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Dehalosilylation reactions involving E(sime3)3 and Ph2Incl. Synthesis and X-ray structures of [Ph2Ine(SiMe3)2]2 (E = P or As)

Publication ,  Journal Article
Wells, RL; McPhail, AT; Jones, LJ; Self, MF
Published in: Polyhedron
January 1, 1993
Published version (DOI)

Combining P(SiMe3)3 or As(SiMe3)3 with Ph2InCl in a 1:1 mole ratio results in the elimination of Me3SiCl via a dehalosilylation reaction to yield [Ph2InP(SiMe3)2]2 (I) and [Ph2InAs(SiMe3)2]2 (II), respectively. X-ray structures were determined for I and II. The (InP)2 core of dimer I is planar, whereas in dimer II the (InAs)2 ring is slightly puckered. © 1993.

Duke Scholars

Andrew T. McPhail
Author Andrew T. McPhail Chemistry

Published In

Polyhedron

DOI

10.1016/S0277-5387(00)81620-4

ISSN

0277-5387

Publication Date

January 1, 1993

Volume

12

Issue

2

Start / End Page

141 / 147

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

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ICMJE
MLA
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Wells, R. L., McPhail, A. T., Jones, L. J., & Self, M. F. (1993). Dehalosilylation reactions involving E(sime3)3 and Ph2Incl. Synthesis and X-ray structures of [Ph2Ine(SiMe3)2]2 (E = P or As). Polyhedron, 12(2), 141–147. https://doi.org/10.1016/S0277-5387(00)81620-4
Wells, R. L., A. T. McPhail, L. J. Jones, and M. F. Self. “Dehalosilylation reactions involving E(sime3)3 and Ph2Incl. Synthesis and X-ray structures of [Ph2Ine(SiMe3)2]2 (E = P or As).” Polyhedron 12, no. 2 (January 1, 1993): 141–47. https://doi.org/10.1016/S0277-5387(00)81620-4.
Wells, R. L., et al. “Dehalosilylation reactions involving E(sime3)3 and Ph2Incl. Synthesis and X-ray structures of [Ph2Ine(SiMe3)2]2 (E = P or As).” Polyhedron, vol. 12, no. 2, Jan. 1993, pp. 141–47. Scopus, doi:10.1016/S0277-5387(00)81620-4.
Journal cover image

Published In

Polyhedron

DOI

10.1016/S0277-5387(00)81620-4

ISSN

0277-5387

Publication Date

January 1, 1993

Volume

12

Issue

2

Start / End Page

141 / 147

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry