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Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide

Publication ,  Journal Article
Yang, H; Zhang, T; Tian, H; Tang, J; Xu, D; Yang, W; Lin, L
Published in: Reaction Kinetics and Catalysis Letters
December 1, 2001
Published version (DOI)

La1-XSrXMnO3 (0≤x<0.8) perovskite-type oxides were synthesized by the combined EDTA-citrate complexing method and their catalytic activity for the decomposition of hydrogen peroxide was investigated. Hydrogen peroxide decomposition was observed as a first-order reaction on these catalysts. With the increase of Sr substitution, the catalytic activity increased accordingly. Through analysis of the kinetic results, the compensation effect was found for these perovskites and Mn4+ ions were ascribed as the active sites of hydrogen peroxide decomposition.

Duke Scholars

Huanghe Yang
Author Huanghe Yang Biochemistry

Published In

Reaction Kinetics and Catalysis Letters

DOI

10.1023/A:1014115508872

ISSN

0133-1736

Publication Date

December 1, 2001

Volume

73

Issue

2

Start / End Page

311 / 316

Related Subject Headings

  • Physical Chemistry
  • 0307 Theoretical and Computational Chemistry
  • 0306 Physical Chemistry (incl. Structural)
 

Citation

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ICMJE
MLA
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Yang, H., Zhang, T., Tian, H., Tang, J., Xu, D., Yang, W., & Lin, L. (2001). Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide. Reaction Kinetics and Catalysis Letters, 73(2), 311–316. https://doi.org/10.1023/A:1014115508872
Yang, H., T. Zhang, H. Tian, J. Tang, D. Xu, W. Yang, and L. Lin. “Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide.” Reaction Kinetics and Catalysis Letters 73, no. 2 (December 1, 2001): 311–16. https://doi.org/10.1023/A:1014115508872.
Yang H, Zhang T, Tian H, Tang J, Xu D, Yang W, et al. Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide. Reaction Kinetics and Catalysis Letters. 2001 Dec 1;73(2):311–6.
Yang, H., et al. “Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide.” Reaction Kinetics and Catalysis Letters, vol. 73, no. 2, Dec. 2001, pp. 311–16. Scopus, doi:10.1023/A:1014115508872.
Yang H, Zhang T, Tian H, Tang J, Xu D, Yang W, Lin L. Effect of Sr substitution on catalytic activity of La1-xSrxMnO3 (0≤x≤0.8) perovskite-type oxides for catalytic decomposition of hydrogen peroxide. Reaction Kinetics and Catalysis Letters. 2001 Dec 1;73(2):311–316.

Published In

Reaction Kinetics and Catalysis Letters

DOI

10.1023/A:1014115508872

ISSN

0133-1736

Publication Date

December 1, 2001

Volume

73

Issue

2

Start / End Page

311 / 316

Related Subject Headings

  • Physical Chemistry
  • 0307 Theoretical and Computational Chemistry
  • 0306 Physical Chemistry (incl. Structural)