An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane
Publication
, Journal Article
Widenhoefer, RA; Vadehra, A
Published in: Tetrahedron Letters
December 3, 1999
A 1:1 mixture of (Me4-phen)Pd(Me)Cl [Me4-phen=3,4,7,8-tetramethyl-1,10-phenanthroline] and NaBAr4 [Ar=3,5-C6H3(CF3)2] catalyzed the cyclization/hydrosilylation of functionalized 1,6-dienes with dimethylphenylsilane within minutes at room temperature to form silylated cyclopentanes in good yield with high trans-selectivity.
Duke Scholars
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
December 3, 1999
Volume
40
Issue
49
Start / End Page
8499 / 8502
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Widenhoefer, R. A., & Vadehra, A. (1999). An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane. Tetrahedron Letters, 40(49), 8499–8502. https://doi.org/10.1016/S0040-4039(99)01706-2
Widenhoefer, R. A., and A. Vadehra. “An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane.” Tetrahedron Letters 40, no. 49 (December 3, 1999): 8499–8502. https://doi.org/10.1016/S0040-4039(99)01706-2.
Widenhoefer RA, Vadehra A. An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane. Tetrahedron Letters. 1999 Dec 3;40(49):8499–502.
Widenhoefer, R. A., and A. Vadehra. “An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane.” Tetrahedron Letters, vol. 40, no. 49, Dec. 1999, pp. 8499–502. Scopus, doi:10.1016/S0040-4039(99)01706-2.
Widenhoefer RA, Vadehra A. An improved catalyst for the cyclization/hydrosilylation of functionalized 1,6-dienes employing dimethylphenylsilane. Tetrahedron Letters. 1999 Dec 3;40(49):8499–8502.
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
December 3, 1999
Volume
40
Issue
49
Start / End Page
8499 / 8502
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry