Photolysis of some ortho-methylated monochlorobiphenyls
Publication
, Journal Article
Bunce, NJ; Deschutter, CT; Toone, EJ
Published in: Journal of the Chemical Society, Perkin Transactions 2
January 1, 1983
A series of monochloro-o-methylated biphenyls was photolysed. Quantum yields of dechlorination lie in between the low values observed for 3- and 4-chlorobiphenyl and the high values obtained for 2-chlorobiphenyl. The results are interpreted in terms of raising the energy of the excited state due to steric crowding of the ortho-substituent and relief of strain upon the departure of an ortho-chlorine.
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Published In
Journal of the Chemical Society, Perkin Transactions 2
DOI
ISSN
1472-779X
Publication Date
January 1, 1983
Issue
6
Start / End Page
859 / 861
Related Subject Headings
- Organic Chemistry
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Bunce, N. J., Deschutter, C. T., & Toone, E. J. (1983). Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2, (6), 859–861. https://doi.org/10.1039/P29830000859
Bunce, N. J., C. T. Deschutter, and E. J. Toone. “Photolysis of some ortho-methylated monochlorobiphenyls.” Journal of the Chemical Society, Perkin Transactions 2, no. 6 (January 1, 1983): 859–61. https://doi.org/10.1039/P29830000859.
Bunce NJ, Deschutter CT, Toone EJ. Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2. 1983 Jan 1;(6):859–61.
Bunce, N. J., et al. “Photolysis of some ortho-methylated monochlorobiphenyls.” Journal of the Chemical Society, Perkin Transactions 2, no. 6, Jan. 1983, pp. 859–61. Scopus, doi:10.1039/P29830000859.
Bunce NJ, Deschutter CT, Toone EJ. Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2. 1983 Jan 1;(6):859–861.
Published In
Journal of the Chemical Society, Perkin Transactions 2
DOI
ISSN
1472-779X
Publication Date
January 1, 1983
Issue
6
Start / End Page
859 / 861
Related Subject Headings
- Organic Chemistry