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Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization

Publication ,  Journal Article
Roe, AN; McPhail, AT; Porter, NA
Published in: Journal of the American Chemical Society
January 1, 1983

In this study two unsaturated hydroperoxides, model compounds for natural rubber, polyunsaturated isoprenoids such as polyprenols, and polybutadiene, were exposed to initiators in the presence of oxygen. The products of these reactions were isolated and found to be cyclic peroxides that could be produced by a series of reactions involving peroxy radical cyclizations followed by trapping of molecular oxygen to form new peroxy radicals. © 1983, American Chemical Society. All rights reserved.

Duke Scholars

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

January 1, 1983

Volume

105

Issue

5

Start / End Page

1199 / 1203

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Roe, A. N., McPhail, A. T., & Porter, N. A. (1983). Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization. Journal of the American Chemical Society, 105(5), 1199–1203. https://doi.org/10.1021/ja00343a021
Roe, A. N., A. T. McPhail, and N. A. Porter. “Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization.” Journal of the American Chemical Society 105, no. 5 (January 1, 1983): 1199–1203. https://doi.org/10.1021/ja00343a021.
Roe AN, McPhail AT, Porter NA. Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization. Journal of the American Chemical Society. 1983 Jan 1;105(5):1199–203.
Roe, A. N., et al. “Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization.” Journal of the American Chemical Society, vol. 105, no. 5, Jan. 1983, pp. 1199–203. Scopus, doi:10.1021/ja00343a021.
Roe AN, McPhail AT, Porter NA. Serial Cyclization: Studies in the Mechanism and Stereochemistry of Peroxy Radical Cyclization. Journal of the American Chemical Society. 1983 Jan 1;105(5):1199–1203.
Journal cover image

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

January 1, 1983

Volume

105

Issue

5

Start / End Page

1199 / 1203

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences