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Interactional effect of cerium and manganese on NO catalytic oxidation.

Publication ,  Journal Article
Liang, Y; Huang, Y; Zhang, H; Lan, L; Zhao, M; Gong, M; Chen, Y; Wang, J
Published in: Environ Sci Pollut Res Int
April 2017

To preferably catalyze the oxidation of NO to NO2 in diesel after-treatment system, a series of CeO2-MnO x composite oxides was supported on silica-alumina material by the co-impregnation method. The maximum conversion of NO of the catalyst with a Ce/Mn weight ratio of 5:5 was improved by around 40%, compared to the supported manganese-only or cerium-only sample. And its maximum reaction rate was 0.056 μmol g-1 s-1 at 250 °C at the gas hourly space velocity of 30,000 h-1. The experimental results suggested that Ce-Mn solid solution was formed, which could modulate the valence state of cerium and manganese and exhibit great redox properties. Moreover, the strong interaction between ceria and manganese resulted in the largest desorption amount of strong chemical oxygen and oxygen vacancies, leading to the maximum O α area ratio of 62.26% from the O 1s result. These effective oxygen species could be continually transferred to the surface, leading to the best NO catalytic activity of 5Ce5Mn/SA catalyst. Graphical abstract.

Duke Scholars

Published In

Environ Sci Pollut Res Int

DOI

EISSN

1614-7499

Publication Date

April 2017

Volume

24

Issue

10

Start / End Page

9314 / 9324

Location

Germany

Related Subject Headings

  • Oxides
  • Oxidation-Reduction
  • Manganese
  • Environmental Sciences
  • Cerium
  • Catalysis
  • 06 Biological Sciences
  • 05 Environmental Sciences
  • 03 Chemical Sciences
 

Citation

APA
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ICMJE
MLA
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Liang, Y., Huang, Y., Zhang, H., Lan, L., Zhao, M., Gong, M., … Wang, J. (2017). Interactional effect of cerium and manganese on NO catalytic oxidation. Environ Sci Pollut Res Int, 24(10), 9314–9324. https://doi.org/10.1007/s11356-017-8645-x
Liang, Yanli, Yufen Huang, Hailong Zhang, Li Lan, Ming Zhao, Maochu Gong, Yaoqiang Chen, and Jianli Wang. “Interactional effect of cerium and manganese on NO catalytic oxidation.Environ Sci Pollut Res Int 24, no. 10 (April 2017): 9314–24. https://doi.org/10.1007/s11356-017-8645-x.
Liang Y, Huang Y, Zhang H, Lan L, Zhao M, Gong M, et al. Interactional effect of cerium and manganese on NO catalytic oxidation. Environ Sci Pollut Res Int. 2017 Apr;24(10):9314–24.
Liang, Yanli, et al. “Interactional effect of cerium and manganese on NO catalytic oxidation.Environ Sci Pollut Res Int, vol. 24, no. 10, Apr. 2017, pp. 9314–24. Pubmed, doi:10.1007/s11356-017-8645-x.
Liang Y, Huang Y, Zhang H, Lan L, Zhao M, Gong M, Chen Y, Wang J. Interactional effect of cerium and manganese on NO catalytic oxidation. Environ Sci Pollut Res Int. 2017 Apr;24(10):9314–9324.
Journal cover image

Published In

Environ Sci Pollut Res Int

DOI

EISSN

1614-7499

Publication Date

April 2017

Volume

24

Issue

10

Start / End Page

9314 / 9324

Location

Germany

Related Subject Headings

  • Oxides
  • Oxidation-Reduction
  • Manganese
  • Environmental Sciences
  • Cerium
  • Catalysis
  • 06 Biological Sciences
  • 05 Environmental Sciences
  • 03 Chemical Sciences