Scholars@Duke publication: Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Journal cover image

Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Publication , Journal Article

Perch, NS; Widenhoefer, RA

Published in: Organometallics

December 10, 2001

Published version (DOI)

Warming a solution of {(phen)Pd[η¹:η²-CH(CH2SiEt3) CH2C(CO2Me)2CH2CH= CH2]}⁺[BAr4]^- (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10^-4 M s^-1, ΔG‡ = 17.1 ± 0.1 kcal mol^-1) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH2 CHCH2CC(CO2Me)2CH2CHCH2 SiEt3](NC Ar)}⁺-[BAr4]^- (5) in 96 ± 10% yield (¹H NMR).

Duke Scholars

Author Ross A. Widenhoefer Chemistry

Published In

Organometallics

DOI

10.1021/om010876u

ISSN

0276-7333

Publication Date

December 10, 2001

Volume

20

Issue

25

Start / End Page

5251 / 5253

Related Subject Headings

Organic Chemistry
3406 Physical chemistry
3402 Inorganic chemistry
0399 Other Chemical Sciences
0305 Organic Chemistry
0302 Inorganic Chemistry

Citation

APA

Chicago

ICMJE

MLA

NLM

Perch, N. S., & Widenhoefer, R. A. (2001). Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics, 20(25), 5251–5253. https://doi.org/10.1021/om010876u

Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics 20, no. 25 (December 10, 2001): 5251–53. https://doi.org/10.1021/om010876u.

Perch NS, Widenhoefer RA. Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics. 2001 Dec 10;20(25):5251–3.

Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics, vol. 20, no. 25, Dec. 2001, pp. 5251–53. Scopus, doi:10.1021/om010876u.

Perch NS, Widenhoefer RA. Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics. 2001 Dec 10;20(25):5251–5253.

Journal cover image

Published In

Organometallics

DOI

10.1021/om010876u

ISSN

0276-7333

Publication Date

December 10, 2001

Volume

20

Issue

25

Start / End Page

5251 / 5253

Related Subject Headings

Organic Chemistry
3406 Physical chemistry
3402 Inorganic chemistry
0399 Other Chemical Sciences
0305 Organic Chemistry
0302 Inorganic Chemistry