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Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule

Publication ,  Journal Article
Efstathiou, K; Joyeux, M; Sadovskií, DA
Published in: Physical Review A Atomic Molecular and Optical Physics
January 1, 2004

The vibrational potential of HCN/CNH isomerized molecule was analyzed using model system based on deformation of spherical pendulum. This model was used to reproduce large amplitude bending vibrations of flexible triatomic molecules with two stable linear equilibria. The second global bending quantum number was introduced for HCN/CNH molecule and no monodromy was observed for the system. The spherical pendulum was represented as motion of particle which was located in linear gravitational field and constrained to sphere.

Duke Scholars

Published In

Physical Review A Atomic Molecular and Optical Physics

DOI

ISSN

1050-2947

Publication Date

January 1, 2004

Volume

69

Issue

3

Start / End Page

1 / 32504

Related Subject Headings

  • General Physics
  • 03 Chemical Sciences
  • 02 Physical Sciences
  • 01 Mathematical Sciences
 

Citation

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MLA
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Efstathiou, K., Joyeux, M., & Sadovskií, D. A. (2004). Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule. Physical Review A Atomic Molecular and Optical Physics, 69(3), 1–32504. https://doi.org/10.1103/PhysRevA.69.032504
Efstathiou, K., M. Joyeux, and D. A. Sadovskií. “Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule.” Physical Review A Atomic Molecular and Optical Physics 69, no. 3 (January 1, 2004): 1–32504. https://doi.org/10.1103/PhysRevA.69.032504.
Efstathiou K, Joyeux M, Sadovskií DA. Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule. Physical Review A Atomic Molecular and Optical Physics. 2004 Jan 1;69(3):1–32504.
Efstathiou, K., et al. “Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule.” Physical Review A Atomic Molecular and Optical Physics, vol. 69, no. 3, Jan. 2004, pp. 1–32504. Scopus, doi:10.1103/PhysRevA.69.032504.
Efstathiou K, Joyeux M, Sadovskií DA. Global bending quantum number and the absence of monodromy in the HCN↔CNH molecule. Physical Review A Atomic Molecular and Optical Physics. 2004 Jan 1;69(3):1–32504.

Published In

Physical Review A Atomic Molecular and Optical Physics

DOI

ISSN

1050-2947

Publication Date

January 1, 2004

Volume

69

Issue

3

Start / End Page

1 / 32504

Related Subject Headings

  • General Physics
  • 03 Chemical Sciences
  • 02 Physical Sciences
  • 01 Mathematical Sciences