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Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks

Publication ,  Journal Article
Zhang, L; Yuan, S; Feng, L; Guo, B; Qin, J; Xu, B; Lollar, C; Sun, D; Zhou, H
Published in: Angewandte Chemie
April 23, 2018

Multi‐component metal–organic frameworks (MOFs) with precisely controlled pore environments are highly desired owing to their potential applications in gas adsorption, separation, cooperative catalysis, and biomimetics. A series of multi‐component MOFs, namely PCN‐900(RE), were constructed from a combination of tetratopic porphyrinic linkers, linear linkers, and rare‐earth hexanuclear clusters (RE) under the guidance of thermodynamics. These MOFs exhibit high surface areas (up to 2523 cm g) and unlimited tunability by modification of metal nodes and/or linker components. Post‐synthetic exchange of linear linkers and metalation of two organic linkers were realized, allowing the incorporation of a wide range of functional moieties. Two different metal sites were sequentially placed on the linear linker and the tetratopic porphyrinic linker, respectively, giving rise to an ideal platform for heterogeneous catalysis.

Duke Scholars

Published In

Angewandte Chemie

DOI

EISSN

1521-3757

ISSN

0044-8249

Publication Date

April 23, 2018

Volume

130

Issue

18

Start / End Page

5189 / 5193

Publisher

Wiley

Related Subject Headings

  • Organic Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

APA
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ICMJE
MLA
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Zhang, L., Yuan, S., Feng, L., Guo, B., Qin, J., Xu, B., … Zhou, H. (2018). Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Angewandte Chemie, 130(18), 5189–5193. https://doi.org/10.1002/ange.201802661
Zhang, Liangliang, Shuai Yuan, Liang Feng, Bingbing Guo, Jun‐Sheng Qin, Ben Xu, Christina Lollar, Daofeng Sun, and Hong‐Cai Zhou. “Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks.” Angewandte Chemie 130, no. 18 (April 23, 2018): 5189–93. https://doi.org/10.1002/ange.201802661.
Zhang L, Yuan S, Feng L, Guo B, Qin J, Xu B, et al. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Angewandte Chemie. 2018 Apr 23;130(18):5189–93.
Zhang, Liangliang, et al. “Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks.” Angewandte Chemie, vol. 130, no. 18, Wiley, Apr. 2018, pp. 5189–93. Crossref, doi:10.1002/ange.201802661.
Zhang L, Yuan S, Feng L, Guo B, Qin J, Xu B, Lollar C, Sun D, Zhou H. Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks. Angewandte Chemie. Wiley; 2018 Apr 23;130(18):5189–5193.
Journal cover image

Published In

Angewandte Chemie

DOI

EISSN

1521-3757

ISSN

0044-8249

Publication Date

April 23, 2018

Volume

130

Issue

18

Start / End Page

5189 / 5193

Publisher

Wiley

Related Subject Headings

  • Organic Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences