Stereochemically active lead chloride enantiomers mediated by homochiral organic cation
Publication
, Journal Article
Zhu, LL; Huang, YE; Lin, YP; Huang, XY; Liu, HQ; Mitzi, DB; Du, KZ
Published in: Polyhedron
January 15, 2019
Two-dimensional ((S)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (1) and ((R)-1-(1-naphthyl)ethylamineH)2Pb4Cl10·2DMF (2) have been synthesized using the corresponding homochiral organic cations. The lead atoms within the structure adopt a variety of coordination geometries, with Pb(II)Cl6 adopting a distorted pentagonal pyramid geometry and exhibiting stereochemically active lone-pair electrons, instead of a more typical octahedral geometry with less stereochemical activity.
Duke Scholars
Altmetric Attention Stats
Dimensions Citation Stats
Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
January 15, 2019
Volume
158
Start / End Page
445 / 448
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Zhu, L. L., Huang, Y. E., Lin, Y. P., Huang, X. Y., Liu, H. Q., Mitzi, D. B., & Du, K. Z. (2019). Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron, 158, 445–448. https://doi.org/10.1016/j.poly.2018.11.026
Zhu, L. L., Y. E. Huang, Y. P. Lin, X. Y. Huang, H. Q. Liu, D. B. Mitzi, and K. Z. Du. “Stereochemically active lead chloride enantiomers mediated by homochiral organic cation.” Polyhedron 158 (January 15, 2019): 445–48. https://doi.org/10.1016/j.poly.2018.11.026.
Zhu LL, Huang YE, Lin YP, Huang XY, Liu HQ, Mitzi DB, et al. Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron. 2019 Jan 15;158:445–8.
Zhu, L. L., et al. “Stereochemically active lead chloride enantiomers mediated by homochiral organic cation.” Polyhedron, vol. 158, Jan. 2019, pp. 445–48. Scopus, doi:10.1016/j.poly.2018.11.026.
Zhu LL, Huang YE, Lin YP, Huang XY, Liu HQ, Mitzi DB, Du KZ. Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron. 2019 Jan 15;158:445–448.
Published In
Polyhedron
DOI
ISSN
0277-5387
Publication Date
January 15, 2019
Volume
158
Start / End Page
445 / 448
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry