Analysis of the ferroelectric phase transition in BaAl2O4 by group theoretical methods and first-principles calculations

Group theoretical methods are applied to a ferroelectric phase transition in barium aluminate (BaAl2O4). The atomic displacements from x-ray-diffraction data are decomposed into four modes: a primary order parameter and three secondary order parameters. The spontaneous polarization Ps is shown to arise from a secondary order parameter, resulting in a very small value of Ps, as is typical of other improper ferroelectrics. Using a first-principles computational method, we show that the primary order parameter becomes unstable, and is driven to a nonzero value at the phase transition. Through coupling, the nonzero primary order parameter then drives the secondary order parameters to nonzero values as well.

Duke Scholars

Author Michael J Mehl Thomas Lord Department of Mechanical Engineering and Materia ...