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X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2

Publication ,  Journal Article
Self, MF; McPhail, AT; Wells, RL
Published in: Journal of Coordination Chemistry
January 1, 1993
Published version (DOI)

The solid-state structure of (Ph2InOSiMe3)2, 1. has been established by single-crystal X-ray analysis. Monoclinic crystals of 1 belong to space group P21/c, with a = 9.136(1), b = 15.503(2), c = 11.836(1) A, β= 102.46(1)°, Z = 2. Refinement of atomic parameters converged at R =0.050 (Rw = 0.063) over 1718 observed reflections with l>3.0σ(I). The dimeric molecule lies on a crystallographic centre of symmetry with In-0 = 2.159(7) and 2.149(8) A, O-In-O = 78.9(3)°, and In-O-In= 101.1(3)°. Compound 1 is only the second example of a simple dimeric organoindium alkoxide to be structurally characterized in this manner. © 1993, Taylor & Francis Group, LLC. All rights reserved.

Duke Scholars

Andrew T. McPhail
Author Andrew T. McPhail Chemistry

Published In

Journal of Coordination Chemistry

DOI

10.1080/00958979308037122

EISSN

1029-0389

ISSN

0095-8972

Publication Date

January 1, 1993

Volume

29

Issue

1-2

Start / End Page

27 / 32

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0302 Inorganic Chemistry
 

Citation

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Self, M. F., McPhail, A. T., & Wells, R. L. (1993). X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2. Journal of Coordination Chemistry, 29(1–2), 27–32. https://doi.org/10.1080/00958979308037122
Self, M. F., A. T. McPhail, and R. L. Wells. “X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2.” Journal of Coordination Chemistry 29, no. 1–2 (January 1, 1993): 27–32. https://doi.org/10.1080/00958979308037122.
Self MF, McPhail AT, Wells RL. X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2. Journal of Coordination Chemistry. 1993 Jan 1;29(1–2):27–32.
Self, M. F., et al. “X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2.” Journal of Coordination Chemistry, vol. 29, no. 1–2, Jan. 1993, pp. 27–32. Scopus, doi:10.1080/00958979308037122.
Self MF, McPhail AT, Wells RL. X-Ray Crystal Structure of an Organoindium Alkoxide Dimer, (Ph2InOSiMe3)2. Journal of Coordination Chemistry. 1993 Jan 1;29(1–2):27–32.

Published In

Journal of Coordination Chemistry

DOI

10.1080/00958979308037122

EISSN

1029-0389

ISSN

0095-8972

Publication Date

January 1, 1993

Volume

29

Issue

1-2

Start / End Page

27 / 32

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0302 Inorganic Chemistry