Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes.
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, Journal Article
Robertson, BD; Brooner, REM; Widenhoefer, RA
Published in: Chemistry (Weinheim an der Bergstrasse, Germany)
April 2015
Mixtures of [{PCy2(o-biphenyl)}AuCl] and AgSbF6 catalyze the tandem cycloaddition/hydroarylation of 7-aryl-1,6-enynes with electron-rich arenes to form 6,6-diarylbicyclo[3.2.0]heptanes in good yield under mild conditions. Experimental observations point to a mechanism involving gold-catalyzed cycloaddition followed by silver-catalyzed hydroarylation of a bicyclo[3.2.0]hept-1(7)-ene intermediate.
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Published In
Chemistry (Weinheim an der Bergstrasse, Germany)
DOI
EISSN
1521-3765
ISSN
0947-6539
Publication Date
April 2015
Volume
21
Issue
15
Start / End Page
5714 / 5717
Related Subject Headings
- General Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences
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Robertson, B. D., Brooner, R. E. M., & Widenhoefer, R. A. (2015). Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes. Chemistry (Weinheim an Der Bergstrasse, Germany), 21(15), 5714–5717. https://doi.org/10.1002/chem.201500371
Robertson, Bradley D., Rachel E. M. Brooner, and Ross A. Widenhoefer. “Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes.” Chemistry (Weinheim an Der Bergstrasse, Germany) 21, no. 15 (April 2015): 5714–17. https://doi.org/10.1002/chem.201500371.
Robertson BD, Brooner REM, Widenhoefer RA. Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes. Chemistry (Weinheim an der Bergstrasse, Germany). 2015 Apr;21(15):5714–7.
Robertson, Bradley D., et al. “Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes.” Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 21, no. 15, Apr. 2015, pp. 5714–17. Epmc, doi:10.1002/chem.201500371.
Robertson BD, Brooner REM, Widenhoefer RA. Tandem gold/silver-catalyzed cycloaddition/hydroarylation of 7-aryl-1,6-enynes to form 6,6-diarylbicyclo[3.2.0]heptanes. Chemistry (Weinheim an der Bergstrasse, Germany). 2015 Apr;21(15):5714–5717.
Published In
Chemistry (Weinheim an der Bergstrasse, Germany)
DOI
EISSN
1521-3765
ISSN
0947-6539
Publication Date
April 2015
Volume
21
Issue
15
Start / End Page
5714 / 5717
Related Subject Headings
- General Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences