Journal ArticleSensors (Basel, Switzerland) · February 2015
Gold nanostars (AuNSs) are unique systems that can provide a novel multifunctional nanoplatform for molecular sensing and diagnostics. The plasmonic absorption band of AuNSs can be tuned to the near infrared spectral range, often referred to as the "tissue ...
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Journal ArticleACS Nano · September 28, 2010
Responsive biomaterials play important roles in imaging, diagnostics, and therapeutics. Polymeric nanoparticles (NPs) containing hydrophobic and hydrophilic segments are one class of biomaterial utilized for these purposes. The incorporation of luminescent ...
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Journal ArticleLangmuir : the ACS journal of surfaces and colloids · May 2008
Polymer bridging between surfaces plays an important role in a range of fundamental processes in the material and life sciences. Bridges formed by main-chain reversible polymers differ from their covalent analogs in that they can dynamically adjust their s ...
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Journal ArticleJournal of the Royal Society, Interface · April 2007
A family of hybrid polymer gels is described, in which covalent cross-links create a permanent, stiff scaffold onto which reversible metal-ligand coordinative cross-links are added. The reversible metal-ligand interactions are shown to bear mechanical stre ...
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ConferenceAnnual Technical Conference ANTEC Conference Proceedings · July 10, 2006
When macromolecular superstructures are defined by very specific chemical interactions, their properties are likely to be very sensitive to the steric constraints of interfaces. Modular systems of molecules, constructed for the purpose of obtaining structu ...
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Journal ArticleJournal of the American Chemical Society · March 2006
The mechanochemistry of the bimolecular nucleophilic substitution of DMSO for substituted pyridines at a square-planar pincer Pd(II) center was investigated using single-molecule force spectroscopy (SMFS). The SMFS data are interpreted in terms of the Bell ...
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Journal ArticleJournal of the American Chemical Society · March 2004
Self-assembled polymers whose main chains are defined by reversible DNA base pairing form bridges between the tip of an atomic force microscope and substrate. The forces associated with the rupture of these assemblies are independent of polymer bridge leng ...
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