Enantioselectivity in camphor pinacolisation
Publication
, Journal Article
Pradhan, SK; Thakker, KR; McPhail, AT
Published in: Tetrahedron Letters
January 1, 1987
Total enantioselectivity has been observed in pinacol formation using Li/THF. (+) Camphor and (±) Camphor give the optically active and racemic form of a single pinacol whose stereochemistry has been established as endo:endo by X-ray analysis. An exo:endo pinacol is formed as the sole product if camphor is added to Li/NH3. Tentative mechanism is proposed. © 1987.
Duke Scholars
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
January 1, 1987
Volume
28
Issue
16
Start / End Page
1813 / 1816
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Pradhan, S. K., Thakker, K. R., & McPhail, A. T. (1987). Enantioselectivity in camphor pinacolisation. Tetrahedron Letters, 28(16), 1813–1816. https://doi.org/10.1016/S0040-4039(00)95429-7
Pradhan, S. K., K. R. Thakker, and A. T. McPhail. “Enantioselectivity in camphor pinacolisation.” Tetrahedron Letters 28, no. 16 (January 1, 1987): 1813–16. https://doi.org/10.1016/S0040-4039(00)95429-7.
Pradhan SK, Thakker KR, McPhail AT. Enantioselectivity in camphor pinacolisation. Tetrahedron Letters. 1987 Jan 1;28(16):1813–6.
Pradhan, S. K., et al. “Enantioselectivity in camphor pinacolisation.” Tetrahedron Letters, vol. 28, no. 16, Jan. 1987, pp. 1813–16. Scopus, doi:10.1016/S0040-4039(00)95429-7.
Pradhan SK, Thakker KR, McPhail AT. Enantioselectivity in camphor pinacolisation. Tetrahedron Letters. 1987 Jan 1;28(16):1813–1816.
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
January 1, 1987
Volume
28
Issue
16
Start / End Page
1813 / 1816
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry