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The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3

Publication ,  Journal Article
Wells, RL; Purdy, AP; McPhail, AT; Pitt, CG
Published in: Journal of Organometallic Chemistry
October 25, 1988

[(Me3SiCH2)2AsGaBr2]3, the first trimeric mono(arsino)gallane to be structurally characterized by X-ray crystallographic analysis, has been shown to contain a (GaAs)3 ring in the twist-boat conformation. Crystals of the trimer are monoclinic, space group P2/c (C42h), with a 18.877(4), b 13.710(3), c 24.821(4) Å, β 122.24(2)°, U 5433.4 Å3, and Z = 4. The GaAs bond lengths (2.432(2)-2.464(1) Å) are all less than any of those found in the (GaAs)2 rings of dimeric arsinogallanes. © 1988.

Duke Scholars

Published In

Journal of Organometallic Chemistry

DOI

ISSN

0022-328X

Publication Date

October 25, 1988

Volume

354

Issue

3

Start / End Page

287 / 292

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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Wells, R. L., Purdy, A. P., McPhail, A. T., & Pitt, C. G. (1988). The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3. Journal of Organometallic Chemistry, 354(3), 287–292. https://doi.org/10.1016/0022-328X(88)80653-3
Wells, R. L., A. P. Purdy, A. T. McPhail, and C. G. Pitt. “The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3.” Journal of Organometallic Chemistry 354, no. 3 (October 25, 1988): 287–92. https://doi.org/10.1016/0022-328X(88)80653-3.
Wells RL, Purdy AP, McPhail AT, Pitt CG. The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3. Journal of Organometallic Chemistry. 1988 Oct 25;354(3):287–92.
Wells, R. L., et al. “The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3.” Journal of Organometallic Chemistry, vol. 354, no. 3, Oct. 1988, pp. 287–92. Scopus, doi:10.1016/0022-328X(88)80653-3.
Wells RL, Purdy AP, McPhail AT, Pitt CG. The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3. Journal of Organometallic Chemistry. 1988 Oct 25;354(3):287–292.
Journal cover image

Published In

Journal of Organometallic Chemistry

DOI

ISSN

0022-328X

Publication Date

October 25, 1988

Volume

354

Issue

3

Start / End Page

287 / 292

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry