (2002). Low-temperature melt processing of organic-inorganic hybrid films. Chemistry of Materials, 14(7), 2839–2841. https://doi.org/10.1021/cm020264f
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  - Kagan, C. R., Afzali, A., Breen, T. L., Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2002). Solution deposition and patterning of organic and organic-inorganic thin film transistors. Abstracts of Papers of the American Chemical Society, 223, D73–D73.
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  - Maxcy, K. R., Mitzi, D. B., Afzali, A., & Willett, R. D. (2002). Benzylammonium tin(II) iodide based perovskites. Abstracts of Papers of the American Chemical Society, 223, A13–A13.
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  - Maxey, K. R., Mitzi, D. B., Afzali, A., & Willett, R. (2002). Benzylammonium TiN(II) iodide based perovskites. Abstracts of Papers of the American Chemical Society, 223, U656–U656.
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  - Mitzi, D. B., Medeiros, D. R., Dimitrakopoulos, C. D., Malenfant, P. R. L., Kosbar, L. L., Xu, Z. T., & DeHaven, P. W. (2002). Organic-inorganic perovskite semiconductors: Chemistry, properties, and device applications. Abstracts of Papers of the American Chemical Society, 223, C23–C23.
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  - Mitzi, D. B., Medeiros, D. R., & Malenfant, P. R. L. (2002). Intercalated organic-inorganic perovskites stabilized by fluoroaryl-aryl interactions. Inorganic Chemistry, 41(8), 2134–2145. https://doi.org/10.1021/ic011190x
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  - Mitzi, D. B. (2001). Templating and structural engineering in organic-inorganic perovskites. Journal of the Chemical Society, Dalton Transactions, (1), 1–12. https://doi.org/10.1039/b007070j
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  - Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2001). Structurally tailored organic-inorganic perovskites: Optical properties and solution-processed channel materials for thin-film transistors. Chemistry of Materials, 13(10), 3728–3740. https://doi.org/10.1021/cm010105g
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  - Mitzi, D. B. (2001). Thin-film deposition of organic-inorganic hybrid materials. Chemistry of Materials, 13(10), 3283–3298. https://doi.org/10.1021/cm0101677
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  - Kagan, C. R., Mitzi, D. B., Dimitrakopoulos, C. D., Breen, T. L., Afzali, A., & Kosbar, L. L. (2001). Organic-inorganic thin-film field effect transistors. Abstracts of Papers of the American Chemical Society, 221, U632–U632.
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  - Kagan, C. R., Mitzi, D. B., Dimitrakopoulos, C. D., Breen, T. L., Afzali, A., & Kosbar, L. L. (2001). Organic-inorganic perovskites as semiconducting channels in thin film transistors. Abstracts of Papers of the American Chemical Society, 221, U735–U735.
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  - Maxcy, K. R., Willett, R., Afzali, A., & Mitzi, D. B. (2001). Thioxanthene lead perovskite structure and optical properties. Abstracts of Papers of the American Chemical Society, 221, U657–U657.
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  - Mitzi, D. B., & Brock, P. (2001). Structure and optical properties of several organic-inorganic hybrids containing corner-sharing chains of bismuth iodide octahedra. Inorganic Chemistry, 40(9), 2096–2104. https://doi.org/10.1021/ic000622l
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  - Mitzi, D. B., Chondroudis, K., & Kagan, C. R. (2001). Organic-inorganic electronics. Ibm J. Res. Dev., 45, 29–46.
  - Mitzi, D. B., Dimitrakopoulos, C. D., & Kosbar, L. L. (2001). Organic-inorganic electronic devices based on hybrid perovskites. Annual Device Research Conference Digest, 185–186.
  - Mitzi, D. B. (2000). Organic-inorganic perovskites containing trivalent metal halide layers: the templating influence of the organic cation layer. Inorganic Chemistry, 39(26), 6107–6113. https://doi.org/10.1021/ic000794i
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  - Maxcy, K. R., Afzali, A., & Mitzi, D. B. (2000). Crystal growth of perovskites and chain compounds with complex organic cations. Abstracts of Papers of the American Chemical Society, 219, U861–U861.
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  - Chondroudis, K., & Mitzi, D. B. (2000). The use of ionic salt dyes as amorphous, thermally stable emitting layers in organic light-emitting diodes. Applied Physics Letters, 76(1), 58–60. https://doi.org/10.1063/1.125655
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  - Chondroudis, K., Mitzi, D. B., & Brock, P. (2000). Effect of thermal annealing on the optical and morphological properties of (AETH)PbX4 (X = Br, I) perovskite films prepared using single source thermal ablation. Chemistry of Materials, 12(1), 169–175. https://doi.org/10.1021/cm990516l
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  - Mitzi, D. B., Chondroudis, K., & Kagan, C. R. (1999). Design, Structure, and Optical Properties of Organic-Inorganic Perovskites Containing an Oligothiophene Chromophore. Inorganic Chemistry, 38(26), 6246–6256. https://doi.org/10.1021/ic991048k
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  - Kagan, C. R., Mitzi, D. B., & Dimitrakopoulos, C. D. (1999). Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science (New York, N.Y.), 286(5441), 945–947. https://doi.org/10.1126/science.286.5441.945
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  - Chondroudis, K., & Mitzi, D. B. (1999). Electroluminescence from an organic-inorganic perovskite incorporating a quaterthiophene dye within lead halide perovskite layers. Chemistry of Materials, 11(11), 3028–3030. https://doi.org/10.1021/cm990561t
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  - Mitzi, D. B. (1999). A layered solution crystal growth technique and the crystal structure of (C₆H₅C₂H₄NH₃) ₂PbCl₄. Journal of Solid State Chemistry, 145(2), 694–704.
  - Mitzi, D. B. (1999). A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3) 2PbCl4. Journal of Solid State Chemistry, 145(2), 694–704. https://doi.org/10.1006/jssc.1999.8281
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  - Mitzi, D. B., Prikas, M. T., & Chondroudis, K. (1999). Thin film deposition of organic-inorganic hybrid materials using a single source thermal ablation technique. Chemistry of Materials, 11(3), 542–544. https://doi.org/10.1021/cm9811139
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  - Mitzi, D. B., Liang, K. N., & Wang, S. M. (1998). Synthesis and characterization of [NH2C(I)=NH2](2)ASnI(5) with A = iodoformamidinium or formamidinium: The chemistry of cyanamide and tin(II) iodide in concentrated aqueous hydriodic acid solutions. Inorganic Chemistry, 37(2), 321–327. https://doi.org/10.1021/ic971332g
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  - Kossler, W. J., Dai, Y., Petzinger, K. G., Greer, A. J., Williams, D. L., Koster, E., … Mitzi, D. B. (1998). Transparency of the ab planes of Bi₂Sr₂CaCu₂O_8+δ to magnetic fields. Physical Review Letters, 80(3), 592–595.
  - Kossler, W. J., Dai, Y., Petzinger, K. G., Greer, A. J., Williams, D. L., Koster, E., … Mitzi, D. B. (1998). Transparency of the ab Planes of Bi2Sr2CaCu2O8+δto magnetic fields. Physical Review Letters, 80(3), 592–595. https://doi.org/10.1103/PhysRevLett.80.592
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  - Liang, K., Mitzi, D. B., & Prikas, M. T. (1998). Synthesis and Characterization of Organic-Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique. Chemistry of Materials, 10(1), 403–411. https://doi.org/10.1021/cm970568f
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  - Mitzi, D. B., & Liang, K. (1997). Synthesis, Resistivity, and Thermal Properties of the Cubic Perovskite NH2CH=NH2SnI3and Related Systems. Journal of Solid State Chemistry, 134(2), 376–381. https://doi.org/10.1006/jssc.1997.7593
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  - Mitzi, D. B., & Liang, K. N. (1997). Preparation and properties of(C4H9NH3)(2)EUI4: A luminescent organic-inorganic perovskite with a divalent rare-earth metal halide framework. Chemistry of Materials, 9(12), 2990–2995. https://doi.org/10.1021/cm970352d
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  - Wang, S. M., Mitzi, D. B., Landrum, G. A., Genin, H., & Hoffmann, R. (1997). Synthesis and solid state chemistry of CH3BiI2: A structure with an extended one-dimensional organometallic framework. Journal of the American Chemical Society, 119(4), 724–732. https://doi.org/10.1021/ja961753h
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  - Koutselas, I. B., Mitzi, D. B., Papavassiliou, G. C., Papaioannou, G. J., & Krautscheid, H. (1997). Optical and related properties and natural one-dimensional semiconductors based on PbI and SnI units. Synthetic Metals, 86(1–3 pt 3), 2171–2172. https://doi.org/10.1016/S0379-6779(97)81081-8
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  - Mitzi, D. B., & Liang, K. (1997). Preparation and Properties of (C₄H₉NH₃)₂EuI₄: A Luminescent Organic-Inorganic Perovskite with a Divalent Rare-Earth Metal Halide Framework. Chemistry of Materials, 9(12), 2990–2995.
  - Mitzi, D. B., & Wang, S. M. (1996). Layered group IVB metal halide organic-inorganic perovskites. Abstracts of Papers of the American Chemical Society, 211, 86-INOR.
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  - Mitzi, D. B. (1996). Synthesis, crystal structure, and optical and thermal properties of (C4H9NH3)(2)MI(4) (M=Ge, Sn, Pb). Chemistry of Materials, 8(3), 791–800. https://doi.org/10.1021/cm9505097
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  - Chen, B. H., Walker, D., Scott, B. A., & Mitzi, D. B. (1996). Synthesis and structure of a new perovskite, SrCuO 2.5. Journal of Solid State Chemistry, 121(2), 498–501. https://doi.org/10.1006/jssc.1996.0070
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  - Mitzi, D. B. (1996). Synthesis and Crystal Structure of the Alkylbismuth Diiodides: A Family of Extended One-Dimensional Organometallic Compounds. Inorganic Chemistry, 35(26), 7614–7619. https://doi.org/10.1021/ic961083g
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  - Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., & Guloy, A. M. (1995). Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets. Science (New York, N.Y.), 267(5203), 1473–1476. https://doi.org/10.1126/science.267.5203.1473
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  - Mitzi, D. B., Feild, C. A., Schlesinger, Z., & Laibowitz, R. B. (1995). Transport, optical, and magnetic properties of the conducting halide perovskite ch3nh3sni3. Journal of Solid State Chemistry, 114(1), 159–163. https://doi.org/10.1006/jssc.1995.1023
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  - Wang, S., Guloy, A., Mitzi, D. B., & Feild, C. A. (1995). Synthesis and Characterization of [NH2C(I)=NH2]3MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single (110) Perovskite Sheets. Journal of the American Chemical Society, 117(19), 5297–5302. https://doi.org/10.1021/ja00124a012
