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Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface.

Publication ,  Journal Article
Barenberg, SA; Reichert, WM; Mauritz, KA
Published in: Annals of the New York Academy of Sciences
January 1983

The effect and interrelationship between primary and secondary molecular motions, morphological order/disorder, and associated water on thrombogenesis are elucidated using an amorphous hydrophobic polymer of poly[trifluoroethoxy) ( fluoroalkoxy ) phosphazene ], a semicrystalline triblock copolymer of poly[(gamma-benzyl-L-glutamate) (acrylonitrile/butadiene) (gamma-benzyl-L-glutamate)] and a surface cross-linked hydrophilic/hydrophobic(core)/hydrophilic triblock copolymer of poly[(hydroxy propyl glutamine) (gamma-benzyl-L-glutamate) (hydroxy propyl glutamine)]. The thrombogenic response of the polymers indicated that for a semicrystalline polymer an epitaxial model can be employed to correlate and interrelate the ultrastructure morphology, surface chemistry, surface molecular motions, degrees and types of associated bound water and surface/subsurface ion binding to thrombogenesis. Further for an amorphous polymer, of given side chain length and chemistry, the results indicate that there is an initial effect of molecular motions on thrombogenesis, independent of morphological order/disorder and/or associated water.

Duke Scholars

Published In

Annals of the New York Academy of Sciences

DOI

EISSN

1749-6632

ISSN

0077-8923

Publication Date

January 1983

Volume

416

Start / End Page

538 / 560

Related Subject Headings

  • X-Ray Diffraction
  • Time Factors
  • Thrombosis
  • Surface Properties
  • Spectrophotometry
  • Polymers
  • Models, Molecular
  • Microscopy, Electron, Scanning
  • General Science & Technology
  • Dogs
 

Citation

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ICMJE
MLA
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Barenberg, S. A., Reichert, W. M., & Mauritz, K. A. (1983). Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface. Annals of the New York Academy of Sciences, 416, 538–560. https://doi.org/10.1111/j.1749-6632.1983.tb35211.x
Barenberg, S. A., W. M. Reichert, and K. A. Mauritz. “Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface.Annals of the New York Academy of Sciences 416 (January 1983): 538–60. https://doi.org/10.1111/j.1749-6632.1983.tb35211.x.
Barenberg SA, Reichert WM, Mauritz KA. Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface. Annals of the New York Academy of Sciences. 1983 Jan;416:538–60.
Barenberg, S. A., et al. “Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface.Annals of the New York Academy of Sciences, vol. 416, Jan. 1983, pp. 538–60. Epmc, doi:10.1111/j.1749-6632.1983.tb35211.x.
Barenberg SA, Reichert WM, Mauritz KA. Thrombogenesis: effect of molecular motions, surface order, and hydrophobicity of the polymer interface. Annals of the New York Academy of Sciences. 1983 Jan;416:538–560.
Journal cover image

Published In

Annals of the New York Academy of Sciences

DOI

EISSN

1749-6632

ISSN

0077-8923

Publication Date

January 1983

Volume

416

Start / End Page

538 / 560

Related Subject Headings

  • X-Ray Diffraction
  • Time Factors
  • Thrombosis
  • Surface Properties
  • Spectrophotometry
  • Polymers
  • Models, Molecular
  • Microscopy, Electron, Scanning
  • General Science & Technology
  • Dogs