Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons
Publication
, Journal Article
Solum, MS; Facelli, JC; Michl, J; Grant, DM
Published in: Journal of the American Chemical Society
January 1, 1986
The principal values of the 13C shielding tensors for a variety of methyl groups in small organic molecules are reported at 25 K. They were measured on neat samples of natural abundance materials. The assignment of the experimental principal values of the shielding tensors to the molecular frame was based on ab initio IGLO (Individual Gauge for Localized Orbitals) calculations of the shielding tensor for cases not determined by symmetry. The analysis of the IGLO bond contributions in the local bond frame was used to obtain some insight into the origin of the chemical shielding and, particularly, of the small variation of the σ
Duke Scholars
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1986
Volume
108
Issue
21
Start / End Page
6464 / 6470
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Solum, M. S., Facelli, J. C., Michl, J., & Grant, D. M. (1986). Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons. Journal of the American Chemical Society, 108(21), 6464–6470. https://doi.org/10.1021/ja00281a003
Solum, M. S., J. C. Facelli, J. Michl, and D. M. Grant. “Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons.” Journal of the American Chemical Society 108, no. 21 (January 1, 1986): 6464–70. https://doi.org/10.1021/ja00281a003.
Solum MS, Facelli JC, Michl J, Grant DM. Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons. Journal of the American Chemical Society. 1986 Jan 1;108(21):6464–70.
Solum, M. S., et al. “Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons.” Journal of the American Chemical Society, vol. 108, no. 21, Jan. 1986, pp. 6464–70. Scopus, doi:10.1021/ja00281a003.
Solum MS, Facelli JC, Michl J, Grant DM. Low-Temperature Carbon-13 Magnetic Resonance in Solids. 7. Methyl Carbons. Journal of the American Chemical Society. 1986 Jan 1;108(21):6464–6470.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1986
Volume
108
Issue
21
Start / End Page
6464 / 6470
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences