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Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol.

Publication ,  Journal Article
Rauckman, EJ; Rosen, GM; Lefkowitz, RJ
Published in: J Med Chem
October 1976

Spin-labeled analogues of dichloroisoproterenol and propranolol were synthesized. It was found that the KD's of both probes for the beta-adrenergic receptors of frog erythrocytes were about 30-fold higher than the KD's previously reported for the parent antagonists. Thus the introduction of a bulky nitroxide moiety in place of the isopropyl group on the amino nitrogen is associated with a decrease in affinity for the beta-adrenergic receptors. Nonetheless, the affinity of the spin-labeled propranolol would appear to be within a range compatible with EPR measurements.

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Published In

J Med Chem

DOI

ISSN

0022-2623

Publication Date

October 1976

Volume

19

Issue

10

Start / End Page

1254 / 1256

Location

United States

Related Subject Headings

  • Structure-Activity Relationship
  • Spin Labels
  • Receptors, Adrenergic, beta
  • Rana pipiens
  • Propranolol
  • Medicinal & Biomolecular Chemistry
  • Isoproterenol
  • In Vitro Techniques
  • Erythrocytes
  • Binding, Competitive
 

Citation

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Rauckman, E. J., Rosen, G. M., & Lefkowitz, R. J. (1976). Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol. J Med Chem, 19(10), 1254–1256. https://doi.org/10.1021/jm00232a018
Rauckman, E. J., G. M. Rosen, and R. J. Lefkowitz. “Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol.J Med Chem 19, no. 10 (October 1976): 1254–56. https://doi.org/10.1021/jm00232a018.
Rauckman EJ, Rosen GM, Lefkowitz RJ. Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol. J Med Chem. 1976 Oct;19(10):1254–6.
Rauckman, E. J., et al. “Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol.J Med Chem, vol. 19, no. 10, Oct. 1976, pp. 1254–56. Pubmed, doi:10.1021/jm00232a018.
Rauckman EJ, Rosen GM, Lefkowitz RJ. Pharmacological activity of nitroxide analogues of dichloroisoproterenol and propranolol. J Med Chem. 1976 Oct;19(10):1254–1256.
Journal cover image

Published In

J Med Chem

DOI

ISSN

0022-2623

Publication Date

October 1976

Volume

19

Issue

10

Start / End Page

1254 / 1256

Location

United States

Related Subject Headings

  • Structure-Activity Relationship
  • Spin Labels
  • Receptors, Adrenergic, beta
  • Rana pipiens
  • Propranolol
  • Medicinal & Biomolecular Chemistry
  • Isoproterenol
  • In Vitro Techniques
  • Erythrocytes
  • Binding, Competitive