Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes.
Publication
, Journal Article
Widenhoefer, RA
Published in: Accounts of chemical research
October 2002
This Account describes the development and mechanistic study of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes. These transformations are characterized by good functional group compatibility, high regio- and stereoselectivity, and low air- and moisture-sensitivity. Mechanistic studies of palladium phenanthroline-catalyzed diene cycloisomerization and cyclization/hydrosilylation established mechanisms involving C-C bond formation via intramolecular carbometalation of an alkyl olefin chelate complex, which was directly observed in the context of cyclization/hydrosilylation.
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Published In
Accounts of chemical research
DOI
EISSN
1520-4898
ISSN
0001-4842
Publication Date
October 2002
Volume
35
Issue
10
Start / End Page
905 / 913
Related Subject Headings
- Phenanthrolines
- Palladium
- Organosilicon Compounds
- Molecular Structure
- Isomerism
- Hydrocarbons, Cyclic
- General Chemistry
- Cyclization
- Catalysis
- 34 Chemical sciences
Citation
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ICMJE
MLA
NLM
Widenhoefer, R. A. (2002). Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes. Accounts of Chemical Research, 35(10), 905–913. https://doi.org/10.1021/ar010040n
Widenhoefer, Ross A. “Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes.” Accounts of Chemical Research 35, no. 10 (October 2002): 905–13. https://doi.org/10.1021/ar010040n.
Widenhoefer RA. Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes. Accounts of chemical research. 2002 Oct;35(10):905–13.
Widenhoefer, Ross A. “Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes.” Accounts of Chemical Research, vol. 35, no. 10, Oct. 2002, pp. 905–13. Epmc, doi:10.1021/ar010040n.
Widenhoefer RA. Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes. Accounts of chemical research. 2002 Oct;35(10):905–913.
Published In
Accounts of chemical research
DOI
EISSN
1520-4898
ISSN
0001-4842
Publication Date
October 2002
Volume
35
Issue
10
Start / End Page
905 / 913
Related Subject Headings
- Phenanthrolines
- Palladium
- Organosilicon Compounds
- Molecular Structure
- Isomerism
- Hydrocarbons, Cyclic
- General Chemistry
- Cyclization
- Catalysis
- 34 Chemical sciences