Measuring Topological Constraint Relaxation in Ring-Linear Polymer Blends.

Polymers are an effective test bed for studying topological constraints in condensed matter due to a wide array of synthetically available chain topologies. When linear and ring polymers are blended together, emergent rheological properties are observed as the blend can be more viscous than either of the individual components. This emergent behavior arises since ring-linear blends can form long-lived topological constraints as the linear polymers thread the ring polymers. Here, we demonstrate how the Gauss linking integral can be used to efficiently evaluate the relaxation of topological constraints in ring-linear polymer blends. For majority-linear blends, the relaxation rate of topological constraints depends primarily on reptation of the linear polymers, resulting in the diffusive time τ_{d,R} for rings of length N_{R} blended with linear chains of length N_{l} to scale as τ_{d,R}∼N_{R}^{2}N_{L}^{3.4}.

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Author Michael Rubinstein Thomas Lord Department of Mechanical Engineering and Materia ...