Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs.
Publication
, Journal Article
Norton, AE; Abdolmaleki, MK; Liang, J; Sharma, M; Golsby, R; Zoller, A; Krause, JA; Connick, WB; Chatterjee, S
Published in: Chem Commun (Camb)
September 1, 2020
Red crystals of [Pt(tpy)Cl]NO3·HNO3 show mechanochromic behaviour turning yellow when pressure is applied. The electronic character and spectroscopic signature of the red and yellow polymorphs change as a result of slipping of the molecular stacking planes in the solid state. The slippage alters the PtPt intermolecular distances from a linear stacked motif with <3.5 Å separations in the red polymorph to a less stacked motif of alternating short intradimer and long interdimer interactions in the yellow polymorph.
Duke Scholars
Published In
Chem Commun (Camb)
DOI
EISSN
1364-548X
Publication Date
September 1, 2020
Volume
56
Issue
70
Start / End Page
10175 / 10178
Location
England
Related Subject Headings
- Organic Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Norton, A. E., Abdolmaleki, M. K., Liang, J., Sharma, M., Golsby, R., Zoller, A., … Chatterjee, S. (2020). Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs. Chem Commun (Camb), 56(70), 10175–10178. https://doi.org/10.1039/d0cc03436c
Norton, Amie E., Mahmood Karimi Abdolmaleki, Jiamin Liang, Malvika Sharma, Robert Golsby, Ann Zoller, Jeanette A. Krause, William B. Connick, and Sayandev Chatterjee. “Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs.” Chem Commun (Camb) 56, no. 70 (September 1, 2020): 10175–78. https://doi.org/10.1039/d0cc03436c.
Norton AE, Abdolmaleki MK, Liang J, Sharma M, Golsby R, Zoller A, et al. Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs. Chem Commun (Camb). 2020 Sep 1;56(70):10175–8.
Norton, Amie E., et al. “Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs.” Chem Commun (Camb), vol. 56, no. 70, Sept. 2020, pp. 10175–78. Pubmed, doi:10.1039/d0cc03436c.
Norton AE, Abdolmaleki MK, Liang J, Sharma M, Golsby R, Zoller A, Krause JA, Connick WB, Chatterjee S. Phase transformation induced mechanochromism in a platinum salt: a tale of two polymorphs. Chem Commun (Camb). 2020 Sep 1;56(70):10175–10178.
Published In
Chem Commun (Camb)
DOI
EISSN
1364-548X
Publication Date
September 1, 2020
Volume
56
Issue
70
Start / End Page
10175 / 10178
Location
England
Related Subject Headings
- Organic Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences