Scholars@Duke
Journal cover image

Stereochemically active lead chloride enantiomers mediated by homochiral organic cation

Publication ,  Journal Article
Zhu, LL; Huang, YE; Lin, YP; Huang, XY; Liu, HQ; Mitzi, DB; Du, KZ
Published in: Polyhedron
January 15, 2019
Published version (DOI)

Two-dimensional ((S)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (1) and ((R)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (2) have been synthesized using the corresponding homochiral organic cations. The lead atoms within the structure adopt a variety of coordination geometries, with Pb(II)Cl6 adopting a distorted pentagonal pyramid geometry and exhibiting stereochemically active lone-pair electrons, instead of a more typical octahedral geometry with less stereochemical activity.

Duke Scholars

David Mitzi
Author David Mitzi Thomas Lord Department of Mechanical Engineering and Materia ...

Published In

Polyhedron

DOI

10.1016/j.poly.2018.11.026

ISSN

0277-5387

Publication Date

January 15, 2019

Volume

158

Start / End Page

445 / 448

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Zhu, L. L., Huang, Y. E., Lin, Y. P., Huang, X. Y., Liu, H. Q., Mitzi, D. B., & Du, K. Z. (2019). Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron, 158, 445–448. https://doi.org/10.1016/j.poly.2018.11.026
Zhu, L. L., Y. E. Huang, Y. P. Lin, X. Y. Huang, H. Q. Liu, D. B. Mitzi, and K. Z. Du. “Stereochemically active lead chloride enantiomers mediated by homochiral organic cation.” Polyhedron 158 (January 15, 2019): 445–48. https://doi.org/10.1016/j.poly.2018.11.026.
Zhu LL, Huang YE, Lin YP, Huang XY, Liu HQ, Mitzi DB, et al. Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron. 2019 Jan 15;158:445–8.
Zhu, L. L., et al. “Stereochemically active lead chloride enantiomers mediated by homochiral organic cation.” Polyhedron, vol. 158, Jan. 2019, pp. 445–48. Scopus, doi:10.1016/j.poly.2018.11.026.
Zhu LL, Huang YE, Lin YP, Huang XY, Liu HQ, Mitzi DB, Du KZ. Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron. 2019 Jan 15;158:445–448.
Journal cover image

Published In

Polyhedron

DOI

10.1016/j.poly.2018.11.026

ISSN

0277-5387

Publication Date

January 15, 2019

Volume

158

Start / End Page

445 / 448

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry