Skip to main content
Journal cover image

Photochemical Reaction of a Diplatinum μ-Phenylethenylidene Complex with Diphenylacetylene: Unusual Formation of a μ-η13-Butadienediyl Complex

Publication ,  Journal Article
Baralt, E; Lukehart, CM; McPhail, AT; McPhail, DR
Published in: Organometallics
February 1, 1991

Photochemical reaction of a diplatinum μ-alkenylidene complex with PhC≡CPh occurs with C-C coupling of the alkenylidene and alkyne moieties to give an expanded, unsaturated μ-η1:η3-butadienediyl ligand. Structural and isotopic-labeling studies indicate that this reaction proceeds by an unusually complex mechanism. © 1991, American Chemical Society. All rights reserved.

Duke Scholars

Published In

Organometallics

DOI

EISSN

1520-6041

ISSN

0276-7333

Publication Date

February 1, 1991

Volume

10

Issue

2

Start / End Page

516 / 520

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Baralt, E., Lukehart, C. M., McPhail, A. T., & McPhail, D. R. (1991). Photochemical Reaction of a Diplatinum μ-Phenylethenylidene Complex with Diphenylacetylene: Unusual Formation of a μ-η13-Butadienediyl Complex. Organometallics, 10(2), 516–520. https://doi.org/10.1021/om00048a032
Baralt, E., C. M. Lukehart, A. T. McPhail, and D. R. McPhail. “Photochemical Reaction of a Diplatinum μ-Phenylethenylidene Complex with Diphenylacetylene: Unusual Formation of a μ-η13-Butadienediyl Complex.” Organometallics 10, no. 2 (February 1, 1991): 516–20. https://doi.org/10.1021/om00048a032.
Baralt, E., et al. “Photochemical Reaction of a Diplatinum μ-Phenylethenylidene Complex with Diphenylacetylene: Unusual Formation of a μ-η13-Butadienediyl Complex.” Organometallics, vol. 10, no. 2, Feb. 1991, pp. 516–20. Scopus, doi:10.1021/om00048a032.
Journal cover image

Published In

Organometallics

DOI

EISSN

1520-6041

ISSN

0276-7333

Publication Date

February 1, 1991

Volume

10

Issue

2

Start / End Page

516 / 520

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry