Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex
Publication
, Journal Article
Perch, NS; Widenhoefer, RA
Published in: Organometallics
December 10, 2001
Warming a solution of {(phen)Pd[η1:η2-CH(CH2SiEt3) CH2C(CO2Me)2CH2CH= CH2]}+[BAr4]- (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10-4 M s-1, ΔG‡ = 17.1 ± 0.1 kcal mol-1) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH2 CHCH2CC(CO2Me)2CH2CHCH2 SiEt3](NC Ar)}+-[BAr4]- (5) in 96 ± 10% yield (1H NMR).
Duke Scholars
Published In
Organometallics
DOI
ISSN
0276-7333
Publication Date
December 10, 2001
Volume
20
Issue
25
Start / End Page
5251 / 5253
Related Subject Headings
- Organic Chemistry
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Perch, N. S., & Widenhoefer, R. A. (2001). Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics, 20(25), 5251–5253. https://doi.org/10.1021/om010876u
Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics 20, no. 25 (December 10, 2001): 5251–53. https://doi.org/10.1021/om010876u.
Perch NS, Widenhoefer RA. Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics. 2001 Dec 10;20(25):5251–3.
Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics, vol. 20, no. 25, Dec. 2001, pp. 5251–53. Scopus, doi:10.1021/om010876u.
Perch NS, Widenhoefer RA. Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics. 2001 Dec 10;20(25):5251–5253.
Published In
Organometallics
DOI
ISSN
0276-7333
Publication Date
December 10, 2001
Volume
20
Issue
25
Start / End Page
5251 / 5253
Related Subject Headings
- Organic Chemistry
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry