Stereochemically active lead chloride enantiomers mediated by homochiral organic cation
Publication
, Journal Article
Zhu, LL; Huang, YE; Lin, YP; Huang, XY; Liu, HQ; Mitzi, DB; Du, KZ
Published in: Polyhedron
January 15, 2019
Two-dimensional ((S)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (1) and ((R)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (2) have been synthesized using the corresponding homochiral organic cations. The lead atoms within the structure adopt a variety of coordination geometries, with Pb(II)Cl6 adopting a distorted pentagonal pyramid geometry and exhibiting stereochemically active lone-pair electrons, instead of a more typical octahedral geometry with less stereochemical activity.
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Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
January 15, 2019
Volume
158
Start / End Page
445 / 448
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
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Zhu, L. L., Huang, Y. E., Lin, Y. P., Huang, X. Y., Liu, H. Q., Mitzi, D. B., & Du, K. Z. (2019). Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron, 158, 445–448. https://doi.org/10.1016/j.poly.2018.11.026
Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
January 15, 2019
Volume
158
Start / End Page
445 / 448
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry