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Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons

Publication ,  Journal Article
Facelli, JC; Orendt, AM; Solum, MS; Depke, G; Grant, DM; Michl, J
Published in: Journal of the American Chemical Society
January 1, 1986

The low-temperature static solid 13C NMR spectra of the methine carbons of bicyclo[1.1.1]pentane, bicyclo-[1.1.1]pentanone, norbornadiene, cubane, trimethoxymethane, and isobutane were measured. Calculations of the shielding tensors by the individual gauge localized orbitals (IGLO) method were also performed for these compounds and for tetrahedrane. Assignments of the principal values to the molecular frame were made on the basis of these calculations for cases in which they were not determined by symmetry. The analysis of the IGLO bond contributions either in the principal axis or in the local bond frames was used to obtain some insight into the origin of the chemical shielding. © 1986, American Chemical Society. All rights reserved.

Duke Scholars

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

January 1, 1986

Volume

108

Issue

15

Start / End Page

4268 / 4272

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Chicago
ICMJE
MLA
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Facelli, J. C., Orendt, A. M., Solum, M. S., Depke, G., Grant, D. M., & Michl, J. (1986). Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons. Journal of the American Chemical Society, 108(15), 4268–4272. https://doi.org/10.1021/ja00275a005
Facelli, J. C., A. M. Orendt, M. S. Solum, G. Depke, D. M. Grant, and J. Michl. “Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons.” Journal of the American Chemical Society 108, no. 15 (January 1, 1986): 4268–72. https://doi.org/10.1021/ja00275a005.
Facelli JC, Orendt AM, Solum MS, Depke G, Grant DM, Michl J. Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons. Journal of the American Chemical Society. 1986 Jan 1;108(15):4268–72.
Facelli, J. C., et al. “Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons.” Journal of the American Chemical Society, vol. 108, no. 15, Jan. 1986, pp. 4268–72. Scopus, doi:10.1021/ja00275a005.
Facelli JC, Orendt AM, Solum MS, Depke G, Grant DM, Michl J. Low-Temperature 13C Magnetic Resonance in Solids. 6. Methine Carbons. Journal of the American Chemical Society. 1986 Jan 1;108(15):4268–4272.
Journal cover image

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

January 1, 1986

Volume

108

Issue

15

Start / End Page

4268 / 4272

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences