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Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}

Publication ,  Journal Article
Wells, RL; Purdy, AP; McPhail, AT; Pitt, CG
Published in: Journal of Organometallic Chemistry
July 15, 1986
Published version (DOI)

The dimer [(Me3SiCH2)2AsGaPh2]2, obtained from the reaction of (Me3SiCH2)2AsH with Ph3Ga, has been characterized by partial elemental analysis, NMR spectroscopy, cryoscopic molecular weight determination, and complete single-crystal X-ray analysis. Crystals of the dimer are triclinic, space group P1, with a 10.541(1), b 11.939(1), c 10.539(1) Å, α 99.72(1), β 83.00(1), γ 114.55(1)°, U 1187.1 Å3 and Z = 1. The bond lenghts (GaAs 2.518(1) and GaAs′ 2.530(1) Å) and bond angles (AsGaAs′ 85.08(2) and GaAsGa′ 94.92(2)°) in the centrosymmetric, and consequently planar, four-membered ring indicate a significant degree of strain. © 1986.

Duke Scholars

Andrew T. McPhail
Author Andrew T. McPhail Chemistry

Published In

Journal of Organometallic Chemistry

DOI

10.1016/S0022-328X(00)99726-2

ISSN

0022-328X

Publication Date

July 15, 1986

Volume

308

Issue

3

Start / End Page

281 / 288

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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MLA
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Wells, R. L., Purdy, A. P., McPhail, A. T., & Pitt, C. G. (1986). Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}. Journal of Organometallic Chemistry, 308(3), 281–288. https://doi.org/10.1016/S0022-328X(00)99726-2
Wells, R. L., A. P. Purdy, A. T. McPhail, and C. G. Pitt. “Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}.” Journal of Organometallic Chemistry 308, no. 3 (July 15, 1986): 281–88. https://doi.org/10.1016/S0022-328X(00)99726-2.
Wells RL, Purdy AP, McPhail AT, Pitt CG. Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}. Journal of Organometallic Chemistry. 1986 Jul 15;308(3):281–8.
Wells, R. L., et al. “Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}.” Journal of Organometallic Chemistry, vol. 308, no. 3, July 1986, pp. 281–88. Scopus, doi:10.1016/S0022-328X(00)99726-2.
Wells RL, Purdy AP, McPhail AT, Pitt CG. Synthesis and crystal structure of the dimer bis{[bis(trimethylsilylmethyl)arsino]diphenylgallane}. Journal of Organometallic Chemistry. 1986 Jul 15;308(3):281–288.
Journal cover image

Published In

Journal of Organometallic Chemistry

DOI

10.1016/S0022-328X(00)99726-2

ISSN

0022-328X

Publication Date

July 15, 1986

Volume

308

Issue

3

Start / End Page

281 / 288

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry