X-ray crystal structure analyses and conformational studies of cis-cyclo-octane-1,5-diol and cyclo-octane-1,5-dione
Single-crystal X-ray analyses of cis-cyclo-octane-1,5-diol (1) and cyclo-octane-1,5-dione (2) have established that the eight membered rings in both compounds adopt boat-chair conformations in the solid state. The observed geometries accord well with those derived by force-field methods. Monoclinic crystals of (1) belong to space group Cc, a = 9.119(4), b = 11.717(5), c = 8.118(4) Å, β = 108.35(5)°, Z = 4. Crystals of (2) are orthorhombic, space group P2
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Published In
DOI
ISSN
Publication Date
Issue
Start / End Page
Related Subject Headings
- Organic Chemistry