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Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture

Publication ,  Journal Article
Urso, JH; Gilbertson, LM
Published in: ACS Sustainable Chemistry and Engineering
April 2, 2018

Agriculture fertilization suffers from inefficiencies that carry significant environmental and economic consequences. These consequences include high fertilizer production energy demand, on-field greenhouse gas emissions, and eutrophication. Additionally, inefficient fertilizer use is responsible for billions of dollars in annual economic losses in the form of resource loss as well as environmental burdens. Furthermore, the unsustainability of current fertilization practices and the reliance upon finite resources calls into question the ability of agriculture to meet projected increases in global demand. Herein, critical fertilizer system inefficiencies are highlighted and quantified with a new proposed metric, atom conversion efficiency (ACE), which captures inefficiencies of primary nutrient atoms (N and P) at each stage of the fertilizer life cycle, from synthesis to farm gate, for the model crop, corn. Conversion efficiencies for the most common forms of N and P used in conventional fertilizers range from 5% (diammonium phosphate) to 10% (ammonium nitrate). These low system efficiency values motivate advancements in agriculture sustainability through (i) improvements in the conversion of the raw forms of N and P into fertilizers, (ii) enhancement of nutrient use efficiency (NUE), and (iii) nutrient form selection, signaling an opportunity for advancement through innovative technologies.

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Published In

ACS Sustainable Chemistry and Engineering

DOI

EISSN

2168-0485

Publication Date

April 2, 2018

Volume

6

Issue

4

Start / End Page

4453 / 4463

Related Subject Headings

  • 4004 Chemical engineering
  • 3401 Analytical chemistry
  • 0904 Chemical Engineering
  • 0502 Environmental Science and Management
  • 0301 Analytical Chemistry
 

Citation

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Urso, J. H., & Gilbertson, L. M. (2018). Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture. ACS Sustainable Chemistry and Engineering, 6(4), 4453–4463. https://doi.org/10.1021/acssuschemeng.7b03600
Urso, J. H., and L. M. Gilbertson. “Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture.” ACS Sustainable Chemistry and Engineering 6, no. 4 (April 2, 2018): 4453–63. https://doi.org/10.1021/acssuschemeng.7b03600.
Urso JH, Gilbertson LM. Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture. ACS Sustainable Chemistry and Engineering. 2018 Apr 2;6(4):4453–63.
Urso, J. H., and L. M. Gilbertson. “Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture.” ACS Sustainable Chemistry and Engineering, vol. 6, no. 4, Apr. 2018, pp. 4453–63. Scopus, doi:10.1021/acssuschemeng.7b03600.
Urso JH, Gilbertson LM. Atom Conversion Efficiency: A New Sustainability Metric Applied to Nitrogen and Phosphorus Use in Agriculture. ACS Sustainable Chemistry and Engineering. 2018 Apr 2;6(4):4453–4463.
Journal cover image

Published In

ACS Sustainable Chemistry and Engineering

DOI

EISSN

2168-0485

Publication Date

April 2, 2018

Volume

6

Issue

4

Start / End Page

4453 / 4463

Related Subject Headings

  • 4004 Chemical engineering
  • 3401 Analytical chemistry
  • 0904 Chemical Engineering
  • 0502 Environmental Science and Management
  • 0301 Analytical Chemistry