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  - Scott, B. A., Suard, E. Y., Tsuei, C. C., Mitzi, D. B., McGuire, T. R., Chen, B. H., & Walker, D. (1994). Layer dependence of the superconducting transition temperature of HgBa2Can-1CunO2n+2+δ. Physica C: Superconductivity and Its Applications, 230(3–4), 239–245. https://doi.org/10.1016/0921-4534(94)90835-4
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  - Takigawa, M., & Mitzi, D. B. (1994). NMR studies of spin excitations in superconducting Bi2Sr2CaCu2O8+ delta single crystals. Physical Review Letters, 73(9), 1287–1290. https://doi.org/10.1103/physrevlett.73.1287
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  - Tsuei, C. C., Gupta, A., Trafas, G., & Mitzi, D. (1994). Superconducting mercury-based cuprate films with a zero-resistance transition temperature of 124 Kelvin. Science (New York, N.Y.), 263(5151), 1259–1261. https://doi.org/10.1126/science.263.5151.1259
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  - Mitzi, D. B., Feild, C. A., Harrison, W. T. A., & Guloy, A. M. (1994). Conducting tin halides with a layered organic-based perovskite structure. Nature, 369(6480), 467–469. https://doi.org/10.1038/369467a0
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  - Wu, X. D., Fanton, J. G., Kino, G. S., Ryu, S., Mitzi, D. B., & Kapitulnik, A. (1993). Thermal diffusivity of Bi2Sr2CaCu2O8 single crystals. Physica C: Superconductivity and Its Applications, 218(3–4), 417–423. https://doi.org/10.1016/0921-4534(93)90044-Q
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  - Phelps, R. B., Akavoor, P., Kesmodel, L. L., Demuth, J. E., & Mitzi, D. B. (1993). Surface phonons on Bi2Sr2CaCu2O8+ delta. Physical Review. B, Condensed Matter, 48(17), 12936–12940. https://doi.org/10.1103/physrevb.48.12936
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  - Arribére, A., Pastoriza, H., Goffman, M. F., de la Cruz F, ., Mitzi, D. B., & Kapitulnik, A. (1993). Loss of interplane correlation in Bi2Sr2CaCu2O8 single crystals. Physical Review. B, Condensed Matter, 48(10), 7486–7491. https://doi.org/10.1103/physrevb.48.7486
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  - Harshman, D. R., Brandt, E. H., Fiory, A. T., Inui, M., Mitzi, D. B., Schneemeyer, L. F., & Waszczak, J. V. (1993). Longitudinal disordering of vortex lattices in anisotropic superconductors. Physical Review. B, Condensed Matter, 47(5), 2905–2908. https://doi.org/10.1103/physrevb.47.2905
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  - Wells, B. O., Shen, Z. X., Dessau, D. S., Spicer, W. E., Mitzi, D. B., Lombardo, L., … Arko, A. J. (1992). Evidence for k-dependent, in-plane anisotropy of the superconducting gap in Bi2Sr2CaCu2O8+ delta. Physical Review. B, Condensed Matter, 46(18), 11830–11834. https://doi.org/10.1103/physrevb.46.11830
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  - Borg, A., King, P. L., Pianetta, P., Lindau, I., Mitzi, D. B., Kapitulnik, A., … Bianconi, A. (1992). Ca 3d unoccupied states in Bi2Sr2CaCu2O8 investigated by Ca L2,3 x-ray-absorption near-edge structure. Physical Review. B, Condensed Matter, 46(13), 8487–8495. https://doi.org/10.1103/physrevb.46.8487
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  - Pastoriza, H., de la Cruz F, ., Mitzi, D. B., & Kapitulnik, A. (1992). Two-step transition towards the reversibility region in Bi2Sr2CaCu2O8- delta single crystals. Physical Review. B, Condensed Matter, 46(14), 9278–9281. https://doi.org/10.1103/physrevb.46.9278
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  - Lombardo, L. W., Mitzi, D. B., Kapitulnik, A., & Leone, A. (1992). Defect dependence of the irreversibility line in Bi2Sr2CaCu2O8 single crystals. Physical Review. B, Condensed Matter, 46(9), 5615–5620. https://doi.org/10.1103/physrevb.46.5615
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  - Safar, H., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1992). SQUID picovoltometry of single crystal Bi2Sr2CaCu2O8+ delta : Observation of the crossover from high-temperature Arrhenius to low-temperature vortex-glass behavior. Physical Review Letters, 68(17), 2672–2675. https://doi.org/10.1103/physrevlett.68.2672
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  - Dessau, D. S., Shen, Z., Wells, B. O., King, D. M., Spicer, W. E., Arko, A. J., … Kapitulnik, A. (1992). Nature of the high-binding-energy dip in the low-temperature photoemission spectra of Bi2Sr2CaCu2O8+ delta. Physical Review. B, Condensed Matter, 45(9), 5095–5098. https://doi.org/10.1103/physrevb.45.5095
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  - Tsuei, C. C., Chi, C. C., Frey, T., Mitzi, D. B., Kazyaka, T., Haugan, T., … Wu, M. K. (1992). A jelly-roll process for high temperature superconducting tapes and wires. Materials Chemistry and Physics, 32(1), 95–98. https://doi.org/10.1016/0254-0584(92)90253-5
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  - Yazyi, J., Arribére, A., Durán, C., de la Cruz, F., Mitzi, D. B., & Kapitulnik, A. (1991). Inter- and intraplane softening of the vortex structure in Bi2.1Sr1.9Ca0.9Cu2O8+δ: a two-step transition. Physica C: Superconductivity and Its Applications, 184(4–6), 254–258. https://doi.org/10.1016/0921-4534(91)90390-K
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  - Dessau, D. S., Wells, B. O., Shen, Z. X., Spicer, W. E., Arko, A. J., List, R. S., … Geballe, T. H. (1991). Search for a proximity effect induced gap in gold/high Tc junctions. Applied Physics Letters, 58(12), 1332–1334. https://doi.org/10.1063/1.104301
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  - Shen, Z., Dessau, D. S., Wells, B. O., Olson, C. G., Mitzi, D. B., Lombado, L., … Arko, A. J. (1991). Evidence of chemical-potential shift with hole doping in Bi2Sr2CaCu2O8+ delta. Physical Review. B, Condensed Matter, 44(21), 12098–12101. https://doi.org/10.1103/physrevb.44.12098
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  - Harshman, D. R., Kleiman, R. N., Inui, M., Espinosa, G. P., Mitzi, D. B., Kapitulnik, A., … Williams, D. L. (1991). Magnetic penetration depth and flux dynamics in single-crystal Bi2Sr2CaCu2O8+ delta. Physical Review Letters, 67(22), 3152–3155. https://doi.org/10.1103/physrevlett.67.3152
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  - Duran, C., Yazyi, J., de la Cruz F, ., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Flux-lattice melting, anisotropy, and the role of interlayer coupling in Bi-Sr-Ca-Cu-O single crystals. Physical Review. B, Condensed Matter, 44(14), 7737–7740. https://doi.org/10.1103/physrevb.44.7737
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  - Hsu, J. W., Mitzi, D. B., Kapitulnik, A., & Lee, M. (1991). In-plane dissipation maxima and vortex-line distortions in the resistive transitions of oxygen-doped Bi2Sr2CaCu2O8+ delta single crystals. Physical Review Letters, 67(15), 2095–2098. https://doi.org/10.1103/physrevlett.67.2095
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  - Walstedt, R. E., Bell, R. F., & Mitzi, D. B. (1991). Nuclear relaxation behavior of the superconducting cuprates: Bi2Sr2CaCu2O8. Physical Review. B, Condensed Matter, 44(14), 7760–7763. https://doi.org/10.1103/physrevb.44.7760
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  - Chan, L. P., Harshman, D. R., Lynn, K. G., Massidda, S., & Mitzi, D. B. (1991). Pair momentum distribution in Bi2Sr2CaCu2O8+ delta measured by positron annihilation: Existence and nature of the Fermi surface. Physical Review Letters, 67(10), 1350–1353. https://doi.org/10.1103/physrevlett.67.1350
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  - Dessau, D. S., Wells, B. O., Shen, Z., Spicer, W. E., Arko, A. J., List, R. S., … Kapitulnik, A. (1991). Anomalous spectral weight transfer at the superconducting transition of Bi2Sr2CaCu2O8+ delta. Physical Review Letters, 66(16), 2160–2163. https://doi.org/10.1103/physrevlett.66.2160
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  - Grier, D. G., Murray, C. A., Bolle, C. A., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Translational and bond-orientational order in the vortex lattice of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+ delta. Physical Review Letters, 66(17), 2270–2273. https://doi.org/10.1103/physrevlett.66.2270
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  - Parmigiani, F., Shen, Z. X., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1991). O 1s core levels in Bi2Sr2CaCu2O8+ delta single crystals. Physical Review. B, Condensed Matter, 43(4), 3085–3090. https://doi.org/10.1103/physrevb.43.3085
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  - Bolle, C. A., Gammel, P. L., Grier, D. G., Murray, C. A., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1991). Observation of a commensurate array of flux chains in tilted flux lattices in Bi-Sr-Ca-Cu-O single crystals. Physical Review Letters, 66(1), 112–115. https://doi.org/10.1103/physrevlett.66.112
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  - Dessau, D. S., Shen, Z. X., Wells, B. O., Spicer, W. E., List, R. S., Arko, A. J., … Schirber, J. E. (1990). Electronic structure of the gold/Bi2Sr2CaCu 2O8 and gold/EuBa2Cu3O 7-δ interfaces as studied by photoemission spectroscopy. Applied Physics Letters, 57(3), 307–309. https://doi.org/10.1063/1.104219
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  - Lindberg, P. A. P., Wells, B. O., Shen, Z. X., Dessau, D. S., Lindau, I., Spicer, W. E., … Kapitulnik, A. (1990). Interaction of overlayers of Al and Rb with single-crystalline surfaces of Bi2Sr2CaCu2O8. Journal of Applied Physics, 67(5), 2667–2670. https://doi.org/10.1063/1.345480
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  - Wells, B. O., Shen, Z., Dessau, D. S., Spicer, W. E., Olson, C. G., Mitzi, D. B., … Arko, A. (1990). Angle-resolved-photoemission study of Bi2Sr2CaCu2O8+ delta : Metallicity of the Bi-O plane. Physical Review Letters, 65(24), 3056–3059. https://doi.org/10.1103/physrevlett.65.3056
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  - BISHOP, D. J., GAMMEL, P. L., MURRAY, C. A., MITZI, D. B., & KAPITULNIK, A. (1990). OBSERVATION OF AN HEXATIC VORTEX GLASS IN FLUX LATTICES OF THE HIGH-TC SUPERCONDUCTOR BI2.1SR1.9CA0.9CU2O8+DELTA. Annals of the New York Academy of Sciences, 581, 77–87.
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  - Ferrari, M. J., Johnson, M., Wellstood, F. C., Clarke, J., Mitzi, D., Rosenthal, P. A., … Beasley, M. R. (1990). Ferrari et al. reply. Physical Review Letters, 65(2), 279. https://doi.org/10.1103/physrevlett.65.279
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  - Murray, C. A., Gammel, P. L., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1990). Observation of a hexatic vortex glass in flux lattices of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+ delta. Physical Review Letters, 64(19), 2312–2315. https://doi.org/10.1103/physrevlett.64.2312
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  - Kim, J. H., Bozovic, I., Mitzi, D. B., Kapitulnik, A., & Harris, J. S. (1990). Optical anisotropy of Bi2Sr2CaCu2O8. Physical Review. B, Condensed Matter, 41(10), 7251–7253. https://doi.org/10.1103/physrevb.41.7251
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  - Mitzi, D. B., Lombardo, L. W., Kapitulnik, A., Laderman, S. S., & Jacowitz, R. D. (1990). Growth and properties of oxygen- and ion-doped Bi2Sr2CaCu2O8+ delta single crystals. Physical Review. B, Condensed Matter, 41(10), 6564–6574. https://doi.org/10.1103/physrevb.41.6564
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  - Harshman, D. R., Kleiman, R. N., Haddon, R. C., Chichester-Hicks, S. V., Kaplan, M. L., Rupp, L. W., … Mitzi, D. B. (1990). Magnetic penetration depth in the organic superconductor kappa -. Physical Review Letters, 64(11), 1293–1296. https://doi.org/10.1103/physrevlett.64.1293
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  - Ferrari, M. J., Johnson, M., Wellstood, F. C., Clarke, J., Mitzi, D., Rosenthal, P. A., … Beasley, M. R. (1990). Distribution of flux-pinning energies in YBa2Cu3O7- delta and Bi2Sr2CaCu2O8+ delta from flux noise. Physical Review Letters, 64(1), 72–75. https://doi.org/10.1103/physrevlett.64.72
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  - Fanton, J. T., Mitzi, D. B., Kapitulnik, A., Khuri-Yakub, B. T., Kino, G. S., Gazit, D., & Feigelson, R. S. (1989). Photothermal measurements of high Tc superconductors. Applied Physics Letters, 55(6), 598–599. https://doi.org/10.1063/1.101843
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  - Lindberg, P. A. P., Shen, Z. X., Wells, B. O., Dessau, D. S., Borg, A., Lindau, I., … Kapitulnik, A. (1989). Spectroscopic evidence of two-dimensional character of the 90 K Bi 2(Sr,La,Ca)3Cu2O8 superconductors. Applied Physics Letters, 55(11), 1141–1143. https://doi.org/10.1063/1.101889
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  - Lindberg, P. A., Shen, Z., Wells, B. O., Dessau, D. S., Ellis, W. P., Borg, A., … Kapitulnik, A. (1989). Photoemission study of absorption mechanisms in Bi2.0Sr1.8Ca0.8La0.3Cu2.1O8+ delta, BaBiO3, and Nd1.85Ce0.15CuO4. Physical Review. B, Condensed Matter, 40(13), 8840–8843. https://doi.org/10.1103/physrevb.40.8840
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  - Lindberg, P. A., Shen, Z., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1989). Electronic structure of clean and Ag-covered single-crystalline Bi2Sr2CuO6. Physical Review. B, Condensed Matter, 40(13), 8769–8773. https://doi.org/10.1103/physrevb.40.8769
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  - Lindberg, P. A., Shen, Z., Dessau, D. S., Wells, B. O., Mitzi, D. B., Lindau, I., … Kapitulnik, A. (1989). Energy dispersions of single-crystalline Bi2.0Sr1.8Ca0.8La0.3Cu2.1O8+ delta superconductors determined using angle-resolved photoelectron spectroscopy. Physical Review. B, Condensed Matter, 40(7), 5169–5171. https://doi.org/10.1103/physrevb.40.5169
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  - Wells, B. O., Lindberg, P. A., Shen, Z., Dessau, D. S., Spicer, W. E., Lindau, I., … Kapitulnik, A. (1989). Valence-band states in Bi2(Ca,Sr,La)3Cu2O8. Physical Review. B, Condensed Matter, 40(7), 5259–5262. https://doi.org/10.1103/physrevb.40.5259
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  - Lindberg, P. A. P., Shen, Z. X., Dessau, D. S., Wells, B. O., Borg, A., Ellis, W., … Kapitulnik, A. (1989). The electronic structure of Bi2.0Sr1.8La0.3Ca0.8Cu2.1O8+δ superconductors studied using ultraviolet and X-ray photoelectron spectroscopy. Physica C: Superconductivity and Its Applications, 159(5), 649–653. https://doi.org/10.1016/0921-4534(89)91299-9
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  - Urbach, J. S., Mitzi, D. B., Kapitulnik, A., Wei, J. Y., & Morris, D. E. (1989). Low-temperature specific heat of single-crystal Bi2CaSr2Cu2O8 and Tl2Ca2Ba2Cu3O10. Physical Review. B, Condensed Matter, 39(16), 12391–12394. https://doi.org/10.1103/physrevb.39.12391
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  - Shen, Z., Lindberg, P. A., Dessau, D. S., Lindau, I., Spicer, W. E., Mitzi, D. B., … Kapitulnik, A. (1989). Photoelectron energy-loss study of the Bi2CaSr2Cu2O8 superconductor. Physical Review. B, Condensed Matter, 39(7), 4295–4298. https://doi.org/10.1103/physrevb.39.4295
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  - Kuiper, P., Grioni, M., Sawatzky, G. A., Mitzi, D. B., Kapitulnik, A., Santaniello, A., … Thiry, P. (1989). Symmetry of the oxygen hole states in Bi2Sr2CaCu2O8 investigated by XAS. Physica C: Superconductivity and Its Applications, 157(2), 260–262. https://doi.org/10.1016/0921-4534(89)90012-9
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  - Lindberg, P. A., Shen, Z., Wells, B. O., Dessau, D. S., Mitzi, D. B., Lindau, I., … Kapitulnik, A. (1989). Reaction of Rb and oxygen overlayers with single-crystalline Bi2Sr2CaCu2O8+ delta superconductors. Physical Review. B, Condensed Matter, 39(4), 2890–2893. https://doi.org/10.1103/physrevb.39.2890
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  - Lee, M., Mitzi, D. B., Kapitulnik, A., & Beasley, M. R. (1989). Electron tunneling and the energy gap in Bi2Sr2CaCu2Ox. Physical Review. B, Condensed Matter, 39(1), 801–803. https://doi.org/10.1103/physrevb.39.801
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  - Lindberg, P. A. P., Shen, Z. X., Hwang, J., Shih, C. K., Lindau, I., Spicer, W. E., … Kapitulnik, A. (1989). Electronic structure of the La1 + xBa2 - xCu3O7 + δ system studied by photoelectron spectroscopy. Solid State Communications, 69(1), 27–31. https://doi.org/10.1016/0038-1098(89)90020-3
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  - Lindberg, P. A. P., Shen, Z. X., Lindau, I., Spicer, W. E., Mitzi, D. B., & Kapitulnik, A. (1989). Photoemission study of the electronic structure (Pr0.2La0.8)(Ba1.875La0.125)Cu3O7-gd. Solid State Communications, 72(6), 575–578. https://doi.org/10.1016/0038-1098(89)91036-3
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  - Newsam, J. M., Jacobson, A. J., Goshorn, D. P., Lewandowski, J. T., Mitzi, D. B., Kapitulnik, A., … Yelon, W. B. (1989). Orthorhombic and tetragonal structures in the La(Ba2-yLay)Cu3O7-x system. Solid State Ionics, 32–33(PART 2), 1064–1079. https://doi.org/10.1016/0167-2738(89)90399-8
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  - Kirillov, D., Bozovic, I., Geballe, T. H., Kapitulnik, A., & Mitzi, D. B. (1988). Raman scattering spectra of superconducting Bi2Sr2CaCu2O8 single crystals. Physical Review. B, Condensed Matter, 38(16), 11955–11957. https://doi.org/10.1103/physrevb.38.11955
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  - Kirk, M. D., Nogami, J., Baski, A. A., Mitzi, D. B., Kapitulnik, A., Geballe, T. H., & Quate, C. F. (1988). The Origin of the Superstructure in Bi2Sr2CaCu2O8+dgr as Revealed by Scanning Tunneling Microscopy. Science (New York, N.Y.), 242(4886), 1673–1675. https://doi.org/10.1126/science.242.4886.1673
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  - Lindberg, P. A. P., Shen, Z. X., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1988). Surface structure of Bi2Sr2CaCu2O 8+δ high-temperature superconductors studied using low-energy electron diffraction. Applied Physics Letters, 53(25), 2563–2565. https://doi.org/10.1063/1.100532
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  - Shen, Z., Lindberg, P. A., Wells, B. O., Mitzi, D. B., Lindau, I., Spicer, W. E., & Kapitulnik, A. (1988). Valence-band and core-level photoemission study of single-crystal Bi2CaSr2Cu2O8 superconductors. Physical Review. B, Condensed Matter, 38(16), 11820–11823. https://doi.org/10.1103/physrevb.38.11820
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  - Mitzi, D. B., Feffer, P. T., Newsam, J. M., Webb, D. J., Klavins, P., Jacobson, A. J., & Kapitulnik, A. (1988). Site-selective doping and superconductivity in (La1-yPry)(Ba2-xLax)Cu3O7+ delta. Physical Review. B, Condensed Matter, 38(10), 6667–6676. https://doi.org/10.1103/physrevb.38.6667
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  - Newsam, J. (1988). Orthorhombic and tetragonal structures in the La(La/Ba)2Cu3O9−δ system. Solid State Ionics, 26(2), 168–168. https://doi.org/10.1016/0167-2738(88)90150-6
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  - Kirk, M. D., Nogami, J., Baski, A. A., Mitzi, D. B., Kapitulnik, A., Geballe, T. H., & Quate, C. F. (1988). The origin of the superstructure in Bi₂Sr₂CaCu ₂O_8+δ as revealed by scanning tunneling microscopy. Science, 242(4886), 1673–1675.
  - Bozovic, I., Mitzi, D., Beasley, M., Kapitulnik, A., Geballe, T., Perkowitz, S., … Yom, S. S. (1987). Vibrational spectra and lattice instabilities in the high-Tc superconductors YBa2Cu3O7 and GdBa2Cu3O7. Physical Review. B, Condensed Matter, 36(7), 4000–4002. https://doi.org/10.1103/physrevb.36.4000
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  - Kirk, M. D., Smith, D. P., Mitzi, D. B., Sun, J. Z., Webb, D. J., Char, K., … Quate, C. F. (1987). Point-contact electron tunneling into the high-Tc superconductor Y-Ba-Cu-O. Physical Review. B, Condensed Matter, 35(16), 8850–8852. https://doi.org/10.1103/physrevb.35.8850
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  - Naito, M., Smith, D. P., Kirk, M. D., Oh, B., Hahn, M. R., Char, K., … Quate, C. F. (1987). Electron-tunneling studies of thin films of high-Tc superconducting La-Sr-Cu-O. Physical Review. B, Condensed Matter, 35(13), 7228–7231. https://doi.org/10.1103/physrevb.35.7228
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  - Sun, J. Z., Webb, D. J., Naito, M., Char, K., Hahn, M. R., Hsu, J. W., … Kapitulnik, A. (1987). Superconductivity and magnetism in the high-Tc superconductor YBaCuO. Physical Review Letters, 58(15), 1574–1576. https://doi.org/10.1103/physrevlett.58.1574
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  - Laibowitz, R. B., & Mitzi, D. B. (1984). CHANNEL SQUID. Ibm Technical Disclosure Bulletin, 26(11), 5775–5776.
  - Wallace, S. K., Svane, K. L., Huhn, W. P., Zhu, T., Mitzi, D. B., Blum, V., & Walsh, A. (n.d.). Candidate photoferroic absorber materials for thin-film solar cells from naturally occurring minerals: enargite, stephanite, and bournonite. Sustainable Energy & Fuels, 1(6), 1339–1350. https://doi.org/10.1039/c7se00277g
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- Book Sections
  - Gunawan, O., Gokmen, T., & Mitzi, D. B. (2015). Device Characteristics of Hydrazine-Processed CZTSSe. In Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells (pp. 387–411). https://doi.org/10.1002/9781118437865.ch17
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  - Mitzi, D. B. (2008). Preface. https://doi.org/10.1002/9780470407790
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- Conference Papers
  - Gunawan, O., Pae, S. R., Bishop, D. M., Shin, B., Virgus, Y., & Mitzi, D. B. (2020). Carrier-Resolved Photo-Hall Effect: Unlocking a 140-year-old secret in Hall effect. In Conference Record of the Ieee Photovoltaic Specialists Conference (Vol. 2020-June, pp. 2126–2129). https://doi.org/10.1109/PVSC45281.2020.9300483
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  - Jiang, T., Bai, Y., Han, Q., Mitzi, D., & Therien, M. (2018). How to turn iron into ruthenium. In Abstracts of Papers of the American Chemical Society (Vol. 256). Boston, MA: AMER CHEMICAL SOC.
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  - Mitzi, D. (2018). Halide perovskites beyond CH3NH3PbI3: Structural diversity and opportunities for semiconductor design. In Abstracts of Papers of the American Chemical Society (Vol. 255). New Orleans, LA: AMER CHEMICAL SOC.
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  - Stiff-Roberts, A. D., Mitzi, D. B., Barraza, E. T., & Dunlap-Shohl, W. A. (2018). Resonant infrared matrix-assisted pulsed laser evaporation of hybrid perovskites. In Optics Infobase Conference Papers (Vol. Part F107-NOMA 2018). https://doi.org/10.1364/NOMA.2018.NoM4D.2
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  - Keenan, E., Hu, J., Zhi, J., Mitzi, D., & You, W. (2017). Diffusion of cations in 2D/3D perovskite films made by melt infiltration. In Abstracts of Papers of the American Chemical Society (Vol. 253). San Francisco, CA: AMER CHEMICAL SOC.
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  - Gunawan, O., Gokmen, T., & Mitzi, D. B. (2015). High intensity and integrated Suns-Voc characterization of high performance kesterite solar cells. In 2015 Ieee 42nd Photovoltaic Specialist Conference, Pvsc 2015. https://doi.org/10.1109/PVSC.2015.7355690
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  - Mitzi, D. (2013). Solution-processing of high-performance CZTS devices for photovoltaic application. In Abstracts of Papers of the American Chemical Society (Vol. 245). New Orleans, LA: AMER CHEMICAL SOC.
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  - Mitzi, D. B., Todorov, T. K., Gunawan, O., Barkhouse, A. R., Bag, S., Qiu, X., … Miyamoto, H. (2011). Slurry-based processing of high-performance CZTSSe photovoltaic absorber layers. In Acs National Meeting Book of Abstracts.
  - Mitzi, D. B., Todorov, T. K., Gunawan, O., Yuan, M., Cao, Q., Liu, W., … Fogel, K. E. (2010). Torwards marketable efficiency solution-processed kesterite and chalcopyrite photovoltaic devices. In Conference Record of the Ieee Photovoltaic Specialists Conference (pp. 640–645). https://doi.org/10.1109/PVSC.2010.5616865
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  - Liu, W., Mitzi, D. B., Chey, S. J., & Kellock, A. (2009). CuIn(Se,S)2 absorbers processed using a hydrazine-based solution approach. In Materials Research Society Symposium Proceedings (Vol. 1123, pp. 117–122).
  - Mitzi, D. B., Yuan, M., Liu, W., Kellock, A. J., Chey, S. J., Gignac, L., & Schrott, A. G. (2009). Hydrazine-based deposition route for device-quality CIGS films. In Thin Solid Films (Vol. 517, pp. 2158–2162). https://doi.org/10.1016/j.tsf.2008.10.079
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  - Chey, S. J., Wei, L., Min, Y., & Mitzi, D. B. (2009). CHARACTERIZATION OF INDIUM TIN OXIDE AND AL-DOPED ZINC OXIDE THIN FILMS DEPOSITED BY CONFOCAL RF MAGNETRON SPUTTER DEPOSITION. In 2009 34th Ieee Photovoltaic Specialists Conference, Vols 1 3 (pp. 29–33). Philadelphia, PA: IEEE.
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  - Mitzi, D. B., Min Yuan, ., Wei Liu, ., Kellock, A., Chey, S. J., Schrott, A., & Deline, V. (2008). Solution processing of CIGS absorber layers using a hydrazine-based approach. In Conference Record of the Ieee Photovoltaic Specialists Conference. https://doi.org/10.1109/PVSC.2008.4922730
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  - Milliron, D. J., & Mitzi, D. B. (2006). Solution processed metal chalcogenide thin films for flexible and large scale electronics. In Acs National Meeting Book of Abstracts (Vol. 231).
  - Mitzi, D. B., Milliron, D. J., Copel, M., Murray, C., & Kosbar, L. (2005). High mobility solution-deposited chalcogenide films for flexible applications. In 2005 Ieee Vlsi Tsa International Symposium on Vlsi Technology Vlsi Tsa Tech, Proceedings of Technical Papers (pp. 41–44). https://doi.org/10.1109/VTSA.2005.1497075
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  - Mitzi, D. B., Xu, Z. T., Dimitrakopoulos, C. D., & Medeiros, D. R. (2003). Structures, properties and devices based on hybrid perovskites and related materials. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U85–U85). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.
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  - Xu, Z. T., & Mitzi, D. (2003). New structural motifs in semiconducting organic-inorganic perovskites. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U94–U94). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.
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  - Xu, Z. T., Mitzi, D., & Dimitrakopoulos, C. D. (2003). Crystal and electronic structure correlation in organic-inorganic perovskites. In Abstracts of Papers of the American Chemical Society (Vol. 225, pp. U87–U87). NEW ORLEANS, LOUISIANA: AMER CHEMICAL SOC.
