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Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection.

Publication ,  Journal Article
Sergueev, DS; Sergueeva, ZA; Shaw, BR
Published in: Nucleosides, nucleotides & nucleic acids
April 2001

Short oligonucleoside boranophosphates containing all four nucleosides were synthesized on solid support using base-unprotected nucleoside H-phosphonate monomers. This strategy avoided irreversible base modifications during the boronation procedure. Structures of the boranophosphate oligomers were confirmed by 1H, 31P, 10B NMR and MS analysis as well as by enzymatic hydrolysis.

Duke Scholars

Published In

Nucleosides, nucleotides & nucleic acids

DOI

EISSN

1532-2335

ISSN

1525-7770

Publication Date

April 2001

Volume

20

Issue

4-7

Start / End Page

789 / 795

Related Subject Headings

  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
  • Organophosphonates
  • Organic Chemistry
  • Oligonucleotides
  • Magnetic Resonance Spectroscopy
  • Chromatography, High Pressure Liquid
  • Boron Compounds
  • 3404 Medicinal and biomolecular chemistry
  • 3101 Biochemistry and cell biology
  • 0601 Biochemistry and Cell Biology
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Sergueev, D. S., Sergueeva, Z. A., & Shaw, B. R. (2001). Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection. Nucleosides, Nucleotides & Nucleic Acids, 20(4–7), 789–795. https://doi.org/10.1081/ncn-100002431
Sergueev, D. S., Z. A. Sergueeva, and B. R. Shaw. “Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection.Nucleosides, Nucleotides & Nucleic Acids 20, no. 4–7 (April 2001): 789–95. https://doi.org/10.1081/ncn-100002431.
Sergueev DS, Sergueeva ZA, Shaw BR. Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection. Nucleosides, nucleotides & nucleic acids. 2001 Apr;20(4–7):789–95.
Sergueev, D. S., et al. “Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection.Nucleosides, Nucleotides & Nucleic Acids, vol. 20, no. 4–7, Apr. 2001, pp. 789–95. Epmc, doi:10.1081/ncn-100002431.
Sergueev DS, Sergueeva ZA, Shaw BR. Synthesis of oligonucleoside boranophosphates via an H-phosphonate method without nucleobase protection. Nucleosides, nucleotides & nucleic acids. 2001 Apr;20(4–7):789–795.

Published In

Nucleosides, nucleotides & nucleic acids

DOI

EISSN

1532-2335

ISSN

1525-7770

Publication Date

April 2001

Volume

20

Issue

4-7

Start / End Page

789 / 795

Related Subject Headings

  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
  • Organophosphonates
  • Organic Chemistry
  • Oligonucleotides
  • Magnetic Resonance Spectroscopy
  • Chromatography, High Pressure Liquid
  • Boron Compounds
  • 3404 Medicinal and biomolecular chemistry
  • 3101 Biochemistry and cell biology
  • 0601 Biochemistry and Cell Biology