Angle-strained sila-cycloalkynes.
Publication
, Journal Article
Wakefield, H; Melvin, SJ; Jiang, J; Kevlishvili, I; Siegler, MA; Craig, SL; Kulik, HJ; Klausen, RS
Published in: Chemical communications (Cambridge, England)
April 2024
Second row elements in small- and medium-rings modulate strain. Herein we report the synthesis of two novel oligosilyl-containing cycloalkynes that exhibit angle-strain, as observed by X-ray crystallography. However, the angle-strained sila-cyclooctynes are sluggish participants in cycloadditions with benzyl azide. A distortion-interaction model analysis based on density functional theory calculations was performed.
Duke Scholars
Published In
Chemical communications (Cambridge, England)
DOI
EISSN
1364-548X
ISSN
1359-7345
Publication Date
April 2024
Volume
60
Issue
36
Start / End Page
4842 / 4845
Related Subject Headings
- Organic Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Wakefield, H., Melvin, S. J., Jiang, J., Kevlishvili, I., Siegler, M. A., Craig, S. L., … Klausen, R. S. (2024). Angle-strained sila-cycloalkynes. Chemical Communications (Cambridge, England), 60(36), 4842–4845. https://doi.org/10.1039/d4cc00439f
Wakefield, Herbert, Sophia J. Melvin, Jennifer Jiang, Ilia Kevlishvili, Maxime A. Siegler, Stephen L. Craig, Heather J. Kulik, and Rebekka S. Klausen. “Angle-strained sila-cycloalkynes.” Chemical Communications (Cambridge, England) 60, no. 36 (April 2024): 4842–45. https://doi.org/10.1039/d4cc00439f.
Wakefield H, Melvin SJ, Jiang J, Kevlishvili I, Siegler MA, Craig SL, et al. Angle-strained sila-cycloalkynes. Chemical communications (Cambridge, England). 2024 Apr;60(36):4842–5.
Wakefield, Herbert, et al. “Angle-strained sila-cycloalkynes.” Chemical Communications (Cambridge, England), vol. 60, no. 36, Apr. 2024, pp. 4842–45. Epmc, doi:10.1039/d4cc00439f.
Wakefield H, Melvin SJ, Jiang J, Kevlishvili I, Siegler MA, Craig SL, Kulik HJ, Klausen RS. Angle-strained sila-cycloalkynes. Chemical communications (Cambridge, England). 2024 Apr;60(36):4842–4845.
Published In
Chemical communications (Cambridge, England)
DOI
EISSN
1364-548X
ISSN
1359-7345
Publication Date
April 2024
Volume
60
Issue
36
Start / End Page
4842 / 4845
Related Subject Headings
- Organic Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences