Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles
Publication
, Journal Article
Widenhoefer, RA; Krzyzanowska, B; Webb-Wood, G
Published in: Organometallics
January 1, 1998
The cationic palladium complex (phen)Pd(Me)(OEt2)+BAr4- [phen = 1,10-phenanthroline; Ar = 3,5-C6Hs(CF3)2] catalyzed the intramolecular hydrosilylation of 4-pentenylsilanes and 5-hexenylsilanes to form silacyclohexanes in 43-87% isolated yield and with excellent regioselectivity (typically ≥ 98:1). © 1998 American Chemical Society.
Duke Scholars
Published In
Organometallics
DOI
ISSN
0276-7333
Publication Date
January 1, 1998
Volume
17
Issue
23
Start / End Page
5124 / 5127
Related Subject Headings
- Organic Chemistry
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Widenhoefer, R. A., Krzyzanowska, B., & Webb-Wood, G. (1998). Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles. Organometallics, 17(23), 5124–5127. https://doi.org/10.1021/om980585u
Widenhoefer, R. A., B. Krzyzanowska, and G. Webb-Wood. “Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles.” Organometallics 17, no. 23 (January 1, 1998): 5124–27. https://doi.org/10.1021/om980585u.
Widenhoefer RA, Krzyzanowska B, Webb-Wood G. Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles. Organometallics. 1998 Jan 1;17(23):5124–7.
Widenhoefer, R. A., et al. “Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles.” Organometallics, vol. 17, no. 23, Jan. 1998, pp. 5124–27. Scopus, doi:10.1021/om980585u.
Widenhoefer RA, Krzyzanowska B, Webb-Wood G. Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles. Organometallics. 1998 Jan 1;17(23):5124–5127.
Published In
Organometallics
DOI
ISSN
0276-7333
Publication Date
January 1, 1998
Volume
17
Issue
23
Start / End Page
5124 / 5127
Related Subject Headings
- Organic Chemistry
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry