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Synthesis of novel substituted cyclopentadienes and their early transition metal complexes

Publication ,  Journal Article
Clark, TJ; Nile, TA; McPhail, D; McPhail, AT
Published in: Polyhedron
January 1, 1989

Synthesis of two substituted cyclopentadienes, 1,3-bis(1-methylcyclohexyl) cyclopentadiene, Cp′H and [2-methyl-2-(2-pyridyl)ethyl]cyclopentadiene, Cp″H from fulvene intermediates is reported. These are readily converted to their early transition metal complexes Cp′W(CO)3Me, Cp″Mo(CO)3Me, CP″W(CO)3Me and [Cp″Ti(O)Cl·CH2Cl2]2. The X-ray crystal structure of the titanium compound shows that the nitrogen of the pyridine cyclopentadienyl substituent is coordinated to the titanium. © 1989.

Duke Scholars

Published In

Polyhedron

DOI

ISSN

0277-5387

Publication Date

January 1, 1989

Volume

8

Issue

13-14

Start / End Page

1804 / 1806

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

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ICMJE
MLA
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Clark, T. J., Nile, T. A., McPhail, D., & McPhail, A. T. (1989). Synthesis of novel substituted cyclopentadienes and their early transition metal complexes. Polyhedron, 8(13–14), 1804–1806. https://doi.org/10.1016/S0277-5387(00)80652-X
Clark, T. J., T. A. Nile, D. McPhail, and A. T. McPhail. “Synthesis of novel substituted cyclopentadienes and their early transition metal complexes.” Polyhedron 8, no. 13–14 (January 1, 1989): 1804–6. https://doi.org/10.1016/S0277-5387(00)80652-X.
Clark TJ, Nile TA, McPhail D, McPhail AT. Synthesis of novel substituted cyclopentadienes and their early transition metal complexes. Polyhedron. 1989 Jan 1;8(13–14):1804–6.
Clark, T. J., et al. “Synthesis of novel substituted cyclopentadienes and their early transition metal complexes.” Polyhedron, vol. 8, no. 13–14, Jan. 1989, pp. 1804–06. Scopus, doi:10.1016/S0277-5387(00)80652-X.
Clark TJ, Nile TA, McPhail D, McPhail AT. Synthesis of novel substituted cyclopentadienes and their early transition metal complexes. Polyhedron. 1989 Jan 1;8(13–14):1804–1806.
Journal cover image

Published In

Polyhedron

DOI

ISSN

0277-5387

Publication Date

January 1, 1989

Volume

8

Issue

13-14

Start / End Page

1804 / 1806

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry