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The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra

Publication ,  Journal Article
Gan, ZH; Facelli, JC; Grant, DM
Published in: Journal of Chemical Physics
January 1, 1988
Published version (DOI)

The 13C dipolar powder spectra of 13CH331PO(OH)2 at room temperature and 13CH 319F at low temperature (T = 25 K) are reported. An intense peak is observed at the center of the Pake doublet. This phenomenon is explained by the transverse cross relaxation mechanism between the 13C and either the 31P or 19F nuclei. This theory shows the importance of the nonsecular terms in the Redfield relaxation theory. The chemical shielding tensors and dipolar coupling constants of these two molecules are obtained by fitting the experimental spectra. © 1988 American Institute of Physics.

Duke Scholars

Julio Cesar Facelli
Author Julio Cesar Facelli Biostatistics & Bioinformatics, Division of Translational Bi ...

Published In

Journal of Chemical Physics

DOI

10.1063/1.455698

ISSN

0021-9606

Publication Date

January 1, 1988

Volume

89

Issue

9

Start / End Page

5542 / 5546

Related Subject Headings

  • Chemical Physics
  • 51 Physical sciences
  • 40 Engineering
  • 34 Chemical sciences
  • 09 Engineering
  • 03 Chemical Sciences
  • 02 Physical Sciences
 

Citation

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MLA
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Gan, Z. H., Facelli, J. C., & Grant, D. M. (1988). The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra. Journal of Chemical Physics, 89(9), 5542–5546. https://doi.org/10.1063/1.455698
Gan, Z. H., J. C. Facelli, and D. M. Grant. “The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra.” Journal of Chemical Physics 89, no. 9 (January 1, 1988): 5542–46. https://doi.org/10.1063/1.455698.
Gan ZH, Facelli JC, Grant DM. The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra. Journal of Chemical Physics. 1988 Jan 1;89(9):5542–6.
Gan, Z. H., et al. “The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra.” Journal of Chemical Physics, vol. 89, no. 9, Jan. 1988, pp. 5542–46. Scopus, doi:10.1063/1.455698.
Gan ZH, Facelli JC, Grant DM. The effect of transverse cross relaxation on nuclear magnetic resonance dipolar spectra. Journal of Chemical Physics. 1988 Jan 1;89(9):5542–5546.

Published In

Journal of Chemical Physics

DOI

10.1063/1.455698

ISSN

0021-9606

Publication Date

January 1, 1988

Volume

89

Issue

9

Start / End Page

5542 / 5546

Related Subject Headings

  • Chemical Physics
  • 51 Physical sciences
  • 40 Engineering
  • 34 Chemical sciences
  • 09 Engineering
  • 03 Chemical Sciences
  • 02 Physical Sciences