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  - Mitzi, D. B., & Chondroudis, K. (2001). Crystal structure and properties of dye-containing organic- inorganic perovskites. In Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals (Vol. 356, pp. 549–558). https://doi.org/10.1080/10587250108023733
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  - Takigawa, M., & Mitzi, D. B. (1994). NMR studies of spin dynamics in cuprates. In Journal of Low Temperature Physics (Vol. 95, pp. 89–93). https://doi.org/10.1007/BF00754926
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  - Pastoriza, H., Arribere, A., Goffman, M. F., de la Cruz, F., Mitzi, D. B., & Kapitulnik, A. (1994). Evidence for the quasi-two dimensional behavior of the vortex structure in Bi2Sr2CaCu2O8 single crystals. In Physica B: Physics of Condensed Matter (Vol. 194–196, pp. 2227–2228). https://doi.org/10.1016/0921-4526(94)91613-6
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  - Renner, C., Fischer, ., Kent, A. D., Mitzi, D. B., & Kapitulnik, A. (1994). Spatially resolved vacuum tunneling spectroscopy on Bi2Sr2CaCu2O8 by STM at 4.8K. In Physica B: Physics of Condensed Matter (Vol. 194–196, pp. 1689–1690). https://doi.org/10.1016/0921-4526(94)91344-7
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  - Hallen, H. D., Hess, H. F., Chang, A. M., Pfeiffer, L. N., West, K. W., & Mitzi, D. B. (1993). High-resolution scanning hall probe microscopy. In Proceedings of Spie the International Society for Optical Engineering (Vol. 1855, pp. 152–157). https://doi.org/10.1117/12.146371
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  - Duran, C., Yazyi, J., Arribere, A., De La Cruz, F., Bishop, D. J., Mitzi, D. B., & Kapitulnik, A. (1992). Superconducting interlayer decoupling and softening of the flux line structure in BSCCO single crystals. In Superconductor Science and Technology (Vol. 5). https://doi.org/10.1088/0953-2048/5/1S/060
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  - Bishop, D. J., Gammel, P. L., Murray, C. A., Mitzi, D. B., & Kapitulnik, A. (1991). Observation of an hexatic vortex glass in flux lattices of the high-Tc superconductor Bi2.1Sr1.9Ca0.9Cu2O8+δ. In Physica B: Physics of Condensed Matter (Vol. 169, pp. 72–79). https://doi.org/10.1016/0921-4526(91)90210-6
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  - Chan, L. P., Harshman, D. R., Lynn, K. G., Massidda, S., & Mitzi, D. B. (1991). Evidence for a fermi surface in Bi2Sr2CaCu2O8+δ measured by positron 2D-ACAR. In Journal of Physics and Chemistry of Solids (Vol. 52, pp. 1557–1567). https://doi.org/10.1016/0022-3697(91)90140-U
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  - Dessau, D. S., Shen, Z. X., Wells, B. O., Spicer, W. E., List, R. S., Arko, A. J., … Gebaiie, T. H. (1991). The gold/high temperature superconductor interface; metallicity of the near surface region and a search for the proximity effect. In Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films (Vol. 9, pp. 383–389). https://doi.org/10.1116/1.577418
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  - Bishop, D. J., Gammel, P. L., Murray, C. A., Mitzi, D. B., & Kapitulnik, A. (1990). Observation of an Hexatic Vortex Glass in Flux Lattices of the High Tc Superconductor Bi2.1Sr1.9Ca0.9Cu2O8+§. In Annals of the New York Academy of Sciences (Vol. 581, pp. 77–87). https://doi.org/10.1111/j.1749-6632.1990.tb22701.x
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  - FANTON, J. T., KAPITULNIK, A., MITZI, D. B., KHURIYAKUB, B. T., & KINO, G. S. (1990). PHOTOTHERMAL MEASUREMENTS OF HIGH-TC SUPERCONDUCTORS. In J. C. MURPHY, L. C. AAMODT, J. W. M. SPICER, & B. S. H. ROYCE (Eds.), Photoacoustic and Photothermal Phenomena Ii (Vol. 62, pp. 202–204). BALTIMORE, MD: SPRINGER-VERLAG BERLIN.
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  - KAPITULNIK, A., & MITZI, D. B. (1990). GROWTH AND PROPERTIES OF OXYGEN DOPED BI2SR2CACU2O8+DELTA SINGLE-CRYSTALS. In R. NICOLSKY (Ed.), Proceedings of the Ictps 90 International Conference on Transport Properties of Superconductors (Vol. 25, pp. 491–501). RIO DE JANEIRO, BRAZIL: WORLD SCIENTIFIC PUBL CO PTE LTD.
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  - WELLS, B. O., LINDBERG, P. A. P., SHEN, Z. X., DESSAU, D. S., SPICER, W. E., LINDAU, I., … KAPITULNIK, A. (1990). NATURE OF THE VALENCE BAND STATES IN BI2(CA,SR,LA)3CU2O8. In R. L. STOCKBAUER, S. V. KRISHNASWAMY, & R. L. KURTZ (Eds.), High Tc Superconducting Thin Films : Processing, Characterization, and Applications (Vol. 200, pp. 36–41). BOSTON, MA: AIP PRESS.
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  - Lindberg, P. A. P., Shen, Z. X., Dessau, D. S., Wells, B. O., Borg, A., Mitzi, D. B., … Kapitulnik, A. (1989). Electronic structure of single crystalline Bi2(Sr,Ca,La)3Cu2O8. In Physica C: Superconductivity and Its Applications (Vol. 162–164, pp. 1313–1314). https://doi.org/10.1016/0921-4534(89)90709-0
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