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Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors

Publication ,  Journal Article
Puzyrev, YS; Roy, T; Beck, M; Tuttle, BR; Schrimpf, RD; Fleetwood, DM; Pantelides, ST
Published in: Journal of Applied Physics
February 1, 2011

Degradation mechanisms limiting the electrical reliability of GaN high-electron-mobility transistors (HEMTs) are generally attributed to defect generation by hot-electrons but specific mechanisms for such processes have not been identified. Here we give a model for the generation of active defects by the release of hydrogen atoms that passivate pre-exisiting defects. We report first-principles density-functional calculations of several candidate point defects and their interaction with hydrogen in GaN, under different growth conditions. Candidate precursor point defects in device quality GaN are identified by correlating previously observed trap levels with calculated optical levels. We propose dehydrogenation of point defects as a generic physical mechanism for defect generation in HEMTs under hot-electron stress when the degradation is not spontaneously reversible. Dehydrogenation of point defects explains (1) observed hot electron stress transconductance degradation, (2) increase in yellow luminescence, and opposite threshold voltage shifts in devices where the material was grown under nitrogen- and ammonia-rich conditions. © 2011 American Institute of Physics.

Duke Scholars

Published In

Journal of Applied Physics

DOI

ISSN

0021-8979

Publication Date

February 1, 2011

Volume

109

Issue

3

Related Subject Headings

  • Applied Physics
  • 51 Physical sciences
  • 49 Mathematical sciences
  • 40 Engineering
  • 09 Engineering
  • 02 Physical Sciences
  • 01 Mathematical Sciences
 

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Puzyrev, Y. S., Roy, T., Beck, M., Tuttle, B. R., Schrimpf, R. D., Fleetwood, D. M., & Pantelides, S. T. (2011). Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors. Journal of Applied Physics, 109(3). https://doi.org/10.1063/1.3524185
Puzyrev, Y. S., T. Roy, M. Beck, B. R. Tuttle, R. D. Schrimpf, D. M. Fleetwood, and S. T. Pantelides. “Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors.” Journal of Applied Physics 109, no. 3 (February 1, 2011). https://doi.org/10.1063/1.3524185.
Puzyrev YS, Roy T, Beck M, Tuttle BR, Schrimpf RD, Fleetwood DM, et al. Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors. Journal of Applied Physics. 2011 Feb 1;109(3).
Puzyrev, Y. S., et al. “Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors.” Journal of Applied Physics, vol. 109, no. 3, Feb. 2011. Scopus, doi:10.1063/1.3524185.
Puzyrev YS, Roy T, Beck M, Tuttle BR, Schrimpf RD, Fleetwood DM, Pantelides ST. Dehydrogenation of defects and hot-electron degradation in GaN high-electron-mobility transistors. Journal of Applied Physics. 2011 Feb 1;109(3).
Journal cover image

Published In

Journal of Applied Physics

DOI

ISSN

0021-8979

Publication Date

February 1, 2011

Volume

109

Issue

3

Related Subject Headings

  • Applied Physics
  • 51 Physical sciences
  • 49 Mathematical sciences
  • 40 Engineering
  • 09 Engineering
  • 02 Physical Sciences
  • 01 Mathematical Sciences