Scholars@Duke

Irradiation of benzene with 14CH+ and 14CH3+ ions

Publication ,  Journal Article
Erwin, WR; Gordon, BE; Spicer, LD; Lemmon, RM
Published in: Journal of Physical Chemistry
January 1, 1978
Published version (DOI)

Solid benzene at -196 °C was irradiated with 14CH+ and 14CH3+ ions at 10-eV kinetic energy. Yields were determined for the labeled hydrocarbon products: benzene, toluene, cycloheptatriene, diphenylmethane, biphenyl, and phenylcycloheptatriene. The radioactivity distributions between the ring and the methyl group of the toluene product were also determined. These results have been compared to those previously obtained with 14C+ and 14CH2+ ions. The comparisons have provided both insight into the reaction mechanisms and a tentative estimate of the distribution of the species (14CHx) that react with the benzene. © 1978 American Chemical Society.

Duke Scholars

Leonard D. Spicer
Author Leonard D. Spicer Radiology

Published In

Journal of Physical Chemistry

DOI

10.1021/j100495a007

ISSN

0022-3654

Publication Date

January 1, 1978

Volume

82

Issue

6

Start / End Page

654 / 656
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Erwin, W. R., Gordon, B. E., Spicer, L. D., & Lemmon, R. M. (1978). Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry, 82(6), 654–656. https://doi.org/10.1021/j100495a007
Erwin, W. R., B. E. Gordon, L. D. Spicer, and R. M. Lemmon. “Irradiation of benzene with 14CH+ and 14CH3+ ions.” Journal of Physical Chemistry 82, no. 6 (January 1, 1978): 654–56. https://doi.org/10.1021/j100495a007.
Erwin WR, Gordon BE, Spicer LD, Lemmon RM. Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry. 1978 Jan 1;82(6):654–6.
Erwin, W. R., et al. “Irradiation of benzene with 14CH+ and 14CH3+ ions.” Journal of Physical Chemistry, vol. 82, no. 6, Jan. 1978, pp. 654–56. Scopus, doi:10.1021/j100495a007.
Erwin WR, Gordon BE, Spicer LD, Lemmon RM. Irradiation of benzene with 14CH+ and 14CH3+ ions. Journal of Physical Chemistry. 1978 Jan 1;82(6):654–656.

Published In

Journal of Physical Chemistry

DOI

10.1021/j100495a007

ISSN

0022-3654

Publication Date

January 1, 1978

Volume

82

Issue

6

Start / End Page

654 / 656