Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex
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, Journal Article
Brown, TJ; Robertson, BD; Widenhoefer, RA
Published in: Journal of Organometallic Chemistry
May 15, 2014
The cationic gold tetramethylallene complex {[P(t-Bu)2o- biphenyl]Au(η2-Me2CCCMe2)}+ SbF6- (1) underwent formal 1,3-hydrogen migration in CD2Cl2 solution at or below room temperature in the absence of base to form the 1,3-diene complex {[P(t-Bu)2o-biphenyl] Au[η2-H2C(Me) = C(H)-C(H)CMe2]}+ SbF6- (2), which was isolated in 92% yield and analyzed by X-ray crystallography. © 2014 Elsevier B.V. All rights reserved.
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Published In
Journal of Organometallic Chemistry
DOI
ISSN
0022-328X
Publication Date
May 15, 2014
Volume
758
Start / End Page
25 / 28
Related Subject Headings
- Organic Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry
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Brown, T. J., Robertson, B. D., & Widenhoefer, R. A. (2014). Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex. Journal of Organometallic Chemistry, 758, 25–28. https://doi.org/10.1016/j.jorganchem.2014.01.030
Brown, T. J., B. D. Robertson, and R. A. Widenhoefer. “Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex.” Journal of Organometallic Chemistry 758 (May 15, 2014): 25–28. https://doi.org/10.1016/j.jorganchem.2014.01.030.
Brown TJ, Robertson BD, Widenhoefer RA. Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex. Journal of Organometallic Chemistry. 2014 May 15;758:25–8.
Brown, T. J., et al. “Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex.” Journal of Organometallic Chemistry, vol. 758, May 2014, pp. 25–28. Scopus, doi:10.1016/j.jorganchem.2014.01.030.
Brown TJ, Robertson BD, Widenhoefer RA. Synthesis and X-ray crystal structure of a cationic gold (I) π-(1,3-diene) complex generated via isomerization of a gold π-allene complex. Journal of Organometallic Chemistry. 2014 May 15;758:25–28.
Published In
Journal of Organometallic Chemistry
DOI
ISSN
0022-328X
Publication Date
May 15, 2014
Volume
758
Start / End Page
25 / 28
Related Subject Headings
- Organic Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry