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The use of partially restricted molecular orbitals to investigate transmission mechanisms of spin-spin coupling constants. I. The σ and π contributions within the FPT INDO method

Publication ,  Journal Article
Engelmann, AR; Contreras, RH; Facelli, JC
Published in: Theoretica Chimica Acta
January 1, 1981

Partially restricted INDO MO Calculations have been carried out to separate the π-electron contributions to spin-spin coupling constants in ethylene, butadiene, benzene and toluene. Results reproduce very well known trends such as the pathway invariance, the alternation in sign and the methyl group replacement rule. © 1981 Springer-Verlag.

Duke Scholars

Published In

Theoretica Chimica Acta

DOI

EISSN

1432-2234

ISSN

0040-5744

Publication Date

January 1, 1981

Volume

59

Issue

1

Start / End Page

17 / 24
 

Citation

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Engelmann, A. R., Contreras, R. H., & Facelli, J. C. (1981). The use of partially restricted molecular orbitals to investigate transmission mechanisms of spin-spin coupling constants. I. The σ and π contributions within the FPT INDO method. Theoretica Chimica Acta, 59(1), 17–24. https://doi.org/10.1007/BF00574433
Engelmann, A. R., R. H. Contreras, and J. C. Facelli. “The use of partially restricted molecular orbitals to investigate transmission mechanisms of spin-spin coupling constants. I. The σ and π contributions within the FPT INDO method.” Theoretica Chimica Acta 59, no. 1 (January 1, 1981): 17–24. https://doi.org/10.1007/BF00574433.
Engelmann, A. R., et al. “The use of partially restricted molecular orbitals to investigate transmission mechanisms of spin-spin coupling constants. I. The σ and π contributions within the FPT INDO method.” Theoretica Chimica Acta, vol. 59, no. 1, Jan. 1981, pp. 17–24. Scopus, doi:10.1007/BF00574433.
Journal cover image

Published In

Theoretica Chimica Acta

DOI

EISSN

1432-2234

ISSN

0040-5744

Publication Date

January 1, 1981

Volume

59

Issue

1

Start / End Page

17 / 24