Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans.
Publication
, Journal Article
Han, X; Widenhoefer, RA
Published in: The Journal of organic chemistry
March 2004
Treatment of 4-allyl-2,6-dimethyl-3,5-heptanedione with a catalytic amount of PdCl(2)(CH(3)CN)(2) (5 mol %) and a stoichiometric amount of CuCl(2) (2.2 equiv) in dioxane at 60 degrees C for 12 h formed 3-isobutyryl-2-isopropyl-5-methylfuran in 77% isolated yield. A number of alpha-alkenyl beta-diketones underwent oxidative alkoxylation under these conditions to form 2,3,5-trisubsituted furans in moderate to good yield.
Duke Scholars
Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2004
Volume
69
Issue
5
Start / End Page
1738 / 1740
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Han, X., & Widenhoefer, R. A. (2004). Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans. The Journal of Organic Chemistry, 69(5), 1738–1740. https://doi.org/10.1021/jo035576w
Han, Xiaoqing, and Ross A. Widenhoefer. “Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans.” The Journal of Organic Chemistry 69, no. 5 (March 2004): 1738–40. https://doi.org/10.1021/jo035576w.
Han X, Widenhoefer RA. Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans. The Journal of organic chemistry. 2004 Mar;69(5):1738–40.
Han, Xiaoqing, and Ross A. Widenhoefer. “Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans.” The Journal of Organic Chemistry, vol. 69, no. 5, Mar. 2004, pp. 1738–40. Epmc, doi:10.1021/jo035576w.
Han X, Widenhoefer RA. Palladium-catalyzed oxidative alkoxylation of alpha-alkenyl beta-diketones to form functionalized furans. The Journal of organic chemistry. 2004 Mar;69(5):1738–1740.
Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2004
Volume
69
Issue
5
Start / End Page
1738 / 1740
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry