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Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex.

Publication ,  Journal Article
Madine, JW; Wang, X; Widenhoefer, RA
Published in: Organic letters
February 2001

[figure: see text] A 1:1 mixture of the platinum phenanthroline complex (phen)PtMe2 and B(C6F5)3 catalyzed the cyclization/hydrosilylation of functionalized 1,6- and 1,7-diynes to form silylated 1,2-dialkylidenecycloalkanes in good yield and with high Z-selectivity.

Duke Scholars

Published In

Organic letters

DOI

EISSN

1523-7052

ISSN

1523-7060

Publication Date

February 2001

Volume

3

Issue

3

Start / End Page

385 / 388

Related Subject Headings

  • Silicon
  • Phenanthrolines
  • Organoplatinum Compounds
  • Organic Chemistry
  • Hydrocarbons, Cyclic
  • Alkynes
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Madine, J. W., Wang, X., & Widenhoefer, R. A. (2001). Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex. Organic Letters, 3(3), 385–388. https://doi.org/10.1021/ol006901u
Madine, J. W., X. Wang, and R. A. Widenhoefer. “Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex.Organic Letters 3, no. 3 (February 2001): 385–88. https://doi.org/10.1021/ol006901u.
Madine JW, Wang X, Widenhoefer RA. Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex. Organic letters. 2001 Feb;3(3):385–8.
Madine, J. W., et al. “Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex.Organic Letters, vol. 3, no. 3, Feb. 2001, pp. 385–88. Epmc, doi:10.1021/ol006901u.
Madine JW, Wang X, Widenhoefer RA. Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex. Organic letters. 2001 Feb;3(3):385–388.
Journal cover image

Published In

Organic letters

DOI

EISSN

1523-7052

ISSN

1523-7060

Publication Date

February 2001

Volume

3

Issue

3

Start / End Page

385 / 388

Related Subject Headings

  • Silicon
  • Phenanthrolines
  • Organoplatinum Compounds
  • Organic Chemistry
  • Hydrocarbons, Cyclic
  • Alkynes
  • 34 Chemical sciences
  • 03 Chemical Sciences