Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes
Publication
, Journal Article
Lee, SD; Timmerman, JC; Widenhoefer, RA
Published in: Advanced Synthesis and Catalysis
October 1, 2014
A 1:2 mixture of (P1)(AuCl)2[P1=(S)-DTBM-MeO-BIPHEP] and silver tetrafluoroborate (AgBF4) in methanol catalyzes the intramolecular hydroamination of unactivated alkenes with carbamates and ureas to form pyrrolidine derivatives with up to 85% ee.
Duke Scholars
Published In
Advanced Synthesis and Catalysis
DOI
EISSN
1615-4169
ISSN
1615-4150
Publication Date
October 1, 2014
Volume
356
Issue
14-15
Start / End Page
3187 / 3192
Publisher
Wiley-VCH Verlag
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 0904 Chemical Engineering
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Lee, S. D., Timmerman, J. C., & Widenhoefer, R. A. (2014). Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes. Advanced Synthesis and Catalysis, 356(14–15), 3187–3192. https://doi.org/10.1002/adsc.201400268
Lee, S. D., J. C. Timmerman, and R. A. Widenhoefer. “Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes.” Advanced Synthesis and Catalysis 356, no. 14–15 (October 1, 2014): 3187–92. https://doi.org/10.1002/adsc.201400268.
Lee SD, Timmerman JC, Widenhoefer RA. Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes. Advanced Synthesis and Catalysis. 2014 Oct 1;356(14–15):3187–92.
Lee, S. D., et al. “Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes.” Advanced Synthesis and Catalysis, vol. 356, no. 14–15, Wiley-VCH Verlag, Oct. 2014, pp. 3187–92. Scopus, doi:10.1002/adsc.201400268.
Lee SD, Timmerman JC, Widenhoefer RA. Enantioselective intramolecular hydroamination of unactivated alkenes catalyzed by mono- and bis(gold) phosphine complexes. Advanced Synthesis and Catalysis. Wiley-VCH Verlag; 2014 Oct 1;356(14–15):3187–3192.
Published In
Advanced Synthesis and Catalysis
DOI
EISSN
1615-4169
ISSN
1615-4150
Publication Date
October 1, 2014
Volume
356
Issue
14-15
Start / End Page
3187 / 3192
Publisher
Wiley-VCH Verlag
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 0904 Chemical Engineering
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry