Scholars@Duke publication: Vibrational spectra of fluvalinate

Vibrational spectra of fluvalinate

Publication , Journal Article

Narayanan, VA; Begun, GM; Stump, NA; Stokes, DL; Vo‐Dinh, T

Published in: Journal of Raman Spectroscopy

January 1, 1993

The normal Raman spectrum (NRS), Fourier transform infrared spectrum (FTIRS) and surface‐enhanced Raman spectrum (SERS) of the important insecticide and acaricide fluvalinate (C26H22ClF3N2O3) were recorded for the first time. The spectral data are discussed in terms of characteristic chemical group frequencies and bonds. The fingerprint regions of fluvalinate vibrations that are distinct in FTIRS are identified and presented with the different fingerprint frequencies that are only characteristic to NRS. The enhancement of the benzene ring‐breathing vibration of fluvalinate in SERS is a useful mode for trace analysis for residues of this pesticide at the subnanogram level. The vibrational spectra and polarization characteristics of NRS frequencies are useful as reference spectra for this pesticide in the qualitative analysis of its residues. Copyright © 1993 John Wiley & Sons, Ltd.

Duke Scholars

Author Tuan Vo-Dinh Biomedical Engineering

Published In

Journal of Raman Spectroscopy

DOI

10.1002/jrs.1250240302

EISSN

1097-4555

ISSN

0377-0486

Publication Date

January 1, 1993

Volume

Issue

Start / End Page

123 / 128

Related Subject Headings

Chemical Physics
5104 Condensed matter physics
3406 Physical chemistry
3402 Inorganic chemistry
0913 Mechanical Engineering
0306 Physical Chemistry (incl. Structural)
0204 Condensed Matter Physics

Citation

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ICMJE

MLA

NLM

Narayanan, V. A., Begun, G. M., Stump, N. A., Stokes, D. L., & Vo‐Dinh, T. (1993). Vibrational spectra of fluvalinate. Journal of Raman Spectroscopy, 24(3), 123–128. https://doi.org/10.1002/jrs.1250240302

Narayanan, V. A., G. M. Begun, N. A. Stump, D. L. Stokes, and T. Vo‐Dinh. “Vibrational spectra of fluvalinate.” Journal of Raman Spectroscopy 24, no. 3 (January 1, 1993): 123–28. https://doi.org/10.1002/jrs.1250240302.

Narayanan VA, Begun GM, Stump NA, Stokes DL, Vo‐Dinh T. Vibrational spectra of fluvalinate. Journal of Raman Spectroscopy. 1993 Jan 1;24(3):123–8.

Narayanan, V. A., et al. “Vibrational spectra of fluvalinate.” Journal of Raman Spectroscopy, vol. 24, no. 3, Jan. 1993, pp. 123–28. Scopus, doi:10.1002/jrs.1250240302.

Narayanan VA, Begun GM, Stump NA, Stokes DL, Vo‐Dinh T. Vibrational spectra of fluvalinate. Journal of Raman Spectroscopy. 1993 Jan 1;24(3):123–128.

Published In

Journal of Raman Spectroscopy

DOI

10.1002/jrs.1250240302

EISSN

1097-4555

ISSN

0377-0486

Publication Date

January 1, 1993

Volume

Issue

Start / End Page

123 / 128

Related Subject Headings

Chemical Physics
5104 Condensed matter physics
3406 Physical chemistry
3402 Inorganic chemistry
0913 Mechanical Engineering
0306 Physical Chemistry (incl. Structural)
0204 Condensed Matter Physics